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Synthesis of microcrystalline cellulose/TiO2/fluorine/styrene-acrylate coatings and the application for simulated paper cultural relic protection

机译:微晶纤维素/ TiO2 /氟/苯乙烯 - 丙烯酸酯涂料的合成及模拟纸张文物保护的应用

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摘要

Paper cultural relics are prone to embrittlement, yellowing, powdering, mildew and damage due to the brittleness of materials, natural deterioration, microbial corrosion, and man-made destruction. To prolong the expected life of paper cultural relics, a series of novel microcrystalline cellulose/TiO2/fluorine/styrene-acrylate coatings were prepared with modified microcrystalline cellulose, modified nano-TiO2, dodecafluoroheptyl methacrylate, and several acrylate monomers. The prepared coatings were analyzed by infrared spectroscopy, transmission electron microscopy, UV-Vis spectroscopy, and performance-testing devices. In addition, the optimized protective coatings were coated on the simulated paper cultural relic surface, and its protective effects were evaluated by tensile strength retention rate and weight loss rate. When the content of modified nano-TiO2 was 1.0 wt%, the protective coatings exhibited good hydrophobicity, oil repellency, mechanical strength, anti-aging, and reversibility.
机译:由于材料的脆性,自然恶化,微生物腐蚀和人造破坏,纸质文物易于脆化,泛黄,粉末,霉菌和损坏。为了延长纸张文物的预期寿命,用改性的微晶纤维素,改性的纳米TiO2,十二烷氟庚酰甲基丙烯酸酯制备了一系列新的微晶纤维素/ TiO 2 /氟/苯乙烯 - 丙烯酸酯涂料。通过红外光谱,透射电子显微镜,UV-VIS光谱和性能测试装置分析制备的涂层。此外,在模拟纸培养遗物表面上涂覆优化的保护涂层,通过拉伸强度保持率和减肥率来评估其保护作用。当改性纳米TiO 2的含量为1.0wt%时,保护涂层表现出良好的疏水性,防油性,机械强度,抗衰老和可逆性。

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