Observation of Halide-Induced Conformational Conversion of Dinuclear Copper Complexes Having a Tetradentate Polypyridine Ligand with a p-Xylene Backbone

Takanori Nishioka; Shigeru Mitsui; Isamu Kinoshita

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Observation of Halide-Induced Conformational Conversion of Dinuclear Copper Complexes Having a Tetradentate Polypyridine Ligand with a p-Xylene Backbone

机译：用对二甲苯骨架具有四元萘吡啶配体的二核铜配合物的卤化物诱导的构象转化

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A dinucleating ligand consisting of thiopyridyl groups appended to a p-xylene backbone reacts with copper(I) halides to afford dinuclear copper complexes with terminal halogeno ligands,which are in equilibrium with bridging halogeno dicopper complexes formed by rearrangement and loss one of the terminal halogeno ligands.The identity of the products was confirmed by using 1HNMR spectroscopy,electrospray ionization mass spectrometry,and X-ray structure analyses.

机译：由附着在对二甲苯骨架上的硫吡啶基组成的二甲骨种配体与铜（I）卤化物反应，得到用末端卤素配体的二核铜配合物，其在通过重新排列和丧失终端卤素中的一种桥接卤素二射络合物的平衡配体通过使用1HNMR光谱，电喷雾电离质谱和X射线结构分析来确认产品的身份。

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《Bulletin of the Chemical Society of Japan》 |2007年第7期|共11页
作者
Takanori Nishioka; Shigeru Mitsui; Isamu Kinoshita;
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作者单位

Department of Material Science Graduate School of Science Osaka City University Sugimoto Sumiyoshi-ku Osaka 558-8585;

Department of Chemistry Faculty of Science Nara Women's University Kitauoya-higashi-machi Nara 630-8285;

Division of Chemistry Graduat;

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正文语种 eng
中图分类化学;
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1. Observation of Halide-Induced Conformational Conversion of Dinuclear Copper Complexes Having a Tetradentate Polypyridine Ligand with a p-Xylene Backbone [J] . Takanori Nishioka, Shigeru Mitsui, Isamu Kinoshita Bulletin of the Chemical Society of Japan . 2007,第7期

机译：用对二甲苯骨架具有四元萘吡啶配体的二核铜配合物的卤化物诱导的构象转化
2. Syntheses, structures and catalytic activities of dinuclear copper complexes with tetradentate diaminebis (phenolate) ligands [J] . Hosseini-Monfared Hassan, Soleymani-Babadi Susan, Sadighian Somayeh, Transition Metal Chemistry . 2015,第3期

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3. Mono- and Dinuclear Copper(II) and Iron(III) Complexes of a Tetradentate Bispidine-diacetate Ligand [J] . Peter Comba, Lena Daumann, Julie Lefebvre Australian Journal of Chemistry: A Journal for the Publication of Original Research in All Branches of Chemistry . 2009,第10期

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4. Control of selectivity for CO2 photoreduction using iridium orosmium complexes bearing PNNP-type tetradentate ligand [C] . Kenji Kamada, Jieun Jung, Susumu Saito 日本化学会春季年会 . 2020

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5. Synthesis and application of copper (I) and (II) complexes of monoanionic tripodal tetradentate ligands for the determination of structure-activity relationships in ATRP [D] . Goodwin, Jocelyn Marie. 2005

机译：铜（I）和（II）络合物的铜（I）和（II）复合物用于测定ATRP中结构活性关系的络合物
6. CO and O2 Binding to Pseudo-Tetradentate Ligand-Copper(I)-Complexes with a Variable N-Donor Moiety: Kinetic/Thermodynamic Investigation Reveals Ligand Induced Changes in Reaction Mechanism [O] . Heather R. Lucas, Gerald J. Meyer, Kenneth D. Karlin -1

机译：CO和O 2绑定到伪四齿配体 - 铜（I）-Complexes具有可变的N-供体部分：动力学/热力学研究揭示了反应机理配体诱导的变化
7. Dinuclear Complexes of Chiral Tetradentate Pyridyl-imine Ligands: Diastereoselectivity, Positive Cooperativity, Ligand Self Sorting Based on Chirality, and Magnetism [O] . -1

机译：双核复合物的手性四烯酸吡啶基 - 亚胺配体：基于手性的双对映选择性，积极合作，配体自我分类，以及磁性

Observation of Halide-Induced Conformational Conversion of Dinuclear Copper Complexes Having a Tetradentate Polypyridine Ligand with a p-Xylene Backbone

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