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Thermo-chemical conversion of biomass and upgrading to biofuel: The Thermo-Catalytic Reforming process - A review

机译:生物质热化学转化与生物燃料升级:热催化重整过程 - 综述

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摘要

Thermo-catalytic reforming (TCR (R)) is a promising conversion technology for the production of liquid bio-fuels. The process is a proven opportunity to convert biological wastes and residues into hydrogen-rich syngas, high-quality oil, and char without volatiles. Bio-oil produced from TCR (R) has a high carbon content, low water content, low oxygen content, and a high heating value; it is therefore directly applicable as feed in boilers or as blend in dual fuel engines. A feasible opportunity for using bio-oil in automotive combustion engines is a further upgrade step to bio-fuel by hydrogenation. During this hydrotreatment, heterogeneous atoms like sulfur, nitrogen, and oxygen are removed or substituted with hydrogen. Fraunhofer UMSICHT already produces gasoline and diesel that comply with European fuel standards EN 228 and EN 590, using different catalysts like NiMo/Al2O3, CoMo/Al2O3, and Ru/C for hydrogenation at 643 K and a constant hydrogen pressure of 14 MPa. Various hydrocarbons and benzene derivatives are verified after hydrotreating. (c) 2019 Society of Chemical Industry and John Wiley & Sons, Ltd.
机译:热催化重整(TCR(R))是用于生产液体生物燃料的有前途的转换技术。该过程是将生物废物和残留物转化为富含氢的合成气,高质量的油和炭而没有挥发物的过程。由TCR(R)产生的生物油具有高碳含量,低含水量,低氧含量和高加热值;因此,它直接适用于锅炉的饲料或双燃料发动机中的混合物。在汽车燃烧发动机中使用生物油的可行机会是通过氢化进一步升级生物燃料的步骤。在这种加氢处理期间,除去硫,氮和氧气等异质原子被除去或被氢取代。 Fraunhofer Umsicht已经生产汽油和柴油,符合欧洲燃料标准EN 228和EN 590,使用Nimo / Al2O3,Como / Al2O3和Ru / C等不同的催化剂,用于在643k下氢化和14MPa的恒定氢气压力。在加氢处理后验证各种烃和苯衍生物。 (c)2019化学工业协会和约翰瓦里和儿子有限公司

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