Why salty Grignard reactions fail

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Why salty Grignard reactions fail

机译：为什么咸的格子反应失败

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The mystery of why water and salt contaminants destroy organometallic reagents has been solved thanks to new research conducted by scientists at the University of Melbourne (Khairallah G.N., da Silva G., O'Hair R.A.J. Angew. Chem. Int. Ed. 2014, 53, 10979-83). OrganometaLlic compounds, such as the ubiquitous Grignard reagents, are powerful tools used to help create new organic molecules both in the laboratory and in commercial chemical plants, although careful management by the chemist is required to avoid contaminants in the reaction.

机译：由于科学家在墨尔本大学的科学家（Khairallah Gn，Da Silva G.，O'Hair Raj Angew，Chem.Int.200，为什么水和盐污染物破坏有机金属试剂的谜团已经解决了有机金属试剂。，10979-83）。有机金属化合物，如普遍存在的格子试剂，是用于帮助在实验室和商业化学植物中创建新的有机分子的强大工具，尽管化学家需要仔细管理以避免反应中的污染物。

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《Chemistry in Australia》 |2015年第decaajana期|共1页
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1. Why salty Grignard reactions fail [J] . Chemistry in Australia group Chemistry in Australia . 2015,第DecaaJana期

机译：为什么咸的格子反应失败
2. Preparations of Secondary Amines and β-Amino Esters via Additions of Grignard and Reformatsky Reagents to Imines and by One-Pot Reactions of Primary Amines, Aldehydes, and Grignards [J] . Alan R. Katritzky, Qingmei Hong, Zhijun Yang The Journal of Organic Chemistry . 1995,第11期

机译：通过将格氏试剂和Reformatsky试剂添加到亚胺上，以及通过伯胺，醛和格氏试剂的一锅反应制备仲胺和β-氨基酯
3. Cobalt-catalyzed cross-coupling reactions of alkyl halides with aryl Grignard reagents and their application to sequential radical cyclization/cross-coupling reactions [J] . Ohmiya H, Wakabayashi K, Yorimitsu H, Tetrahedron . 2006,第10期

机译：烷基卤化物与芳基格氏试剂的钴催化交叉偶联反应及其在顺序自由基环化/交叉偶联反应中的应用
4. DEVELOPMENT OF NOVEL PHOSPHONIUM IONIC LIQUID FOR GRIGNARD REACTION: IRON SALT-CATALYZED RAPID HOMOCOUPLING REACTION OF ARYL GRIGNARD REAGENTS [C] . Toshiyuki Itoh, Keisuke Kude, Akihiko Ishioka, Organic and Biology Electrochemistry Symposium in Honor of Yoshihiro Matsumura . 2008

机译：RIG反应的新型磷离子液体的开发：铁盐催化的芳基G试剂的快速同质反应
5. Mechanistic and Stereochemical Insights into the Reactions of Allylic Grignard Reagents with Carbonyl Compounds [D] . Bartolo, Nicole. 2021

机译：用羰基化合物的烯丙基格子试剂反应的机械和立体化学见解
6. Nickel-catalyzed coupling reaction of alkyl halides with aryl Grignard reagents in the presence of 13-butadiene: mechanistic studies of four-component coupling and competing cross-coupling reactions [O] . Takanori Iwasaki, Asuka Fukuoka, Wataru Yokoyama, 2018

机译：13-丁二烯存在下镍催化卤代烷与芳基格氏试剂的偶联反应：四组分偶联和竞争交叉偶联机理的研究
7. Mechanism of the Grignard Addition Reaction. XV. The Reaction of Grignard Reagents with Benzylpyridinium Chloride. [O] . Torkil Holm, Christian Simon, Salvador Mafé, 1991

机译：格氏加法反应的机制。 XV。格氏试剂与苄基吡啶氯化吡啶的反应。
8. Solvation of Pseudo – Grignard Reagents and The Kinetics of Pseudo - Grignard Reactions [R] . H. A. Wolterman 1972

机译：伪格氏试剂的溶剂化和伪格氏反应动力学

Why salty Grignard reactions fail

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