Room-temperature synthesis of a new stable (N_2H_4)WO_3 compound: a route for hydrazine trapping

F. Giovannelli; C. Mathieu; K. Fritsch; K. Adil; F. Goutenoire; K. Habicht; F. Delorme

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Room-temperature synthesis of a new stable (N_2H_4)WO_3 compound: a route for hydrazine trapping

机译：室温合成新稳定（N_2H_4）WO_3化合物：肼捕获的途径

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A new (N_2H_4)WO_3 compound has been obtained by mixing WO_3 and aqueous hydrazine solution at room temperature for 24 h. The reaction is catalyzed by the presence of lithium. X-ray, synchrotron and neutron diffraction techniques have shown that the material crystallizes in trigonal space group P3_221 (No. 154). Chains of distorted WO_4 tetrahedra extend along the a axis of the unit cell, linked by a corner-sharing oxygen atom: the N_2H_4 are in the voids between them. The thermal characterization shows that this new compound is stable up to 220°C, greatly beyond the boiling point of N_2H_4 (114°C); thus making it a promising candidate for catalysis or trapping applications.

机译：通过将WO_3和含水肼水溶液在室温下混合24小时来获得新的（N_2H_4）WO_3化合物。通过锂的存在催化反应。 X射线，同步rotron和中子衍射技术表明，该材料在三角空间组P3_221（No.154）中结晶。扭曲的WO_4 Tetrahedra链沿着单元电池的轴线延伸，由角阳性氧原子连接：N_2H_4位于它们之间的空隙中。热表征表明，该新化合物稳定至220℃，大大超出了N_2H_4（114°C）的沸点; 因此，使其成为催化或捕获应用的有希望的候选者。

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《Acta Crystallographica, Section B. Structural science, crystal engineering and materials》 |2019年第2期|共7页
作者
F. Giovannelli; C. Mathieu; K. Fritsch; K. Adil; F. Goutenoire; K. Habicht; F. Delorme;
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作者单位

Université Fran?ois Rabelais de Tours CNRS INSA CVL GREMAN UMR 7347 IUT de Blois 15 rue de la chocolaterie CS 2903 Blois Cedex 41150 France;

Université Fran?ois Rabelais de Tours CNRS INSA CVL GREMAN UMR 7347 IUT de Blois 15 rue de la chocolaterie CS 2903 Blois Cedex 41150 France;

Helmholtz-Zentrum Berlin für Materialien und Energie GmbH Berlin 14109 Germany;

KAUST (King Abdullah University of Science and Technology) Thuwal Saudi Arabia;

IMMM (Institute of Materials and Molecules of Mans) UMR-CNRS 6283 Le Mans University 72085 Le Mans Cedex 9 France.;

Helmholtz-Zentrum Berlin für Materialien und Energie GmbH Berlin 14109 Germany;

Université Fran?ois Rabelais de Tours CNRS INSA CVL GREMAN UMR 7347 IUT de Blois 15 rue de la chocolaterie CS 2903 Blois Cedex 41150 France;

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正文语种 eng
中图分类晶体学;
关键词
hybrid compound; tungsten oxide; hydrazine trapping;

机译：杂交化合物;氧化钨;肼诱捕;

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专利

1. Room-temperature synthesis of a new stable (N_2H_4)WO_3 compound: a route for hydrazine trapping [J] . F. Giovannelli, C. Mathieu, K. Fritsch, Acta Crystallographica, Section B. Structural science, crystal engineering and materials . 2019,第2期

机译：室温合成新稳定（N_2H_4）WO_3化合物：肼捕获的途径
2. Double Cycloisomerization as a Novel and Expeditious Route to Tricyclic Heteroaromatic Compounds: short and highly Diastereoselective Synthesis of (±)-Tetraponerine T6 [J] . Joseph T. Kim, Vladimir Gevorgyan Organic letters . 2002,第26期

机译：双环异构化作为三环杂芳族化合物的新型快速途径：（±）-四氢萘醌T6的短而高度非对映选择性合成
3. A Convinent Route for Synthesis of New Stable 1,4- Diionie Compounds from Three Component Reactiones of 4,4,4- Trifluoro-1 -thiophen-2-yl-biitan-1,3-dione, Dialkyl Acetylenicesters and Azines [J] . KH. POURSHAMSIAN, N. MONTAZERI, S. ALI-ASGARI Oriental Journal of Chemistry: An International Research Journal of Pure & Applied Chemistry . 2011,第3期

机译：从4,4,4-三氟-1-噻吩-2-基-联苯-1,3-二酮，二烷基乙酰酯和叠氮三组分的三组分反应合成新的稳定的1,4-二酮化合物的简便方法
4. Physical properties of nano-scale WO_3 and their effect on performance of Al/WO_3 Metastable Intermolecular Compounds [C] . Zane Arp, W.Lee Perry, Bettina L.Smith, International Pyrotechnics Seminar . 2004

机译：纳米级WO_3的物理性质及其对Al / WO_3亚稳态分子化合物的性能的影响
5. Development of new chemistry for a dual use hydrazine thruster switchable room temperature ionic liquids a study of silane grafting to model polyethylene compounds synthesis of the novel hydrazine replacement fuel molecules 1,1-dimethyl-2-[2-azidoethyl]hydrazine and 1,1-dimethyl-2-[2-azidoethyl]hydrazone . [D] . Huttenhower, Hilary Anne. 2010

机译：两用肼推进器可切换室温离子液体的新化学研究进展，研究硅烷接枝模拟聚乙烯化合物合成新型肼替代燃料分子1,1-二甲基-2- [2-叠氮基乙基]肼和1,1的研究-二甲基-2- [2-叠氮基乙基] hydr。
6. Double Cycloisomerization as a Novel and Expeditious Route to Tricyclic Heteroaromatic Compounds: Short and Highly Diastereoselective Synthesis of (±)-Tetraponerine T6 [O] . Joseph T. Kim, Vladimir Gevorgyan -1

机译：双环异构化作为三环杂芳族化合物的新型和快速途径：（±）-四氢萘醌T6的短而高度非对映选择性合成。
7. Double Cycloisomerization as a Novel and Expeditious Route to Tricyclic Heteroaromatic Compounds: Short and Highly Diastereoselective Synthesis of (.+-.)-Tetraponerine T6. [O] . Joseph T. Kim, Vladimir Gevorgyan 2003

机译：双循环化作为新的三环杂芳族化合物的新型和迅速的途径：（。+ - 。） - 四烷碱T6的短且高度映选择性合成。

Room-temperature synthesis of a new stable (N_2H_4)WO_3 compound: a route for hydrazine trapping

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