Order-disorder transition in monoclinic sulfur: a precise structural study by high-resolution neutron powder diffraction

David WIF; Ibberson RM; Cox SFJ; Wood PT

首页> 外文期刊>Acta Crystallographica, Section B. Structural Science >Order-disorder transition in monoclinic sulfur: a precise structural study by high-resolution neutron powder diffraction

【24h】

Order-disorder transition in monoclinic sulfur: a precise structural study by high-resolution neutron powder diffraction

机译：单斜硫中的有序-无序过渡：高分辨率中子粉末衍射的精确结构研究

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

High-resolution neutron powder diffraction has been used in order to characterize the order-disorder transition in monoclinic cyclo-octasulphur. Rapid data collection and the novel use of geometrically constrained refinements has enabled a direct and precise determination of the order parameter, based on molecular site occupancies, to be made. The transition is critical and continuous; with a transition temperature, T-c = 198.4 ( 3) K, and a critical exponent, beta = 0.28 (3), which is indicative of three-dimensional ordering. Difficulties encountered as a consequence of the low thermal conductivity of the sample are discussed.

机译：为了表征单斜环八硫中的有序-无序跃迁，已经使用了高分辨率中子粉末衍射。快速的数据收集和几何约束精简的新颖用法，使得能够基于分子位点占用率直接精确地确定阶数参数。过渡是关键和持续的;过渡温度T-c = 198.4（3）K，临界指数beta = 0.28（3），这表明三维排序。讨论了由于样品导热系数低而遇到的困难。

著录项

来源
《Acta Crystallographica, Section B. Structural Science》 |2006年第6期|共7页
作者
David WIF; Ibberson RM; Cox SFJ; Wood PT;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类晶体学;
关键词
CRYSTAL-STRUCTURE; ORTHORHOMBIC SULFUR; MOLECULAR-DYNAMICS; ELEMENTAL SULFUR; REFINEMENT;

机译：晶体结构;正交硫;分子动力学;元素硫;精炼;

相似文献

外文文献
中文文献
专利

1. Order-disorder transition in monoclinic sulfur: a precise structural study by high-resolution neutron powder diffraction [J] . David WIF, Ibberson RM, Cox SFJ, Acta Crystallographica, Section B. Structural Science . 2006,第6期

机译：单斜硫中的有序-无序过渡：高分辨率中子粉末衍射的精确结构研究
2. A high-resolution neutron powder diffraction study of the low-temperature structural phase transitions in RbCaF3 perovskite [J] . Knight Kevin S. Journal of Solid State Chemistry . 2018,第期

机译：RBCAF3钙钛矿低温结构相变的高分子中子粉衍射研究
3. Morin-type spin-reorientation transition below the Neel transition in the monoclinic compositions of (1 - x)BiFeO_(3-x)PbTiO_3 (x = 0.25 and 0.27): A combined dc magnetization and x-ray and neutron powder diffraction study [J] . Shuvrajyoti Bhattacharjee, Anatoliy Senyshyn, Hartmut Fuess, Physical review . 2013,第5期

机译：（1-x）BiFeO_（3-x）PbTiO_3（x = 0.25和0.27）单斜晶组成中Neel转变以下的Morin型自旋取向转变：直流磁化与X射线和中子粉末衍射研究的组合
4. X-Ray and neutron powder diffraction studies of phase transitions in LiCsSO_4 [C] . L.Mestres, M.L.Martinez-Sarrion, A.Bakkali, European powder diffraction conference;EPDIC6 . 1998

机译：LiCsSO_4中相变的X射线和中子粉末衍射研究
5. Neutron scattering and high-resolution synchrotron X-ray diffraction study of disordered perovskite crystals. [D] . La-Orauttapong, Duangmanee. 2003

机译：无序钙钛矿晶体的中子散射和高分辨率同步辐射X射线衍射研究。
6. Isothermal equation of state and high-pressure phase transitions of synthetic meridianiite (MgSO4·11D2O) determined by neutron powder diffraction and quasielastic neutron spectroscopy [O] . A. Dominic Fortes, Felix Fernandez-Alonso, Matthew Tucker, -1

机译：中子粉末衍射和准弹性中子光谱法测定合成堇青石（MgSO4·11D2O）的状态和高压相变等温方程
7. Order–disorder transition in monoclinic sulfur: a precise structural study by high-resolution neutron powder diffraction. Corrigendum [O] . W. I. F. David, R. M. Ibberson, S. F. J. Cox, 2007

机译：单斜硫型秩序紊乱转变：高分辨中子粉衍射的精确结构研究。勘误
8. Structural study of Sr(sub 2)CuO(sub 3+delta) by neutron powder diffraction [R] . Shimakawa, Y., Jorgensen, J. D., Mitchell, J. F., 1996

机译：中子粉末衍射对sr（sub 2）CuO（sub 3 + delta）的结构研究

Order-disorder transition in monoclinic sulfur: a precise structural study by high-resolution neutron powder diffraction

摘要

著录项

相似文献

相关主题

期刊订阅