Aerobic Oxidation of Sulfides to Sulfoxides Catalyzed by Gold/Manganese Oxides

Taketoshi Ayako; Concepcion Patricia; Garcia Hermenegildo; Corma Avelino; Haruta Masatake

首页> 外文期刊>Bulletin of the Chemical Society of Japan >Aerobic Oxidation of Sulfides to Sulfoxides Catalyzed by Gold/Manganese Oxides

【24h】

Aerobic Oxidation of Sulfides to Sulfoxides Catalyzed by Gold/Manganese Oxides

机译：通过金/锰氧化物催化的硫化亚硫化物的有氧氧化

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Although selective oxidation of sulfides to sulfoxides with molecular oxygen is a difficult reaction due to the overoxidation to sulfone, manganese oxides were found to catalyze the aerobic oxidation of sulfides to sulfoxides in 1,2-dichlorobenzene at 100 degrees C with a high selectivity above 99%. The catalytic activity depends on the preparation methods and conditions of manganese oxides but not on the valences of manganese. The deposition of Pd and Pt on manganese oxides was detrimental, whereas the deposition of Au enhanced the catalytic activity and selectivity.

机译：虽然具有分子氧的选择性氧化硫化物与亚砜，但由于砜的过度氧化，发现锰氧化物在100℃下以高于99的选择性催化在1,2-二氯苯中硫化物中的硫化物氧化在亚砜中。％。催化活性取决于锰氧化物的制备方法和条件，但不是锰的级。 Pd和Pt在锰氧化物上的沉积是有害的，而Au的沉积增强了催化活性和选择性。

著录项

来源
《Bulletin of the Chemical Society of Japan》 |2013年第12期|共7页
作者
Taketoshi Ayako; Concepcion Patricia; Garcia Hermenegildo; Corma Avelino; Haruta Masatake;
展开▼
作者单位

Tokyo Metropolitan Univ Dept Appl Chem Grad Sch Urban Environm Sci Hachioji Tokyo 1920397 Japan;

Univ Politecn Valencia Consejo Super Invest Cient Inst Tecnol Quim Valencia 46022 Spain;

Univ Politecn Valencia Consejo Super Invest Cient Inst Tecnol Quim Valencia 46022 Spain;

Univ Politecn Valencia Consejo Super Invest Cient Inst Tecnol Quim Valencia 46022 Spain;

Tokyo Metropolitan Univ Dept Appl Chem Grad Sch Urban Environm Sci Hachioji Tokyo 1920397 Japan;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;
关键词

相似文献

外文文献
中文文献
专利

1. Aerobic Oxidation of Sulfides to Sulfoxides Catalyzed by Gold/Manganese Oxides [J] . Taketoshi Ayako, Concepcion Patricia, Garcia Hermenegildo, Bulletin of the Chemical Society of Japan . 2013,第12期

机译：通过金/锰氧化物催化的硫化亚硫化物的有氧氧化
2. Metal-Free Highly Efficient Aerobic Oxidation of Sulfides to Sulfoxides Catalyzed by DBDMH/TBN/H₂O [J] . Hua Zhang, Renhua Liu Synthetic Communications: An International Journal for Rapid Communication of Synthetic Organic Chemistry . 2012,第6期

机译：DBDMH / TBN / H _{2 O催化硫化物的无金属高效好氧氧化为亚砜}
3. Metal-free highly efficient aerobic oxidation of sulfides to sulfoxides catalyzed by DBDMH/TBN/H _2O [J] . Zhang H., Chen C., Liu R. Synthetic Communications . 2012,第4a6期

机译：DBDMH / TBN / H _2O催化的无金属高效好氧将硫化物好氧氧化为亚砜
4. Highly Efficient and Selective Aerobic Oxidation of Sulfides to Sulfoxides With Br2/NaNO2 /O2 in water [C] . Hong-Jiao Ma, Yong-Hui Hu, Hai-Bo Yuan, Joint China/Japan chemical engineering symposium;CJCES . 2007

机译：水中Br2 / NaNO2 / O2选择性高效地将硫化物好氧氧化为亚砜。
5. Sulfoxides as an intramolecular sulfenylating agent for indoles and diverse applications of the sulfide-sulfoxide redox cycle in organic chemistry. [D] . Jog, Parag V. 2005

机译：亚砜作为吲哚的分子内亚磺化剂，并且在有机化学中具有多种用途。
6. Tertiary amine mediated aerobic oxidation of sulfides into sulfoxides by visible-light photoredox catalysis on TiO2 [O] . Xianjun Lang, Wei Hao, Wan Ru Leow, 2015

机译：TiO2上可见光氧化还原催化叔胺介导的硫化物好氧氧化为亚砜
7. New ligands for manganese catalysed selective oxidation of sulfides to sulfoxides with hydrogen peroxide [O] . Brinksma J., La Crois R.M., Feringa B.L., 2001

机译：锰与过氧化氢催化硫化物选择性氧化为亚砜的新配体

Aerobic Oxidation of Sulfides to Sulfoxides Catalyzed by Gold/Manganese Oxides

摘要

著录项

相似文献

相关主题

期刊订阅