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A Combinatorial Study of Photoelectrochemical Properties of Fe-W-O Thin Films

机译:Fe-W-O薄膜光电化学性质的组合研究

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摘要

A continuous mixed Fe-W-O thin-films materials library was fabricated by means of reactive co-sputtering from elemental iron and tungsten targets in argon/oxygen. The materials library was screened for its local photoelectrochemical properties by using an automated optical scanning droplet cell. Local scanning electron microscopy (SEM) and electron-dispersive Xray spectroscopy (EDX) measurements of the materials library were performed to correlate the composition, morphology, and photocurrents. The iron content was varied in the range from Fe32W68Ox to Fe81W19Ox. A strong dependence of the film morphology and the measured photocurrents on the composition was observed with a maximal photocurrent from a measurement area containing 55 at% iron. The most photoactive area showed a porous structure with a high surface area. The bandgap values of these materials were assessed by photocurrent spectroscopy and showed a systematic variation of the bandgap values with the composition.
机译:通过在氩/氧中的元素铁和钨靶标的反应性共溅射制造连续的混合Fe-W-O薄膜材料文库。 通过使用自动光学扫描液滴电池筛选材料文库的局部光电化学性质。 进行局部扫描电子显微镜(SEM)和电子分散X射线光谱(EDX)物料库的测量,以与组合物,形态和光电流相关联。 铁含量在Fe32w68ox至Fe81w19ox的范围内变化。 薄膜形态和测量的光电流对组合物上的强烈依赖性,用最大光电流从含有55at%铁的测量区域的最大光电流。 最光敏的区域显示出具有高表面积的多孔结构。 通过光电流光谱评估这些材料的带隙值,并显示出与组合物的带隙值的系统变化。

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