A Useful and Convenient Synthetic Protocol for Iodination of Organic Substrates Using a Combination of Vanadyl Acetylacetonate, Hydrogen Peroxide, and Sodium Iodide

Khan Abu T.; Ali Shahzad

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A Useful and Convenient Synthetic Protocol for Iodination of Organic Substrates Using a Combination of Vanadyl Acetylacetonate, Hydrogen Peroxide, and Sodium Iodide

机译：一种有用且方便的合成方案，用于使用乙酰丙酮烷基丙酯，过氧化氢和碘化钠组合的组合碘化

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摘要

A wide variety of organic substrates can be iodinated selectively in good yields by employing a combination of vanadyl acetylacetonate, hydrogen peroxide, and sodium iodide at ice-bath temperature. Good yield, selectivity, use of cost effective reagents, and mild and environmentally benign reaction conditions are some of the major advantages of this protocol.

机译：通过在冰浴温度下使用乙酰丙酮酸酯，过氧化氢和碘化钠的组合，可以良好地有机基质可选择地是良好的产率。良好的产量，选择性，具有成本效益的试剂，以及轻度和环境良性反应条件是本协议的一些主要优势。

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《Bulletin of the Chemical Society of Japan》 |2012年第11期|共5页
作者
Khan Abu T.; Ali Shahzad;
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Indian Inst Technol Guwahati Dept Chem Gauhati 781039 India;

Indian Inst Technol Guwahati Dept Chem Gauhati 781039 India;

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正文语种 eng
中图分类化学;
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1. A Useful and Convenient Synthetic Protocol for Iodination of Organic Substrates Using a Combination of Vanadyl Acetylacetonate, Hydrogen Peroxide, and Sodium Iodide [J] . Khan Abu T., Ali Shahzad Bulletin of the Chemical Society of Japan . 2012,第11期

机译：一种有用且方便的合成方案，用于使用乙酰丙酮烷基丙酯，过氧化氢和碘化钠组合的组合碘化
2. Sodium sulfate-hydrogen peroxide-sodium chloride adduct: selective protocol for the oxidative bromination, iodination and temperature dependent oxidation of sulfides to sulfoxides and sulfones [J] . Gayakwad Eknath M., Patel Khushbu P., Shankarling Ganapati S. New Journal of Chemistry . 2019,第15期

机译：硫酸钠 - 过氧化钠 - 氯化钠加合：用于氧化溴化，碘化和温度依赖性氧化亚硫醚和砜的选择性方案
3. Selenoxides as Catalysts for the Activation of Hydrogen Peroxide.Bromination of Organic Substrates with Sodium Bromide and Hydrogen Peroxide [J] . Margaret A.Goodman, Michael R.Detty Organometallics . 2004,第12期

机译：硒氧化物作为过氧化氢活化的催化剂。溴化钠和过氧化氢对有机底物的溴化作用
4. Sodium iodide: a Trigger for Hypergolic Ignition of Non-Toxic Fuels with Hydrogen Peroxide [C] . Vikas K. Bhosale, Kyu-Seop Kim, Sejin Kwon, Propulsion and Energy Forum . 2020

机译：碘化钠：用过氧化氢的无毒燃料的高胆型点火的触发
5. Copper-induced activation of dioxygen and hydrogen peroxide for the dehydrogenation and oxygenation of organic substrates [D] . Liu, Xiu 1993

机译：铜诱导的双氧和过氧化氢的活化，用于有机底物的脱氢和氧合
6. Killing of Aspergillus fumigatus spores and Candida albicans yeast phase by the iron-hydrogen peroxide-iodide cytotoxic system: comparison with the myeloperoxidase-hydrogen peroxide-halide system. [O] . S M Levitz, R D Diamond 1984

机译：铁-过氧化氢-碘化物的细胞毒性系统杀死烟曲霉孢子和白色念珠菌酵母相：与髓过氧化物酶-过氧化氢-卤化物系统比较。
7. Selenoxides as Catalysts for the Activation of Hydrogen Peroxide. Bromination of Organic Substrates with Sodium Bromide and Hydrogen Peroxide [O] . -1

机译：Selenoxides作为激活过氧化氢的催化剂。用溴化钠和过氧化氢溴化有机底物的溴化
8. Reactions Involving Hydrogen Peroxide, Iodine, and Iodate Ion. 6. Oxidation of Iodine by Hydrogen Peroxide at 50 deg C. [R] . Liebhafsky, H. A., McGavock, W. C., Reyes, R. J., 1977

机译：涉及过氧化氢，碘和碘酸根离子的反应。 6.过氧化氢在50℃下氧化碘

A Useful and Convenient Synthetic Protocol for Iodination of Organic Substrates Using a Combination of Vanadyl Acetylacetonate, Hydrogen Peroxide, and Sodium Iodide

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