Hexaethylbenzene: A Sterically Crowded Arene and Conformationally Versatile Ligand

McGlinchey Michael J.

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Hexaethylbenzene: A Sterically Crowded Arene and Conformationally Versatile Ligand

机译：六甲基苯：空心一居的芳烃和构象通用的配体

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The syntheses, structures and dynamic behaviour of hexaethylbenzene and its transition metal and main group element complexes are reviewed. Sterically protected intermediates in the metal-catalysed trimerisation of 3-hexyne to form hexaethylbenzene are described, and the organic chemistry of hexaethylbenzene and of hexamethylbenzene are compared and contrasted.

机译：综述了六甲基苯及其过渡金属和主要基团元素复合物的合成，结构和动态特征。描述了在3-己酰基形成六甲基苯的金属催化的三聚体中的间隔保护中间体，并比较六甲基苯和六甲基苯的有机化学和对比。

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来源
《ChemPlusChem》 |2018年第6期|共20页
作者
McGlinchey Michael J.;
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作者单位

Univ Coll Dublin Sch Chem Dublin 4 Ireland;

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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
alkyne trimerisations; arene ligands; electron transfer; molecular conformations; rotational barriers;

机译：炔烃整理;芳烃配体;电子转移;分子构象;旋转障碍;

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1. Hexaethylbenzene: A Sterically Crowded Arene and Conformationally Versatile Ligand [J] . McGlinchey Michael J. ChemPlusChem . 2018,第6期

机译：六甲基苯：空心一居的芳烃和构象通用的配体
2. C-H bond activation through steric crowding of normally inert ligands in the sterically crowded gadolinium and yttrium (C5Me5)(3)M complexes [J] . Evans WJ, Davis BL, Champagne TM, Proceedings of the National Academy of Sciences of the United States of America . 2006,第34期

机译：通过空间拥挤的g和钇（C5Me5）（3）M复合物中的正常惰性配体的空间拥挤来激活C-H键
3. Restricted Rotation of tert-Butyl Groups in Sterically Crowded Methylene-Functionalized Calix[4]arenes [J] . Kuno L, Biali SE Organic letters . 2009,第16期

机译：立体拥挤的亚甲基官能杯[4]芳烃中叔丁基的受限旋转
4. Ruthenocenyl Phosphine Designed as Novel Class of Phosphine-Arene Ligand: Application to Suzuki-Miyaura Reaction of Electronically and Sterically Deactivated Aryl Halides with Aryl Boronic Acids [C] . Takashi Hoshi, Taichi Nakazawa, Toshio Suzuki Symposium on Organometallic Chemistry . 2006

机译：设计为新型膦 - 芳烃配体的钌烯基膦：用芳族硼酸的电子和空间去激活的芳基卤化物的铃木 - 咪糕的反应应用
5. (eta(6)-arene)ruthenium(II) complexes containing hybrid and conformationally rigid chiral diphosphine ligands. [D] . Ghebreyessus, Kesete Yehdego. 2003

机译：（eta（6）-芳烃）钌（II）配合物，包含杂化和构象刚性的手性二膦配体。
6. C–H bond activation through steric crowding of normally inert ligands in the sterically crowded gadolinium and yttrium (C5Me5)3M complexes [O] . William J. Evans, Benjamin L. Davis, Timothy M. Champagne, 2006

机译：通过空间拥挤的g和钇（C5Me5）3M复合物中的正常惰性配体的空间拥挤来激活C–H键
7. C–H bond activation through steric crowding of normally inert ligands in the sterically crowded gadolinium and yttrium (C5Me5)3M complexes [O] . Evans, William J., Davis, Benjamin L., Champagne, Timothy M., 2006

机译：通过空间拥挤的g和钇（C5Me5）3M复合物中的正常惰性配体的空间拥挤来激活C–H键
8. Observation of Steric Conformational Effects in Hydrocarbon Adsorption and [R] . Kiskinova, M., Yates, J. T. 1995

机译：碳氢化合物吸附和吸附的空间构象效应观察

Hexaethylbenzene: A Sterically Crowded Arene and Conformationally Versatile Ligand

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