A new one-dimensional cadmium(ll) coordination polymer incorporating 4-[4-(1H-imidazol-1-yl)-phenyl]pyridine and 5-hydroxybenzene-1,3-di-carboxylate ligands

Zhi-Liang Zhang Jia-Cheng Liu

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A new one-dimensional cadmium(ll) coordination polymer incorporating 4-[4-(1H-imidazol-1-yl)-phenyl]pyridine and 5-hydroxybenzene-1,3-di-carboxylate ligands

机译：一种新的一维镉（LL）配位聚合物，其包含4- [4-（1H-咪唑-1-基） - 苯基]吡啶和5-羟基苯-1,3-二羧酸盐配体

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The design and synthesis of new organic lgands is important to the rapid development of coordination polymers (CPs). However, CPs based on asymmetric ligands are still rare, mainly because such ligands are usually expensive and more difficult to synthesize. The new asymmetric ligand 4-[4-(lH-imidazol-l-yl)phenyl]pyridine (IPP) has been used to construct the title one-dimensional coordination polymer, cafma-poly[[[aqua{4-[4-(li/-imidazol-l-yl-/dV3)-phenyl]pyridine}cadmium(II)]-/^-5-hydroxybenzene-l,3-dicarboxylato-/c:3O ,O :O3] monohydrate], {[Cd(C8H4Os)(C14H11N3)2(H2O)]-H2O}n, under hydrothermal reaction of IPP with Cd11 in the presence of 5-hydroxyisophthalic acid (5-OH-H2bdc). The Cd11 cation is coordinated by two N atoms from two distinct IPP ligands, three carboxylate O atoms from two different 5-OH-bdc2~ dianionic ligands and one water O atom in a distorted octahedral geometry. The cationic [Cd(IPP)2]2+ nodes are linked by 5-OH-bdc2~ ligands to generate a one-dimensional chain. These chains are extended into a two-dimensional layer structure via O—H- ? -O and O—H- ? -N hydrogen bonds and it-it interactions.

机译：新的有机LGAND的设计和合成对于协调聚合物的快速发展是重要的（CPS）。然而，基于不对称配体的CPS仍然罕见，主要是因为这种配体通常是昂贵的且难以合成的。新的不对称配体4- [4-（LH-咪唑-1-基）苯基]吡啶（IPP）已用于构建标题一维配位聚合物，Cafma-poly [[[Aqua {4- [4- （Li / -imidazol-L-YL-/ DV3） - 苯基]吡啶}镉（ii）] - / ^ - 5-羟基苯-1,3-二羧酸盐 - / C：3O，O：O 3]一水合物]，{ [Cd（C1H 4孔）（C14H11N3）2（C14H11N3）2（H 2 O）] - H 2 O} N，在IPP的水热反应下，CD11在5-羟基苯甲酸（5-OH-H2BDC）存在下。 CD11阳离子由来自两个不同的IPP配体的两种原子配位，来自两个不同5-OH-BDC2〜Dianionic配体的三种羧酸盐O原子，扭曲的八面体几何形状中的一个水O原子。阳离子[CD（IPP）2] 2+节点由5-OH-BDC2〜配体连接以产生一维链。这些链通过O-H-延伸成二维层结构 - ？ -o和o-h-？ -N氢键和它 - IT相互作用。

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《Acta crystallographica. Section C, Structural chemistry.》 |2016年第5期|共4页
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Zhi-Liang Zhang Jia-Cheng Liu;
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Key Laboratory of Eco-Environment-Related Polymer Materials of Ministry of Education Key;

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1. A new one-dimensional cadmium(ll) coordination polymer incorporating 4-[4-(1H-imidazol-1-yl)-phenyl]pyridine and 5-hydroxybenzene-1,3-di-carboxylate ligands [J] . Zhi-Liang Zhang Jia-Cheng Liu Acta crystallographica. Section C, Structural chemistry. . 2016,第5期

机译：一种新的一维镉（LL）配位聚合物，其包含4- [4-（1H-咪唑-1-基） - 苯基]吡啶和5-羟基苯-1,3-二羧酸盐配体
2. CRYSTAL STRUCTURE OF А NOVEL CADMIUM SULFATE COORDINATION POLYMER BASED ON THE MULTIDENTATE 2-(3-(4-(PYRIDIN-4-YL)PHENYL)-1H-1,2,4-TRIAZOL-5-YL) PYRIDINE LIGAND [J] . F.-L. Liu, X.-P. Wang, D. Sun Журнал струκтурной химии . 2014,第5期

机译：基于多齿2-（3-（4-（4-吡啶基-苯基）苯基）-1H-1,2,4-三唑-5-基）吡啶配体的А新型硫酸镉配位聚合物的晶体结构
3. Crystal structure of a novel cadmium sulfate coordination polymer based on the multidentate 2-(3-(4-(pyridin-4-yl)phenyl)-1H-1,2,4-triazol-5-yl) pyridine ligand [J] . Liu F. -L., Wang X. -P., Sun D. Journal of structural chemistry . 2014,第5期

机译：基于多齿2-（3-（4-（吡啶-4-基）苯基）-1H-1,2,4-三唑-5-基）吡啶配体的新型硫酸镉配位聚合物的晶体结构
4. A NEW NICKEL COORDINATION POLYMER CONSTRUCTED FROM 4-(8-HYDROY-XY 5-QUINOLINYL)AZO-BENZENESULFONIC ACID:SYNTHESIS,STRUCTURE AND PROPERTY [C] . Ya-Nan Luo, Zhi-Chen Liu, Hui-Ying Jiang, International Conference on New Materials and Intelligent Manufacturing . 2018

机译：由4 - （8-hydoy-xy 5-喹啉基）偶氮 - 苯磺酸：合成，结构和性能构建的新镍配位聚合物
5. Hydrothermal synthesis of metal coordination polymers using mixed pyridine-carboxylate ligands. [D] . Lin, Zhuojia. 2005

机译：使用吡啶-羧酸盐混合配体进行水热合成金属配位聚合物。
6. Synthesis and Characterization of Organosoluble Thermal Stable and Hydrophobic Polyimides Derived from 4-(4-(1-Pyrrolidinyl)phenyl)-26-bis(4-(4-aminophenoxy)phenyl)pyridine [O] . Xiaohua Huang, Beicai Chen, Mei Mei, 2017

机译：4-（4-（1-吡咯烷基）苯基）-26-双（4-（4-氨基苯氧基）苯基）吡啶衍生的有机可溶性热稳定和疏水性聚酰亚胺的合成和表征
7. Crystal structure of a one-dimensional looped-chain silver(I) coordination polymer: catena-poly[[silver(I)-bis{μ-4-[1-(5′-isopropyl-[1,1′:3′,1′′-terphenyl]-2′-yl)-1H-imidazol-2-yl]pyridine-κ2N:N′}] nitrate methanol monosolvate monohydrate] [O] . Suk-Hee Moon, Ki-Min Park, Youngjin Kang 2016

机译：一维环状链银（I）配位聚合物的晶体结构：catena-poly [[silver（I）-bis {μ-4- [1-（5'-异丙基 - [1,1'：3'] ，1' - 三联苯] -2'-基）-1H-咪唑-2-基]吡啶-κ2N：N'}]硝酸甲醇单溶剂化物一水合物]

A new one-dimensional cadmium(ll) coordination polymer incorporating 4-[4-(1H-imidazol-1-yl)-phenyl]pyridine and 5-hydroxybenzene-1,3-di-carboxylate ligands

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