Catalytic conversion of furfural-acetone condensation products into bio-derived C-8 linear alcohols over Ni-Cu/Al-SBA-15

Ramos Ruben; Hidalgo Jose M.; Gonel Michael; Tiser Zdenek; Bertella Francine; Martinez Agustin; Kikhtyanin Oleg; Kubicka David

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Catalytic conversion of furfural-acetone condensation products into bio-derived C-8 linear alcohols over Ni-Cu/Al-SBA-15

机译：在Ni-Cu / Al-SBA-15上催化转化糠醛 - 丙酮缩合产物的生物衍生的C-8线性醇

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The production of C-8 linear diols from a furfural-acetone condensation product has been achieved for the first time using a non-noble metal based catalyst. In particular, SBA-15 supported Ni-Cu bimetallic catalyst showed the best hydrogenating activity reaching an outstanding yield (ca. 63%) of the fully saturated product. The incorporation of acidity by the preparation of Ni-Cu/Al-SBA-15 resulted in the promotion of ring-opening steps, which led to a remarkable yield of C-8 linear diols (28%). These results establish a competitive catalytic route for the production of bio-based diols over cost-efficient 3d transition metal-based catalysts.

机译：使用非贵金属基催化剂首次实现了来自糠醛丙酮缩合产物的C-8线性二醇。特别地，SBA-15负载的Ni-Cu Bimetallic催化剂显示出最佳的氢化活性，达到完全饱和产物的出色产率（约63％）。通过制备Ni-Cu / Al-SBA-15掺入酸度导致促进开环步骤，其导致C-8线性二醇的显着产率（28％）。这些结果建立了在成本效益3D过渡金属基催化剂上生产生物基二醇的竞争性催化途径。

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来源
《Catalysis Communications》 |2018年第2018期|共4页
作者
Ramos Ruben; Hidalgo Jose M.; Gonel Michael; Tiser Zdenek; Bertella Francine; Martinez Agustin; Kikhtyanin Oleg; Kubicka David;
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作者单位

Unipetrol Ctr Res &

Educ UNICRE Zaluzi Litvinov 43670 Czech Republic;

Unipetrol Ctr Res &

Educ UNICRE Zaluzi Litvinov 43670 Czech Republic;

Unipetrol Ctr Res &

Educ UNICRE Zaluzi Litvinov 43670 Czech Republic;

Unipetrol Ctr Res &

Educ UNICRE Zaluzi Litvinov 43670 Czech Republic;

Univ Politecn Valencia CSIC Inst Tecnol Quim Avda Naranjos S-N E-46022 Valencia Spain;

Univ Politecn Valencia CSIC Inst Tecnol Quim Avda Naranjos S-N E-46022 Valencia Spain;

Unipetrol Ctr Res &

Educ UNICRE Zaluzi Litvinov 43670 Czech Republic;

Univ Chem &

Technol Prague Technopk Kralupy Zizkova 7 Kralupy Nad Vltavou 27801 Czech Republic;

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原文格式 PDF
正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
关键词
Furfural; Aldol condensation; Hydrogenation; SBA-15; Ni-Cu catalysts;

机译：糠醛;醛醇缩合;氢化;SBA-15;Ni-Cu催化剂;

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专利

1. Catalytic conversion of furfural-acetone condensation products into bio-derived C-8 linear alcohols over Ni-Cu/Al-SBA-15 [J] . Ramos Ruben, Hidalgo Jose M., Gonel Michael, Catalysis Communications . 2018,第期

机译：在Ni-Cu / Al-SBA-15上催化转化糠醛 - 丙酮缩合产物的生物衍生的C-8线性醇
2. Hydrogenation/Deoxygenation (H/D) Reaction of Furfural-Acetone Condensation Product using Ni/Al2O3-ZrO2 Catalyst [J] . Adam Mahfud, Siti Mariyah Ulfa, Edi Priyo Utomo The Journal of Pure and Applied Chemistry Research . 2016,第2期

机译：Ni / Al2O3-ZrO2催化剂催化糠醛丙酮缩合产物加氢/脱氧（H / D）反应
3. Catalytic conversion of levulinic acid under noncorrosive conditions using Ru/Zr/Al-SBA-15 catalysts [J] . Kumaravel Sakthivel, Thiripuranthagan Sivakumar, Erusappan Elangovan, Microporous and mesoporous materials: The offical journal of the International Zeolite Association . 2020,第1期

机译：使用Ru / Zr / Al-SBA-15催化剂在非腐蚀性条件下催化转化乙酰酸
4. Catalytic conversion of furfural to furfuryl alcohol over ruthenium based catalysts [C] . Sudiyarmanto Sudiyarmanto, Fauzan Aulia, Fauzul Adzim, International Symposium on Applied Chemistry . 2018

机译：用钌基催化剂催化转化糠醛在糠醇中的催化剂
5. Catalytic conversion of glycerol and sugar alcohols to value-added products [D] . Dasari, Mohanprasad A. 2006

机译：甘油和糖醇的催化转化为增值产品
6. Product Control and Insight into Conversion of C6 Aldose Toward C2 C4 and C6 Alditols in One‐Pot Retro‐Aldol Condensation and Hydrogenation Processes [O] . Yingshuang Hui, Dr. Yulu Zhan, Wenrong Hou, 2021

机译：产品控制和洞察C6醛糖转化为C2C4和C6 Alditol在一锅中的一种锅中的缩合和氢化过程中
7. Hydrogenation/Deoxygenation (H/D) Reaction of Furfural-Acetone Condensation Product using Ni/Al2O3-ZrO2 Catalyst [O] . Adam Mahfud, Siti Mariyah Ulfa, Edi Priyo Utomo 2016

机译：使用Ni / Al2O3-ZrO2催化剂的糠醛 - 丙酮缩合产物的氢化/脱氧（H / D）反应

Catalytic conversion of furfural-acetone condensation products into bio-derived C-8 linear alcohols over Ni-Cu/Al-SBA-15

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