Iridium(1?1?1), Iridium(1?1?0), and Ruthenium(0?0?0?1) Single Crystals as Model Catalysts for the Oxygen Evolution Reaction: Insights into the Electrochemical Oxide Formation and Electrocatalytic Activity

摘要

Abstract >We report a comparative study on the influence of generic electrochemical activation–oxidation protocols on the resulting surface oxides of Ir(1?1?1) and (1?1?0) and Ru(0?0?0?1) single crystals and their electrocatalytic reactivity for the oxygen evolution reaction. Well‐defined single‐crystal electrodes were prepared in a custom‐made chamber that combines inductive thermal annealing and electrochemistry. The clean surfaces were analyzed for their electrocatalytic oxygen evolution activities and oxidation behavior. Three different oxidation protocols were used, which revealed a strong activity dependence on the duration and upper potential limit of the electrochemical oxidation. The resulting changes of the surface were followed by using cyclic voltammetry and impedance spectroscopy. Important differences between the two faces of Ir in terms of surface morphology of the formed oxide were identified, which allowed us to draw conclusions for preferable crystal faces in nanoparticle catalysts. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> 我们报告了对IR（1？1？1）的所得表面氧化物对常规电化学活化氧化方案的影响的比较研究（1？1？0）和Ru（0≤0≤0≤1 ）单晶及其对氧气进化反应的电催化反应性。在与电感热退火和电化学结合的定制室中制备明确定义的单晶电极。分析干净的表面以用于其电催化氧进化活性和氧化行为。使用三种不同的氧化方案，揭示了对电化学氧化的持续时间和上部潜在极限的强活性依赖性。使用循环伏安法和阻抗光谱进行表面的所得变化。鉴定了所形成的氧化物的表面形态的IR的两个面之间的重要差异，使我们允许我们在纳米颗粒催化剂中为优选的晶体面得出结论。</ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-16041/'>《ChemCatChem》</a> <b style="margin: 0 2px;">|</b><span>2017年第4期</span><b style="margin: 0 2px;">|</b><span>共7页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1186.html" title="物理化学（理论化学）、化学物理学">物理化学（理论化学）、化学物理学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=iridium&option=203" rel="nofollow">iridium;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=oxidation&option=203" rel="nofollow">oxidation;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=ruthenium&option=203" rel="nofollow">ruthenium;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=surface chemistry&option=203" rel="nofollow">surface chemistry;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=water splitting&option=203" rel="nofollow">water splitting;</a> </p> <div class="translation"> 机译：铱;氧化;钌;表面化学;水分裂; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704022056781.html">Iridium(1?1?1), Iridium(1?1?0), and Ruthenium(0?0?0?1) Single Crystals as Model Catalysts for the Oxygen Evolution Reaction: Insights into the Electrochemical Oxide Formation and Electrocatalytic Activity</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> </a> <a href="/journal-foreign-16041/" target="_blank" rel="nofollow" class="tuijian_authcolor">ChemCatChem .</a> <span>2017</span><span>,第4期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：铱（1？1？1），铱（1？1？0），钌（0≤0→0≤1）单晶作为氧气进化反应的模型催化剂：洞察电化学氧化物形成和电催化活性</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/070403023766.html">Electrochemical activity of ruthenium and iridium based catalysts for oxygen evolution reaction</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=N.Mamaca&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">N.Mamaca,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=E.Mayousse&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">E.Mayousse,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=S. 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href="/patent-detail/06130424988305.html">IMMOBILIZED RHODIUM (III), RUTHENIUM (II), OR IRIDIUM (III) CATALYSTS FOR ASYMMETRIC HYDROGENATION REACTIONS</a> <b>[P]</b> . <span> 外国专利：  WO2011026682A1 </span> <span> . 2011-03-10</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：用于不对称加氢反应的固定化铑（III），钌（II）或铱（III）催化剂 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704022056781','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" 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