Selective Oxidation of Methane with Hydrogen Peroxide Towards Formic Acid in a Micro Fixed‐Bed?Reactor

Zuo Hualiang; Meynen Vera; Klemm Elias

摘要

Abstract > Selective oxidation of methane by using aqueous hydrogen peroxide solution as oxidant was investigated. Colloidal nanosized Cu‐Fe‐silicalite‐1 was prepared and a micro reactor was used to intensify mass transport. It was found that the oxygenate productivity could be enhanced nearly three orders of magnitude while simultaneously ensuring high turn‐over‐frequencies of some 100h -1 . However, the main product in liquid phase was not methanol, but formic acid. At optimized reaction conditions, a selectivity to formic acid of 96.7% at a methane conversion of 10.3% could be achieved. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract XMLNS =“http://www.wiley.com/namespaces/wiley”type =“main”xml：lang =“en”> <title type =“main”>抽象</ title> >选择性氧化研究了作为氧化剂的过氧化氢水溶液作为氧化剂的甲烷。制备胶体纳米型Cu-Fe-硅锂-1，并使用微反应器加强质量转运。发现含氧化生产率可以增强近三个数量级，同时确保大约100h -1 / sup>的高逆转频率。然而，液相中的主要产物不是甲醇，但甲酸。在优化的反应条件下，可以实现对甲烷转化率为9.6％的甲酸的甲酸的选择性。 </ p> </ abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-16114/'>《Chemie-Ingenieur-Technik: Verfahrenstechnik Technische Chemie Apparatewesen Biotechnologie》</a> <b style="margin: 0 2px;">|</b><span>2017年第12期</span><b style="margin: 0 2px;">|</b><span>共7页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zuo Hualiang&option=202" target="_blank" rel="nofollow">Zuo Hualiang;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Meynen Vera&option=202" target="_blank" rel="nofollow">Meynen Vera;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Klemm Elias&option=202" target="_blank" rel="nofollow">Klemm Elias;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Faculty of ChemistryUniversity of Stuttgart Institute of Chemical TechnologyPfaffenwaldring 55 70569 Stuttgart Germany;</p> <p>Laboratory of Adsorption and CatalysisUniversity of AntwerpUniversiteitsplein 1 2610 Wilrijk Belgium;</p> <p>Faculty of ChemistryUniversity of Stuttgart Institute of Chemical TechnologyPfaffenwaldring 55 70569 Stuttgart Germany;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/238.html" title="化学工业">化学工业;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Formic acid&option=203" rel="nofollow">Formic acid;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Micro fixed‐bed reactor&option=203" rel="nofollow">Micro fixed‐bed reactor;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Selective oxidation&option=203" rel="nofollow">Selective oxidation;</a> </p> <div class="translation"> 机译：甲酸;微固定床反应器;选择性氧化; 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