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Synthesis of zeolitic imidazolate framework-7 in a water/ethanol mixture and its ethanol-induced reversible phase transition

机译:在水/乙醇混合物中合成沸石咪唑酯骨架-7及其乙醇诱导的可逆相转变

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摘要

Soft porous crystals have emerged as an intriguing class of hybrid nanoporous crystalline materials as they exhibit reversible dynamic frameworks that are able to respond to external stimuli such as light, electric fields, or the presence of particular species.[1] Such structural changes in soft porous crystals are often called “gate opening” and “breathing”, which are characterized by a large hysteresis loop between the adsorption and desorption curves.[1a, 2]
机译:软多孔晶体作为杂交纳米多孔晶体材料的诱人类别,因为它们表现出可逆动态框架,其能够响应外部刺激,例如光,电场或特定物种的存在。[1] 软多孔晶体中的这种结构变化通常称为“闸门开口”和“呼吸”,其特征在于吸附和解吸曲线之间的大型滞后环。[1A,2]

著录项

  • 来源
    《ChemPlusChem》 |2013年第10期|共4页
  • 作者单位

    College of Science Nanjing Forestry University Jiangsu 210037 China Department of Chemical;

    Department of Chemical Engineering Monash University Clayton VIC 3800 Australia;

    Department of Chemical Engineering Monash University Clayton VIC 3800 Australia;

    Department of Chemical Engineering Monash University Clayton VIC 3800 Australia;

    Department of Chemical Engineering Monash University Clayton VIC 3800 Australia;

    Department of Chemical Engineering Monash University Clayton VIC 3800 Australia;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
  • 关键词

    CO2 adsorption; gate-opening processes; phase transitions; zeolites; zeolitic imidazole framework;

    机译:CO2吸附;浇口开启过程;相变;沸石;沸石咪唑框架;

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