A one-dimensional ladder-like six-coordinate cadmium polymer: catena-poly[bis[(S)-2-methylpiperazine-1,4-diium] [bis[trichloridocadmium(II)]-di-μ3-chlorido]]

Wu; De-Hong

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A one-dimensional ladder-like six-coordinate cadmium polymer: catena-poly[bis[(S)-2-methylpiperazine-1,4-diium] [bis[trichloridocadmium(II)]-di-μ3-chlorido]]

机译：一维阶梯状六坐标镉聚合物：链状聚[bis [（S）-2-甲基哌嗪-1,4-diium] [bis [trichloridocadmium（II）]-di-μ3-chloroido]]

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The crystal structure of the title compound {(C5H14N2)2[Cd2Cl8]}n, (I), consists of hydrogen-bonded 2-methylpiperazinediium (H2MPPA2+) cations in the presence of one-dimensional polymeric {[CdCl3(μ3-Cl)]2?}n anions. The CdII centres are hexacoordinated by three terminal chlorides and three bridging chlorides and have a slightly distorted octahedral CdCl3(μ3-Cl)3 arrangement. The alternating CdCl6 octahedra form four-membered Cd2Cl2 rings by the sharing of neighbouring Cd–Cl edges to give rise to extended one-dimensional ladder-like chains parallel to the b axis, with a Cd...Cd distance of 4.094?(2)?? and a Cd...Cd...Cd angle of 91.264?(8)°. The H2MPPA2+ cations crosslink the [CdCl3(μ3-Cl)]n chains by the formation of two N—H...Cl hydrogen bonds to each chain, giving rise to one-dimensional ladder-like H2MPPA2+–Cl2 hydrogen-bonded chains [graph set R42(14)]. The [CdCl3(μ3-Cl)]n chains are interwoven with the H2MPPA2+–Cl2 hydrogen-bonded chains, giving rise to a three-dimensional supramolecular network.

机译：标题化合物{（C5H14N2）2 [Cd2Cl8]} n，（I）的晶体结构由氢键合的2-甲基哌嗪二鎓（H2MPPA2 +）阳离子组成，存在一维聚合{[CdCl3（μ3-Cl）] ] 2？} n阴离子。 CdII中心由三个末端氯化物和三个桥接氯化物进行六配位，并且八面体CdCl3（μ3-Cl）3排列略有变形。交替的CdCl6八面体通过共享相邻的Cd-Cl边缘形成四元Cd2Cl2环，从而产生平行于b轴的扩展的一维阶梯状链，其Cd ... Cd距离为4.094？（2 ）?? Cd ... Cd ... Cd角为91.264？（8）°。 H2MPPA2 +阳离子通过在每个链上形成两个N ... H ... Cl氢键使[CdCl3（μ3-Cl）] n链交联，从而形成一维梯状H2MPPA2 + -Cl2氢键链[图集R42（14）]。 [CdCl3（μ3-Cl）] n链与H2MPPA2 + –Cl2氢键链交织在一起，形成了三维超分子网络。

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《Acta crystallographica. Section C, Structural chemistry.》 |2014年第5期|共4页
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Wu; De-Hong;
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正文语种 eng
中图分类晶体学;
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crystal structure; organic–inorganic hybrid complex; 2-methylpiperazine-1; 4-diium; chloridocadmium(II); one-dimensional coordination polymer;

机译：晶体结构;有机-无机杂化配合物;2-甲基哌嗪-1;4-二碘;氯镉（II）;一维配位聚合物;

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1. A one-dimensional ladder-like six-coordinate cadmium polymer: catena-poly[bis[(S)-2-methylpiperazine-1,4-diium] [bis[trichloridocadmium(II)]-di-μ3-chlorido]] [J] . Wu, De-Hong Acta crystallographica. Section C, Structural chemistry. . 2014,第5期

机译：一维阶梯状六坐标镉聚合物：链状聚[bis [（S）-2-甲基哌嗪-1,4-diium] [bis [trichloridocadmium（II）]-di-μ3-chloroido]]
2. Isotypic one-dimensional coordination polymers: catena-poly[[di-chlorido-cadmium]-μ-5,6-bis-(pyridin-2-yl)pyrazine-2,3-di-carboxyl-ato-κ2N5:N6] and catena-poly[[di-chlorido-mercury(II)]-μ-5,6-bis-(pyridin-2-yl)pyrazine-2,3-di-carboxyl-ato-κ2N5:N6] [J] . Alfonso M., Stoeckli-Evans H. Acta Crystallographica Section E: Crystallographic Communications . 2016,第8期

机译：同型一维配位聚合物：链状聚[[二氯代镉]-μ-5,6-双-（吡啶-2-基）吡嗪-2,3-二羧基-κ2N5：N6]和链状聚[[二氯汞（II）]-μ-5,6-双-（吡啶-2-基）吡嗪-2,3-二羧基-κ2N5：N6]
3. catena-Poly[[bis[2-chloro-6-(1H-1,2,4-triazol-1-yl-κN4)pyridine]cadmium(II)]-di-μ-thiocyanato-κ2N:S;κ2S:N]: a one-dimensional coordination polymer [J] . Sun T.T., Yang Z.N. Acta Crystallographica Section E: Crystallographic Communications . 2008,第10期

机译：阳离子聚[[双[2-氯-6-（1H-1,2,4-三唑-1-基-κN4）吡啶]镉（II）]-二-μ-硫氰酸根-κ2N：S;κ2S： N]：一维配位聚合物
4. Synthesis and X-ray Structural Studies Of Novel Metal-Organic Complex: Diiodobis(2-aminopyridine)Cadmium(II) Single Crystal [C] . Venkatesan. G, Anandha Babu. G, Ramasamy. P DAE Solid State Physics Symposium . 2014

机译：新型金属 - 有机复合物的合成与X射线结构研究：二碘缺鼠（2-氨基吡啶）镉（II）单晶
5. I. Tertiary aryl sulfonamides as new cross coupling partners for nickel catalyzed Kumada-Corriu-Tamao reductive and carbon-carbon bond forming cross coupling reactions. II. N-sulfonyl deprotection under mild nickel(0) catalyzed Kumada-Corriu-Tamao coupling conditions and development of the N-Ans protecting group. III. Synthesis and application of 3,3'-di-(2-pyridyl)-1,1'-bi-2-naphthol ligands [D] . Milburn, Robert Ronald 2004

机译：I.叔芳基磺酰胺作为镍催化的Kumada-Corriu-Tamao还原和碳-碳键形成交叉偶联反应的新交叉偶联伴侣。二。在温和的镍（0）下N-磺酰基脱保护催化了Kumada-Corriu-Tamao偶联条件和N-Ans保护基的发展。三， 3,3'-二-（2-吡啶基）-1,1'-bi-2-萘酚配体的合成及应用
6. catena-Polybis2-chloro-6-(1H-124-triazol-1-yl-κN 4)pyridinecadmium(II)-di-μ-thiocyanato-κ2 N:S;κ2 S:N: a one-dimensional coordination polymer [O] . Zhong Nian Yang, Ting Ting Sun 2008

机译：阳离子多聚bis 2-氯-6-（1H-124-三唑-1-基-κN 4）吡啶镉（II）-二-μ-硫代氰基-κ2 N：S;κ2 S：N：一维配位聚合物
7. Bis[(2S,4S)-4-(2-hydroxyethyl)-2-methylpiperazine-1,4-diium] di-μ-chlorido-bis[trichloridocadmium(II)] [O] . Tao Rong 2011

机译：双[（2s，4s）-4-（2-羟基乙基）-2-甲基哌嗪-1,4-二鎓]二 - ＆amp;＃956; - 氯化物 - 双[三氯化镉（II）]
8. a. c. Conduction in Bis (catena-poly(methylarsenic)) an Organic Ladder Polymer. [R] . lewis, j. e. edris, m. 1974

机译：一个。 C。在Bis（catena-poly（methylarsenic））有机梯形聚合物中导电。

A one-dimensional ladder-like six-coordinate cadmium polymer: catena-poly[bis[(S)-2-methylpiperazine-1,4-diium] [bis[trichloridocadmium(II)]-di-μ3-chlorido]]

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