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Electrostatic and hydrophobic controlled self-assembly of PDMS-E grafted gelatin for self-cleaning application

机译:用于自清洁应用的PDMS-E接枝明胶的静电和疏水控制自组装

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摘要

Understanding the assembly mechanisms of supramolecular architectures in nature is essential for the design and synthesis of novel biomaterials. In the work, self-assembly of gelatin-mono epoxy terminated polydimethylsiloxane polymer (PGG) controlled by electrostatic and hydrophobic interactions between gelatin and sodium dodecyl sulfate (SDS) was investigated in suit. Confocal laser scanning microscopy, circular dichroism spectroscopy, high-resolution transmission electron microscopy and X-ray photoelectron spectroscopy were conducted to reveal the structure evolution of PGG at a molecular level with the increment of SDS concentration, including micro-sized sphere, core-shell and multi-layer structure. Notably, the multi-layer structure was formed from the large contribution of antiparallel beta-sheets on the boundary and new hydrophobic aggregation driven by higher monomer conversions. The delicate supramolecular architectures preliminarily present excellent anti water, anti-contamination and anti-radiation properties in the surface of skin. The excellent self-cleaning function of PGG indicates potential application in biomaterials.
机译:了解自然界中超分子架构的装配机制对于设计和合成新型生物材料是必不可少的。在该作品中,通过明胶和十二烷基硫酸钠(SDS)之间的静电和疏水相互作用控制的明胶-OnoO环氧封端的聚二甲基硅氧烷聚合物(PGG)的自组装。进行了共聚焦激光扫描显微镜,圆形二色光谱,高分辨率透射电子显微镜和X射线光电子能谱,以揭示分子水平的PGG的结构演化,增量SDS浓度,包括微尺寸球体,芯壳和多层结构。值得注意的是,通过通过更高的单体转换驱动的边界和新的疏水聚集的反向β-薄片的大贡献形成多层结构。精致的超分子架构在皮肤表面初步存在优异的抗水,抗污染和抗辐射性能。 PGG的优异自清洁功能表示潜在的应用在生物材料中。

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  • 作者单位

    Qilu Univ Technol Shandong Acad Sci Sch Chem &

    Pharmaceut Engn Shandong Prov Key Lab Mol Engn Jinan 250353 Shandong Peoples R China;

    Shandong Normal Univ Coll Chem Chem Engn &

    Mat Sci Jinan 250353 Shandong Peoples R China;

    Qilu Univ Technol Shandong Acad Sci Sch Chem &

    Pharmaceut Engn Shandong Prov Key Lab Mol Engn Jinan 250353 Shandong Peoples R China;

    Qilu Univ Technol Shandong Acad Sci Sch Chem &

    Pharmaceut Engn Shandong Prov Key Lab Mol Engn Jinan 250353 Shandong Peoples R China;

    Qilu Univ Technol Shandong Acad Sci Sch Chem &

    Pharmaceut Engn Shandong Prov Key Lab Mol Engn Jinan 250353 Shandong Peoples R China;

    Qilu Univ Technol Shandong Acad Sci Sch Chem &

    Pharmaceut Engn Shandong Prov Key Lab Mol Engn Jinan 250353 Shandong Peoples R China;

    Qilu Univ Technol Shandong Acad Sci Sch Chem &

    Pharmaceut Engn Shandong Prov Key Lab Mol Engn Jinan 250353 Shandong Peoples R China;

    Qilu Univ Technol Shandong Acad Sci Sch Chem &

    Pharmaceut Engn Shandong Prov Key Lab Mol Engn Jinan 250353 Shandong Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 胶体化学(分散体系的物理化学);
  • 关键词

    PGG; Self-assembly; Electrostatic and hydrophobic; Controlled; In-suit; Self-cleaning;

    机译:PGG;自我组装;静电和疏水;控制;适合于衣服;自清洁;

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