Vacuum Electrochemistry Approach to Investigate Electrical Double-Layer Capacitances of Ionic Liquid for Epitaxial Thin-Film Electrodes of TiO(2)and SrO on Niobium-Doped (001)SrTiO3

Takahashi Chika; Kanai Mariko; Maruyama Shingo; Matsumoto Yuji

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Vacuum Electrochemistry Approach to Investigate Electrical Double-Layer Capacitances of Ionic Liquid for Epitaxial Thin-Film Electrodes of TiO(2)and SrO on Niobium-Doped (001)SrTiO3

机译：真空电化学方法研究铌掺杂（001）SRTIO3上外延薄膜电极离子液体液体液体液体电化学型电容

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The Cover Featureillustrates a new potentiality of vacuum electrochemistry approach to investigate well-defined ionic liquid/oxide interfaces when vacuum electrochemistry meets pulsed laser deposition (PLD). The electric double layer (EDL) capacitance of ionic liquid is carefully investigated under vacuum for oxide electrodes of not only single-crystal SrTiO3, but also the subsequently PLD-grown SrO and anatase TiO(2)epitaxial films. The direct comparison of these EDL capacitance values allows us to find out that the EDL capacitance is quite sensitive to the kinds of oxide interfaces; the ionicity of the oxides is proposed as a possible key to the interpretation of the present finding. More information can be found in theArticle by C. Takahashi et al.

机译：该封面是真空电化学方法的新潜力，以研究真空电化学符合脉冲激光沉积（PLD）时的良好定义的离子液/氧化物界面。在不仅单晶SrTiO3的氧化物电极真空下仔细研究了离子液体的电双层（EDL）电容，还在氧化物电极下进行氧化物电极，而是随后的PLD生长的SRO和锐钛矿TiO（2）外延薄膜。这些EDL电容值的直接比较允许我们了解EDL电容对氧化物界面种类非常敏感; 提出氧化物的离子性作为对本发现的解释的可能关键。通过C. Takahashi等，可以在Thearticle中找到更多信息。

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来源
《ChemElectroChem》 |2020年第15期|共7页
作者
Takahashi Chika; Kanai Mariko; Maruyama Shingo; Matsumoto Yuji;
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作者单位

Tohoku Univ Dept Appl Chem Sch Engn Aoba Ku 6-6-07 Aramaki Aza Aoba Sendai Miyagi 9808579 Japan;

Tohoku Univ Dept Appl Chem Sch Engn Aoba Ku 6-6-07 Aramaki Aza Aoba Sendai Miyagi 9808579 Japan;

Tohoku Univ Dept Appl Chem Sch Engn Aoba Ku 6-6-07 Aramaki Aza Aoba Sendai Miyagi 9808579 Japan;

Tohoku Univ Dept Appl Chem Sch Engn Aoba Ku 6-6-07 Aramaki Aza Aoba Sendai Miyagi 9808579 Japan;

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原文格式 PDF
正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
关键词
ionic liquids; electrical double layer; oxide electrodes; vacuum electrochemistry; pulsed laser deposition;

机译：离子液体;电双层;氧化物电极;真空电化学;脉冲激光沉积;

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1. Vacuum Electrochemistry Approach to Investigate Electrical Double-Layer Capacitances of Ionic Liquid for Epitaxial Thin-Film Electrodes of TiO(2)and SrO on Niobium-Doped (001)SrTiO3 [J] . Takahashi Chika, Kanai Mariko, Maruyama Shingo, ChemElectroChem . 2020,第15期

机译：真空电化学方法研究铌掺杂（001）SRTIO3上外延薄膜电极离子液体液体液体液体电化学型电容
2. Room-Temperature Ionic Liquids: Excluded Volume and Ion Polarizability Effects in the Electrical Double-Layer Structure and Capacitance [J] . Y. Lauw, M. D. Home, T. Rodopoulos, Physical review letters . 2009,第11期

机译：室温离子液体：双层电子结构和电容中体积和离子极化率的影响
3. In Situ Wettability Characterization of Chemically Heterogeneous Surfaces Probed by Ionic Liquid Contact Angle in Vacuum: Pentacene on Single-Crystal SrTiO3(001) [J] . Kinoshita Takuya, Maruyama Shingo, Matsumoto Yuji The journal of physical chemistry, C. Nanomaterials and interfaces . 2018,第15期

机译：在真空中离子液体接触角探测的化学异质表面的原位润湿性表征：单晶SRTIO3（001）上的五烯烯
4. Room-Temperature Ionic Liquids: Excluded Volume and Ion Polarizability Effects in the Electrical Double-Layer Structure and Capacitance [O] . Lauw Y, Horne MD, Rodopoulos T, 2012

机译：室温离子液体：双层电子结构和电容中体积和离子极化率的影响

Vacuum Electrochemistry Approach to Investigate Electrical Double-Layer Capacitances of Ionic Liquid for Epitaxial Thin-Film Electrodes of TiO(2)and SrO on Niobium-Doped (001)SrTiO3

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