Substitutional disorder in Sr2yEuyB22xSi2+3xAl2xN8+x (x 0.12, y 0.10)

Funahashi; Shiro.; Michiue; Yuichi.; Takeda; Takashi.; Xie; Rong-Jun.; Hirosaki; Naoto

首页> 外文期刊>Acta crystallographica. Section C, Structural chemistry. >Substitutional disorder in Sr2yEuyB22xSi2+3xAl2xN8+x (x 0.12, y 0.10)

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Substitutional disorder in Sr2yEuyB22xSi2+3xAl2xN8+x (x 0.12, y 0.10)

机译：Sr2yEuyB22xSi2 + 3xAl2xN8 + x中的取代障碍（x 0.12，y 0.10）

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摘要

A novel nitride, Sr2yEuyB22xSi2+3xAl2xN8+x (x 0.12, y 0.10) (distrontium europium diboron disilicon dialuminium octanitride), with the space group P2c, was synthesized from Sr3N2, EuN, Si3N4, AlN and BN under nitrogen gas pressure. The structure consists of a host framework with Sr/Eu atoms accommodated in the cavities. The host framework is constructed by the linkage of MN4 tetrahedra (M = Si, Al) and BN3 triangles, and contains substitutional disorder described by the alternative occupation of B2 or Si2N on the (0, 0, z) axis. The B2:Si2N ratio contained in an entire crystal is about 9:1.

机译：在氮气压力下，由Sr3N2，EuN，Si3N4，AlN和BN合成了空间空间为P2c的新型氮化物Sr2yEuyB22xSi2 + 3xAl2xN8 + x（x 0.12，y 0.10）（dis euro二硼二硅二氮合锡）。该结构由一个宿主框架组成，其中的Sr / Eu原子容纳在空腔中。宿主框架是通过MN4四面体（M = Si，Al）和BN3三角形的链接构建的，并包含由B0或Si2N在（0，0，z）轴上的替代占据所描述的取代无序。整个晶体中所含的B2：Si2N之比约为9：1。

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《Acta crystallographica. Section C, Structural chemistry.》 |2014年第5期|共3页
作者
Funahashi; Shiro.; Michiue; Yuichi.; Takeda; Takashi.; Xie; Rong-Jun.; Hirosaki; Naoto;
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正文语种 eng
中图分类晶体学;
关键词
crystal structure; substitutional disorder; nitride; boron-containing nitride phosphors; ceramic materials;

机译：晶体结构置换无序氮化物含硼氮化物荧光粉陶瓷材料;

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1. Substitutional disorder in Sr2yEuyB22xSi2+3xAl2xN8+x (x 0.12, y 0.10) [J] . Funahashi, Shiro., Michiue, Acta crystallographica. Section C, Structural chemistry. . 2014,第5期

机译：Sr2yEuyB22xSi2 + 3xAl2xN8 + x中的取代障碍（x 0.12，y 0.10）
2. Study on phase structure and electrochemical properties of Ml{sub}(1-x)Mg{sub}xNi{sub}2.80Co{sub}0.50Mn{sub}0.10Al{sub}0.10 (x = 0.08, 0.12, 0.20, 0.24, 0.28) hydrogen storage alloys [J] . Yuan Li, Shumin Han, Jinhua Li, Electrochimica Acta . 2007,第19期

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Substitutional disorder in Sr2yEuyB22xSi2+3xAl2xN8+x (x 0.12, y 0.10)

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