Complex Formation of Cyclodextrins with a Dumbbell Molecule Bearing Two Ferrocene Moieties at the Ends

Yamamoto Takaya; Oi Wataru; Hashidzume Akihito; Harada Akira

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Complex Formation of Cyclodextrins with a Dumbbell Molecule Bearing Two Ferrocene Moieties at the Ends

机译：具有哑铃分子的复杂形成环骨分子在两端携带两个二茂铁部分

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The complexation behavior of cyclodextrins (CDs) with a dumbbell molecule possessing ferrocene (Fe) moieties at both the ends (FcC10Fc) was investigated by H-1 NMR, two-dimensional rotating frame Overhauser spectroscopy, circular dichroism spectroscopy, and cyclic voltammetry. alpha-CD includes the cyclopentadienyl rings of the Fe moiety shallowly from the wider side but not the decamethylene (C10) moiety, whereas beta-CD and gamma-CD include not only the Fe moiety but also the C10 moiety. These observations indicate that the Fe moiety can pass through beta-CD and gamma-CD cavities but not the alpha-CD cavity.

机译：通过H-1 NMR，二维旋转框架掺杂器光谱，圆形二色光谱和循环伏安，研究了在两端（FCC10FC）的哑铃分子具有具有二茂铁（Fe）部分的哑铃分子的环糊精（Cds）的络合行为。 α-CD包括Fe部分的环戊二烯基环，浅侧，而不是甲甲基（C10）部分，而β-CD和γ-CD不仅包括Fe部分，而且包括C10部分。这些观察结果表明Fe部分可以通过β-CD和γ-CD腔，但不是α-CD腔。

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来源
《Bulletin of the Chemical Society of Japan》 |2011年第9期|共8页
作者
Yamamoto Takaya; Oi Wataru; Hashidzume Akihito; Harada Akira;
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Osaka Univ Dept Macromol Sci Grad Sch Sci Osaka 5600043 Japan;

Osaka Univ Dept Macromol Sci Grad Sch Sci Osaka 5600043 Japan;

Osaka Univ Dept Macromol Sci Grad Sch Sci Osaka 5600043 Japan;

Osaka Univ Dept Macromol Sci Grad Sch Sci Osaka 5600043 Japan;

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正文语种 eng
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1. Complex Formation of Cyclodextrins with a Dumbbell Molecule Bearing Two Ferrocene Moieties at the Ends [J] . Yamamoto Takaya, Oi Wataru, Hashidzume Akihito, Bulletin of the Chemical Society of Japan . 2011,第9期

机译：具有哑铃分子的复杂形成环骨分子在两端携带两个二茂铁部分
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4. Multiple thermo-responsiveness derived from supra-molecularcomplex formation between TADDOL moieties of polymer sidechains and a guest molecule [C] . Masami Naya, Kenta Kokado, KazukiSada 日本化学会春季年会 . 2020

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5. Part I. Docking calculations on the complexation of ferrocenes with cyclodextrins. Part II. SHADOW. A FORTRAN program for the calculation of molecular area. Application to monolayer packing. Part III. The synthesis and MM2 conformational analysis of a series of rigid and semi-rigid hydroxy olefins [D] . Sherrod, Michael Joseph 1989

机译：第一部分。二茂铁与环糊精络合的对接计算。第二部分阴影。用于分子面积计算的FORTRAN程序。适用于单层包装。第三部分一系列刚性和半刚性羟基烯烃的合成和MM2构象分析
6. Chiral recognition of ephedrine: Hydrophilic polymers bearing β-cyclodextrin moieties as chiral sensitive host molecules [O] . Sabrina Gingter, Helmut Ritter 2011

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8. Synthesis and Reactivity of Cobalt(III) Complexes Bearing Primary- and Secondary-Side Cyclodextrin Binding Sites [R] . Akkaya, E. U., Czarnik, A. W. 1988

机译：含有一级和二级环糊精结合位点的钴（III）配合物的合成和反应性

Complex Formation of Cyclodextrins with a Dumbbell Molecule Bearing Two Ferrocene Moieties at the Ends

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