Kinetic Modeling of Rhodium‐Catalyzed Reductive Amination of Undecanal in Different Solvent Systems

Kirschtowski Sabine; Kadar Christof; Seidel‐Morgenstern Andreas; Hamel Christof

摘要

Abstract >The homogenously rhodium‐catalyzed reductive amination of 1‐undecanal was performed in two different thermomorphic solvent systems with the ligand Xantphos. The influences of partial pressure, temperature, methanol and catalyst concentration on the reaction were investigated. Based on a network analysis a kinetic model was derived and successfully parametrized for all studied solvent systems. Simulation results were found to be in good agreement with the experiments and allow a further process development and optimization. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> >在具有配体Xantphos的两种不同的热晶体溶剂体系中进行1-未甲烷的均匀铑催化的还原胺化。研究了分压，温度，甲醇和催化剂浓度对反应的影响。基于网络分析，为所有研究的溶剂系统推导出和成功参数化了动力学模型。发现仿真结果与实验一致，允许进一步的过程开发和优化。</ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-16114/'>《Chemie-Ingenieur-Technik: Verfahrenstechnik Technische Chemie Apparatewesen Biotechnologie》</a> <b style="margin: 0 2px;">|</b><span>2020年第5期</span><b style="margin: 0 2px;">|</b><span>共7页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kirschtowski Sabine&option=202" target="_blank" rel="nofollow">Kirschtowski Sabine;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kadar Christof&option=202" target="_blank" rel="nofollow">Kadar Christof;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Seidel‐Morgenstern Andreas&option=202" target="_blank" rel="nofollow">Seidel‐Morgenstern Andreas;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Hamel Christof&option=202" target="_blank" rel="nofollow">Hamel Christof;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Institute of Process EngineeringOtto von Guericke University MagdeburgUniversit?tsplatz 2 39106 Magdeburg Germany;</p> <p>Faculty of Applied ChemistryNuremberg Institute of TechnologyKe?lerplatz 12 90489 Nuremberg Germany;</p> <p>Institute of Process EngineeringOtto von Guericke University MagdeburgUniversit?tsplatz 2 39106 Magdeburg Germany;</p> <p>Institute of Process EngineeringOtto von Guericke University MagdeburgUniversit?tsplatz 2 39106 Magdeburg Germany;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/238.html" title="化学工业">化学工业;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Homogenous catalysis&option=203" rel="nofollow">Homogenous catalysis;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kinetic modeling&option=203" rel="nofollow">Kinetic modeling;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Reductive amination&option=203" rel="nofollow">Reductive amination;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Rhodium catalysis&option=203" rel="nofollow">Rhodium catalysis;</a> </p> <div class="translation"> 机译：均匀催化;动力学建模;还原胺化;铑催化; 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href="/journal-cn-7573/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 南京工业大学学报（自然科学版） </a> </span> <span> . 2014</span><span>,第004期</span> </span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chinese-journal-catalysis_thesis/0201231570444.html">铑（III）催化的醛的氧化胺化：一种有效的构建N-吡啶酰胺及酰亚胺的合成方法</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=代伟&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 代伟</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘玉臣&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,刘玉臣</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=童涛&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,童涛</a> <span> <a href="/journal-cn-28399/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 催化学报 </a> </span> <span> . 2014</span><span>,第007期</span> </span> 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