[1‐(Pyrazin‐2‐yl)ethylidene]hydrazine: a new multitopic ligand for the design of hybrid molecular frameworks

Kassim Muhammad Arif; Yassin Ubaidullah H. M.; Tan Ai Ling; Usman Anwar; Hamid Malai Haniti S. A.

首页> 外文期刊>Acta crystallographica. Section C, Structural chemistry. >[1‐(Pyrazin‐2‐yl)ethylidene]hydrazine: a new multitopic ligand for the design of hybrid molecular frameworks

【24h】

[1‐(Pyrazin‐2‐yl)ethylidene]hydrazine: a new multitopic ligand for the design of hybrid molecular frameworks

机译：[1-（吡嗪-2-基）乙基]肼：一种新型多型配体，用于杂交分子骨架设计

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Hydrazones and their derivatives are closely related to imine compounds and are potential antimicrobial agents. They have also found application in supramolecular chemistry as multitopic ligands to link multiple metal centres for the design of hybrid molecular frameworks. The molecule of the title compound, C 6 H 8 N 4 , consists of an imine linkage with an N—N bond length of 1.3540?(14)??. This asymmetric compound is nearly planar and adopts an E configuration about the azomethine C=N double bond. In the solid state, there are two intermolecular N—H…N interactions that interconnect the molecules into a two‐dimensional network. The three‐dimensional arrangement of the crystal packing is further stabilized by intermolecular π–π interactions interconnecting the centroids of the heterocyclic rings.

机译：腙及其衍生物与亚胺化合物密切相关，并且是潜在的抗微生物剂。他们还发现在超分子化学中的应用作为多型配体，以将多个金属中心联系起来设计混合分子框架。标题化合物C 6 H 8 N 4的分子由亚胺连杆组成，N-N键长度为1.3540≤（14）。该不对称化合物几乎是平面的，并采用关于氮杂甲胺C = N双键的E构型。在固态中，有两个分子间N-H ... N相互作用，其将分子互连到二维网络中。通过互连杂环环的质心的分子间π-π相互作用进一步稳定晶体包装的三维布置。

著录项

来源
《Acta crystallographica. Section C, Structural chemistry.》 |2018年第4期|共3页
作者
Kassim Muhammad Arif; Yassin Ubaidullah H. M.; Tan Ai Ling; Usman Anwar; Hamid Malai Haniti S. A.;
展开▼
作者单位

Chemical Sciences Faculty of Science Universiti Brunei Darussalam Jalan Tungku Link BE1410;

Chemical Sciences Faculty of Science Universiti Brunei Darussalam Jalan Tungku Link BE1410;

Chemical Sciences Faculty of Science Universiti Brunei Darussalam Jalan Tungku Link BE1410;

Chemical Sciences Faculty of Science Universiti Brunei Darussalam Jalan Tungku Link BE1410;

Chemical Sciences Faculty of Science Universiti Brunei Darussalam Jalan Tungku Link BE1410;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类晶体学;
关键词
hydrazine; crystal structure; antimicrobial agent; supramolecular chemistry; multitopic ligand; hybrid molecular framework; hydrogen bonding;

机译：肼;晶体结构;抗微生物剂;超分子化学;多型配体;杂交分子框架;氢键;

相似文献

外文文献
中文文献
专利

1. [1‐(Pyrazin‐2‐yl)ethylidene]hydrazine: a new multitopic ligand for the design of hybrid molecular frameworks [J] . Kassim Muhammad Arif, Yassin Ubaidullah H. M., Tan Ai Ling, Acta crystallographica. Section C, Structural chemistry. . 2018,第4期

机译：[1-（吡嗪-2-基）乙基]肼：一种新型多型配体，用于杂交分子骨架设计
2. Syntheses, crystal structures and antioxidant properties of four complexes derived from a new Schiff base ligand (N~1E,N~2E)-N~1,N~2-bis(1-(pyrazin-2-yl)ethylidene)ethane-1,2 diamine [J] . Mohammed A.S. Omer, Jia-Cheng Liu, Wen-Ting Deng, Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2014,第Null期

机译：新型席夫碱配体（N〜1E，N〜2E）-N〜1，N〜2-双（1-（吡嗪-2-基）亚乙基）乙烷-的四种配合物的合成，晶体结构和抗氧化性能1,2二胺
3. Molecular structure, NMR, UV-Visible, vibrational spectroscopic and HOMO, LUMO analysis of (E)-1-(2, 6-bis (4-methoxyphenyl)-3, 3-dimethylpiperidine-4-ylidene)-2-(3-(3, 5-dimethyl-1 H-pyrazol-1-yl) pyrazin-2-yl) hydrazine by DFT method [J] . Alphonsa A. Therasa, Loganathan C., Anand S. Athavan Alias, Journal of Molecular Structure . 2016,第Null期

机译：（E）-1-（2，6-双（4-甲氧基苯基）-3，3-二甲基哌啶-4-亚烷基）-2-（3）的分子结构，NMR，紫外可见光谱，振动光谱和HOMO，LUMO分析DFT法制备-（3，5-二甲基-1 H-吡唑-1-基）吡嗪-2-基）肼
4. Bio-hybrid supramolecule assembled by the fullerol molecule with CU(Ⅱ) azole ligand complex having coordinative bond to the histidine molecule: modelling of molecular structure and FTIR spectroscopic monitoring [C] . Iryna Sporysh, Liliana Lukashyk, Helena Gogotsi, World biomaterials congress . 2012

机译：富勒醇分子与对组氨酸分子具有配位键的CU（Ⅱ）唑配体配合物组装的生物杂交超分子：分子结构建模和FTIR光谱监测
5. Synthesis and characterization of multidimensional supramolecular networks supported by multitopic tris(pyrazolyl)methane ligands. [D] . Semeniuc, Radu Florin. 2004

机译：多主题三（吡唑基）甲烷配体支持的多维超分子网络的合成与表征。
6. Self-assembly of emissive supramolecular rosettes with increasing complexity using multitopic terpyridine ligands [O] . Guang-Qiang Yin, Heng Wang, Xu-Qing Wang, -1

机译：使用多主题三联吡啶配体的自组装超分子发光花环的复杂性不断提高
7. Synthesis and characterization of cobalt(II), nickel(II), copper(II), zinc(II) and cadmium(II) complexes of benzyl N-1-(thiophen-2-yl)ethylidene hydrazine carbodithioate and benzyl N-1-(thiophen-3-yl)ethylidene hydrazine carbodithioate and the X-ray crystal structure of bis{benzyl N-1-(thiophen-2-yl)ethylidene hydrazine carbodithioate}nickel(II) [O] . Mun-Hoe Eddy Chan, Karen A. Crouse, M. Ibrahim M. Tahir, 2008

机译：苄基N- 1-（硫氰酸-2-基）乙基肼碳腈和苄基甲基肼和苄基（II），镍（II），镍（II），铜（II），锌（II），锌（II）和镉（II）复合物的合成及表征 - 1-（噻吩-3-基）乙基肼碳化碳酸肼和双{苄基-1-（苯甲烯-2-基）乙基肼碳脱硫酶}镍（II）

[1‐(Pyrazin‐2‐yl)ethylidene]hydrazine: a new multitopic ligand for the design of hybrid molecular frameworks

摘要

著录项

相似文献

相关主题

期刊订阅