...
  • 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>ChemPlusChem >0D to 1D switching of hybrid polyoxometalate assemblies at the nanoscale by using molecular control
【24h】

0D to 1D switching of hybrid polyoxometalate assemblies at the nanoscale by using molecular control

机译：通过使用分子量控制纳米级杂交多氧化膦组件的0d至1D切换

获取原文
获取原文并翻译 | 示例
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

The control of assembly of polyoxometalates (POMs)1–3 across length scales is challenging because it requires the manipulation of molecular architecture, supramolecular interactions and the physicochemical properties of the assemblies.4,?5 In this respect, the development of novel POM-based organic/inorganic hybrids has focused on the functionality of hybrid materials with improved applications-driven performance and/or other useful physical properties in recent years.1,?2,?6 One effective pathway for the design of POM assemblies is to covalently tether functional organic components onto POMs.2,?7 For example, the incorporation of structural motifs that are responsive to external stimuli onto the POMs allows the generation of POM-containing functional hybrid materials.8 In comparison to conventional POMs, these new POM-containing hybrids involve π–π and van der Waals interactions, which play crucial roles for a better understanding of self-assembly processes and thereby the formations of novel aggregates.4,?7,?9,?10
机译：在长度尺度上对多氧化胍（POMS）1-3组装的控制是挑战性的，因为它需要操纵分子结构，超分子相互作用和组装的物理化学性质.4，在这方面，新的POM基于有机/无机杂种的杂种材料的功能集中在近年来改善的应用驱动性能和/或其他有用的物理性质的功能，如近年来，Δ2，？6用于设计POM组件的一个有效途径是共价系绳在POMS中的功能性有机组分，例如，例如，响应于POMS上的外部刺激的结构基序掺入致态型功能混合材料的产生.8与传统的POM相比，这些新的POM含有这些新的POM混合动力车涉及π-π和范德瓦尔斯相互作用，这起到了更好地理解自组装过程，从而扮演了关键的角色，从而形成了地层新的聚集体.4，？7，？9，？10

著录项

  • 来源
    《ChemPlusChem》 |2013年第10期|共4页
  • 作者

    ChenW.; MaD.; YanJ.; BoydT.; CroninL.; LongD.-L.; SongY.-F.;

  • 作者单位

    State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology;

    State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology;

    WestCHEM Department of Chemistry University of Glasgow Glasgow G12 8QQ United Kingdom;

    WestCHEM Department of Chemistry University of Glasgow Glasgow G12 8QQ United Kingdom;

    WestCHEM Department of Chemistry University of Glasgow Glasgow G12 8QQ United Kingdom;

    WestCHEM Department of Chemistry University of Glasgow Glasgow G12 8QQ United Kingdom;

    State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology;

  • 收录信息
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
  • 关键词

    azo compounds; noncovalent interactions; polyoxometalates; self-assembly; supramolecular chemistry;

    机译：偶氮化合物;非共价相互作用;多氧化物;自组装;超分子化学;

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号