Polynorbornene-based Template for Polymer Synthesis

Lai Guoqiao; Luh Tien-Yau

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Polynorbornene-based Template for Polymer Synthesis

机译：基于多毒树脂合成的基于聚冰片烯的模板

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The recent advances in the use of rigid polynorbornene or polycyclobutene as template for the synthesis of different polymers with well-defined degree of polymerization and narrow polydispersity are reviewed. Polynorbornene and polycyclobutene templates containing fused N-arylpyrrolidene pendants are synthesized by ruthenium or molybdenum-catalyzed ring opening metathesis polymerization (ROMP) of the corresponding monomers. Since these polymerizations are living, the templates thus have well-defined degree of polymerization and narrow polydispersity. Monomers are linked to the template polymer via ester linkage. After polymerization and hydrolysis, the poly-carboxylic acid template can easily be separated from the neutral polyalcohol daughter polymer.

机译：综述了使用刚性多环烯烃或多环丁烯作为用于合成具有明确定义的聚合程度和窄多分散性的不同聚合物的模板的近期进步。含有稠合的N-芳基吡咯烷侧掺杂剂的多环烯和多环丁烯模板由钌或钼催化的环开口复分解聚合（ROMP）合成相应单体。由于这些聚合为生存，因此模板因此具有明确定义的聚合度和窄的多分散性。单体通过酯连杆与模板聚合物连接。聚合和水解后，聚 - 羧酸模板可以容易地与中性多元醇女儿聚合物分离。

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《Bulletin of the Chemical Society of Japan》 |2018年第2期|共12页
作者
Lai Guoqiao; Luh Tien-Yau;
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作者单位

Hangzhou Normal Univ Key Lab Organosilicon Chem &

Mat Technol Minist Educ Hangzhou 311121 Zhejiang Peoples R China;

Natl Taiwan Univ Dept Chem Taipei 106 Taiwan;

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正文语种 eng
中图分类化学;
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1. Polynorbornene-based Template for Polymer Synthesis [J] . Lai Guoqiao, Luh Tien-Yau Bulletin of the Chemical Society of Japan . 2018,第2期

机译：基于多毒树脂合成的基于聚冰片烯的模板
2. Azlactone-functionalized polymers as reactive templates for parallel polymer synthesis: synthesis and screening of a small library of cationic polymers in the context of DNA delivery [J] . Bin Sun, Xianghui Liu, Maren E. Buck, Chemical Communications . 2010,第12期

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3. Unsymmetrical Polymeric Ladderphanes by Sequential Polymerization: A New Approach for the Template Synthesis of Polymers with Well-Defined Chain Length and Narrow Polydispersity [J] . Yuan-Zhen Ke, Shern-Long Lee, Chun-hsien Chen, Chemistry, an Asian journal . 2011,第7期

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4. Synthesis of Poly (vinyl acetate) Based Amphiphilic Surfactant by RAFT/ATRP Polymerization and Preparation Macroporous Materials by Emulsion-templating Polymerization [C] . S.C.Zhang, W.Luo, B.E.Tan Proceedings of the Sixth Asia-Europe symposium on processing and properties of reinforced polymers . 2013

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5. Nonenzymatic oligomerization of RNA by TNA templates, and, Isoguanine-modified thrombin aptamers, and, An antiparallel purine·purine DNA duplex, and, Synthesis and enzymatic polymerization of FNA on DNA templates, and, Thermodynamics and luminescence of novel metallo-DNA base-pairs. [D] . Heuberger, Benjamin David. 2007

机译：TNA模板，异鸟嘌呤修饰的凝血酶适体，反平行嘌呤·嘌呤DNA双链体以及FNA在DNA模板上的合成和酶促聚合，以及新型金属DNA碱基的热力学和发光，通过RNA的非酶促寡聚化对。
6. Azlactone-Functionalized Polymers as Reactive Templates for Parallel Polymer Synthesis: Synthesis and Screening of a Small Library of Cationic Polymers in the Context of DNA Delivery [O] . Bin Sun, Xianghui Liu, Maren E. Buck, -1

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7. Combination of template polymerization and atom transfer radical polymerization: Strategy for synthesis of specifically structural polymers [O] . Saito Reiko 2008

机译：模板聚合和原子转移自由基聚合的结合：特殊结构聚合物的合成策略

Polynorbornene-based Template for Polymer Synthesis

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