A two-dimensional copper(II) coordination polymer based on 2-propyl-1H-imidazole-4,5-dicarboxylic acid

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A two-dimensional copper(II) coordination polymer based on 2-propyl-1H-imidazole-4,5-dicarboxylic acid

机译：基于2-丙基-1H-咪唑-4,5-二羧酸的二维铜（II）配位聚合物

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Single-crystal X-ray diffraction analysis of poly[bis(μ2-5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ3 N3,O4:O5)copper(II)], [Cu(C8H9N2O4)2)] n , indicates that one carboxylic acid group of the 2-propyl-1H-imidazole-4,5-dicarboxylic acid (H3PDI) ligand is deprotonated. The resulting H2PDI- anion, acting as a bridge, connects the CuII cations to form a two-dimensional (4,4)-connected layer. Adjacent layers are further linked through interlayer hydrogen-bond interactions, resulting in a three-dimensional supramolecular structure.

机译：聚[双（μ2-5-羧基-2-丙基-1H-咪唑-4-羧基-κ3N3，O4：O5）铜（II）]，[Cu（C8H9N2O4）2的单晶X射线衍射分析）] n表示2-丙基-1H-咪唑-4,5-二羧酸（H3PDI）配体的一个羧酸基团被去质子化。所得的H2PDI-阴离子充当桥，将CuII阳离子连接起来，形成二维（4,4）连接层。相邻层通过层间氢键相互作用进一步连接，从而产生三维超分子结构。

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《Acta crystallographica. Section C, Structural chemistry.》 |2015年第2期|共3页
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正文语种 eng
中图分类晶体学;
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2-propyl-1H-imidazole-4; 5-dicarboxylic acid; copper(II) polymer structure; crystal structure; two-dimensional coordination polymer;

机译：2-丙基-1H-咪唑-4;5-二羧酸;铜（II）聚合物结构;晶体结构;二维配位聚合物;

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1. A two-dimensional copper(II) coordination polymer based on 2-propyl-1H-imidazole-4,5-dicarboxylic acid [J] . Acta crystallographica. Section C, Structural chemistry. . 2015,第2期

机译：基于2-丙基-1H-咪唑-4,5-二羧酸的二维铜（II）配位聚合物
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A two-dimensional copper(II) coordination polymer based on 2-propyl-1H-imidazole-4,5-dicarboxylic acid

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