Non-order-disorder allotwinning of the rhenium pincer complex cis-Re[(PNP~(CH_2)-iPr)(CO)_2Cl]

Mathias Glatz; Berthold St?ger; Karl Kirchner

首页> 外文期刊>Acta Crystallographica, Section B. Structural science, crystal engineering and materials >Non-order-disorder allotwinning of the rhenium pincer complex cis-Re[(PNP~(CH_2)-iPr)(CO)_2Cl]

【24h】

Non-order-disorder allotwinning of the rhenium pincer complex cis-Re[(PNP~(CH_2)-iPr)(CO)_2Cl]

机译：铼钳复合物CIS-Re的非令失调换药[（PNP〜（CH_2）-IPR）（CO）_2CL]

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Crystals of cis-Re[(PNP~(CH_2)-iPr)(CO)_2Cl] (1) are made up of two geometrically non-equivalent polytypes with respective symmetries of P2_1/c and I2/a. The structures were determined in a concurrent refinement, taking into account overlap of diffraction spots. The polytypes are composed of layers with p_x12_1/c1 symmetry and are of the non-order-disorder (OD) type (the layer interfaces are non-equivalent). Whereas the molecules of (1) differ in both polytypes, the Re atoms are located at nearly identical positions.

机译：CIS-RE的晶体[（PNP〜（CH_2）-IPR）（CO）_2CL]（1）由两个几何非等效多阱组成，其具有P2_1 / C和I2 / A的各自对称的。在同时改进中确定结构，考虑到衍射斑点的重叠。多型由具有P_X12_1 / C1对称性的层组成，并且是非阶无序（OD）类型（层接口是非等同的）。虽然（1）的分子在多种晶体中不同，但重新原子位于几乎相同的位置。

著录项

来源
《Acta Crystallographica, Section B. Structural science, crystal engineering and materials》 |2017年第5期|共9页
作者
Mathias Glatz; Berthold St?ger; Karl Kirchner;
展开▼
作者单位

Institute of Applied Synthethic Chemistry TU Wien Getreidemarkt 9 1060 Vienna Austria;

X-ray Centre TU Wien Getreidemarkt 9 1060 Vienna Austria;

Institute of Applied Synthethic Chemistry TU Wien Getreidemarkt 9 1060 Vienna Austria;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类晶体学;
关键词
polytypism; allotwinning;

机译：多透明度？其他文字;

相似文献

外文文献

1. Non-order-disorder allotwinning of the rhenium pincer complex cis-Re[(PNP~(CH_2)-iPr)(CO)_2Cl] [J] . Mathias Glatz, Berthold St?ger, Karl Kirchner Acta Crystallographica, Section B. Structural science, crystal engineering and materials . 2017,第5期

机译：铼钳复合物CIS-Re的非令失调换药[（PNP〜（CH_2）-IPR）（CO）_2CL]
2. An iron(II) complex featuring κ~3 and labile κ~2-bound PNP pincer ligands – striking differences between CH_2 and NH spacers [J] . Bernhard Bichler, Mathias Glatz, Berthold St?ger, Dalton transactions: An international journal of inorganic chemistry . 2014,第39期

机译：具有κ〜3和不稳定的κ〜2结合PNP钳配体的铁（II）配合物– CH_2和NH间隔基之间的显着差异
3. Synthesis of some manganese rhenium trifluoroacetoxymethyl and iodomethyl complexes. X-ray structure of cis-Re(CO)_4(PPh_3)CH_2OC(O)CF_3, fac-Re(CO)_3(dppp)CH_2OC(O)CF_3 and cis-Re(CO)_4(PPh_3)CH_2I [J] . Damon A. Brown, Santosh K. Mandal, Douglas M. Ho, Journal of Organometallic Chemistry . 1999,第1期

机译：某些锰tri的三氟乙酰氧基甲基和碘甲基配合物的合成。 cis-Re（CO）_4（PPh_3）CH_2OC（O）CF_3，fac-Re（CO）_3（dppp）CH_2OC（O）CF_3和cis-Re（CO）_4（PPh_3）CH_2I的X射线结构
4. Catalytic Nitrogen Fixation Using Rhenium-Dinitrogen ComplexBearing PNP Pincer Ligands [C] . Fanqiang Meng, Shogo Kuriyama, Kazunari Nakajima 日本化学会春季年会 . 2020

机译：催化氮固定采用铼 - 二硝基复合PNP钳子配体
5. Studies of PNP and PCP pincer complexes: Synthesis and carbon-hydrogen activation potential of PNP pincer complexes and a PCP pincer complex applied to alkene hydrogenation [D] . Pelczar, Elizabeth Marie 2008

机译：PNP和PCP钳形复合物的研究：PNP钳形复合物和PCP钳形复合物的合成及其碳氢活化潜力，用于烯烃加氢
6. Non-order–disorder allotwinning of the rhenium pincer complex cis-Re(PNPCH2-iPr)(CO)2Cl [O] . Mathias Glatz, Berthold Stöger, Karl Kirchner -1

机译：pin钳复合物顺-Re （PNPCH2-iPr）（CO）2Cl的无序分配
7. Re(CO)3Cl(C5H4ClP)2 and Re(CO)2Cl(C5H4ClP)3: synthesis and characterization of two novel rhenium(i) phosphinine complexes [O] . Manuela Hollering, Richard O. Reithmeier, Simon Meister, 2016

机译：Re（CO）3Cl（C5H4ClP）2和Re（CO）2Cl（C 5H 4ClP）3：两种新型铼（I）膦腈复合物的合成和表征

Non-order-disorder allotwinning of the rhenium pincer complex cis-Re[(PNP~(CH_2)-iPr)(CO)_2Cl]

摘要

著录项

相似文献

相关主题

期刊订阅