The rich crystal chemistry of the AMM AMM ′(PO 4 4 ) 2 2 morphotropic series: NaZnAl(PO 4 4 ) 2 2 , the first Na representative with a new structure type

Yakubovich Olga; Kiriukhina Galina; Volkov Anatoliy; Dimitrova Olga

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The rich crystal chemistry of the AMM AMM ′(PO 4 4 ) 2 2 morphotropic series: NaZnAl(PO 4 4 ) 2 2 , the first Na representative with a new structure type

机译：AMM AMM'（PO 4 4）的富水晶化学2 2 MorphotoPic系列：Naznal（PO 4 4）2 2，第一个Na代表具有新的结构类型

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A novel phosphate, sodium zinc aluminium bis(phosphate), NaZnAl(PO 4 ) 2 , was obtained under mild‐temperature hydrothermal conditions at 553?K. The crystal structure has been studied using single‐crystal X‐ray experimental data. The pseudo‐hexagonal phase NaZnAl(PO 4 ) 2 crystallizes in the monoclinic space group P 2 1 / c . Its unique crystal structure is based on a three‐dimensional (3D) framework built by Zn‐, Al‐ and P‐centred tetrahedra sharing vertices. Channels parallel to the [101] and [01] directions are limited by six‐ and eight‐membered windows, and incorporate Na atoms. The new compound is discussed as a member of the morphotropic series AMM ′PO 4 , where A = Na, K, Rb or NH 4 , M ?= Cu, Ni, Co, Fe, Zn or Mg and M ′ = Fe, Al or Ga. The title compound is the first Na representative within the series and is characterized by a 3D architecture of tetrahedra populated in an ordered manner by Zn 2+ , Al 3+ and P 5+ ions.

机译：在553μk的温度温度水热条件下获得新型磷酸盐，锌铝双（磷酸盐），纳粹（PO 4）2。已经使用单晶X射线实验数据研究了晶体结构。伪六方阶段纳粹（PO 4）2在单斜晶间空间组P 2 1 / C中结晶。其独特的晶体结构基于由Zn，Al-和P-ineded Tetrahedra共享顶点构建的三维（3D）框架。平行于[101]和[01]方向的通道受六个和八元窗口的限制，并包含Na原子。新化合物被讨论为Morphotopic系列AMM'PO 4的成员，其中A = Na，K，Rb或NH 4，M？= Cu，Ni，Co，Fe，Zn或Mg和M'= Fe，Al 或Ga。标题化合物是该系列内的第一个Na代表性，其特征在于通过Zn 2+，Al 3+和P 5+离子以有序方式填充的Tetrahedra的3D架构。

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《Acta crystallographica. Section C, Structural chemistry.》 |2019年第5期|共8页
作者
Yakubovich Olga; Kiriukhina Galina; Volkov Anatoliy; Dimitrova Olga;
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作者单位

M. V. Lomonosov Moscow State University Leninskye Gory 1 Moscow 119991 Russian Federation;

M. V. Lomonosov Moscow State University Leninskye Gory 1 Moscow 119991 Russian Federation;

M. V. Lomonosov Moscow State University Leninskye Gory 1 Moscow 119991 Russian Federation;

M. V. Lomonosov Moscow State University Leninskye Gory 1 Moscow 119991 Russian Federation;

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正文语种 eng
中图分类晶体学;
关键词
morphotropic series; phosphate; open framework; crystal structure; structure types; crystal chemistry; sodium; zinc; aluminium;

机译：Morphotopic系列;磷酸盐;开放框架;晶体结构;结构类型;晶体化学;钠;锌;铝;

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1. The rich crystal chemistry of the AMM AMM ′(PO 4 4 ) 2 2 morphotropic series: NaZnAl(PO 4 4 ) 2 2 , the first Na representative with a new structure type [J] . Yakubovich Olga, Kiriukhina Galina, Volkov Anatoliy, Acta crystallographica. Section C, Structural chemistry. . 2019,第5期

机译：AMM AMM'（PO 4 4）的富水晶化学2 2 MorphotoPic系列：Naznal（PO 4 4）2 2，第一个Na代表具有新的结构类型
2. A first Mn member in the struvite morphotropic series, CsMn(H 2 2 O) 6 6 (PO 4 4 ): hydrothermal synthesis, crystal structure and interconnections within the family of related phosphates [J] . Kiriukhina Galina V., Yakubovich Olga V., Kochetkova Ekaterina M., Acta crystallographica. Section C, Structural chemistry. . 2018,第8期

机译：Struvite Morphothic系列中的第一MN构件，CSMN（H 2 2 O）6 6（PO 4 4）：相关磷酸盐系列的水热合成，晶体结构和互连
3. Structural chemistry of metal inorganic 3D MT frameworks. Templated nanoclusters-precursors Ga-2(PO4)(2)F-2 and Ga-2(PO4)(2)(HF)F-2 and self-assembly of crystalline gallophosphate structures (NH4)(2)[Ga-2(PO4)(2)F-2](KTP-Type) and (NH4)(2)[Ga-2(PO4)(2)(HF)F-2] (p-KTP-Type) [J] . Shevchenko V. Ya., Blatov V. A., Ilyushin G. D. Glass Physics and Chemistry: A Journal on the Structural, Physical, and Chemical Properties and Nature of Inorganic Glasses and Glass-Forming Melts . 2015,第6期

机译：金属无机3D MT框架的结构化学。模板化的纳米簇前体Ga-2（PO4）（2）F-2和Ga-2（PO4）（2）（HF）F-2和结晶镓磷酸盐结构（NH4）（2）[Ga-2的自组装（PO4）（2）F-2]（KTP型）和（NH4）（2）[Ga-2（PO4）（2）（HF）F-2]（p-KTP型）
4. Microstructure and Deformation Behavior of Lamellar Ti-rich TiAl Crystal with Lotus-type Aligned Pores [C] . Takayoshi Nakano, Takahiro Tachibana, Koji Hagihara, Pacific Rim International Conference on Advanced Materials and Processing; 20071105-09; Jeju Island(KR) . 2007

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The rich crystal chemistry of the AMM AMM ′(PO 4 4 ) 2 2 morphotropic series: NaZnAl(PO 4 4 ) 2 2 , the first Na representative with a new structure type

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