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首页> 外文期刊>Cement and Concrete Research >Application of thermodynamic modeling to predict the stable hydrate phase assemblages in ternary CSA-OPC-anhydrite systems and quantitative verification by QXRD
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Application of thermodynamic modeling to predict the stable hydrate phase assemblages in ternary CSA-OPC-anhydrite systems and quantitative verification by QXRD

机译:热力学建模在QXRD中预测稳定水合物相组合的稳定水合物相组合,QXRD定量验证

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摘要

Thermodynamic modeling was used to predict the stable hydrate phase assemblages in a ternary CSA-OPC-anhydrite system. On the basis of this modeling, five systems with diverging expected hydrate phases were chosen for experimental examination via QXRD and TGA. The aim of this study was to examine whether and to which extent the predicted equilibrium states are reached after 28 days of hydration. Qualitatively the predicted hydrate phase assemblages were reached for all five systems after 28 d of hydration. When the reaction degrees of the anhydrous phases are taken into account the experimental data fits remarkably well to the thermodynamic model. Additionally, C2S dissolution was found to be the most rapid in straetlingite forming environments.
机译:热力学建模用于预测三元CSA-OPC-Anhydry系统中的稳定水合物相组合。 在该建模的基础上,通过QXRD和TGA选择具有分歧的预期水合物阶段的五个系统进行实验检查。 本研究的目的是检查保湿28天后是否达到预测的均衡状态的程度是否和达到预测的均衡状态。 定性地,在28 d水合后,所有五种系统都达到了预测的水合物相组合。 当考虑无水相的反应程度,实验数据非常适合热力学模型。 另外,发现C2S溶解是在Straetlingitle形成环境中最快速的。

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