Azido-directed formation of an unprecedented Mn(II)-organic framework with nanoscale cubic cage units

Zhao J.-P.; Zhao R.; Song W.-C.; Yang Q.; Liu F.-C.; Bu X.-H.

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Azido-directed formation of an unprecedented Mn(II)-organic framework with nanoscale cubic cage units

机译：叠氮定向形成具有纳米级立方笼单元的史无前例的Mn（II）-有机骨架

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A bcu topological three-dimensional Mn(II)-organic framework [Mn _(22)(N_3)_8(L)_(12)(H_2O) _(26)·5H_2O]_∞ (1) (L = 1,2,3-triazole-4,5-dicarboxylate) based on an unprecedented nanoscale cage has been hydrothermally synthesized. Dominating antiferromagnetic interactions were detected between the Mn~(II) ions in 1.

机译：bcu拓扑三维Mn（II）-有机框架[Mn _（22）（N_3）_8（L）_（12）（H_2O）_（26）·5H_2O]_∞（1）（L = 1，已经水热合成了基于史无前例的纳米级笼的2,3-三唑-4,5-二羧酸酯。在1中的Mn〜（II）离子之间检测到主要的反铁磁相互作用。

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《Crystal growth & design》 |2013年第2期|共3页
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Zhao J.-P.; Zhao R.; Song W.-C.; Yang Q.; Liu F.-C.; Bu X.-H.;
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中图分类晶体学;
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1. Azido-directed formation of an unprecedented Mn(II)-organic framework with nanoscale cubic cage units [J] . Zhao J.-P., Zhao R., Song W.-C., Crystal growth & design . 2013,第2期

机译：叠氮定向形成具有纳米级立方笼单元的史无前例的Mn（II）-有机骨架
2. Alkaline cation directed structural diversity of cubic-cage-based cobalt(II) metal-organic frameworks: from pcu to bct net [J] . Zou Ji-Yong, Shi Wei, Zhang Jing-Ya, CrystEngComm . 2014,第30期

机译：碱性阳离子指导的基于立方笼的钴（II）金属-有机骨架的结构多样性：从pcu到bct网
3. Antiferromagnetic Porous Metal–Organic Framework Containing Mixed-Valence [MnII4MnIII2(μ4-O)2]10+ Units with Catecholase Activity and Selective Gas Adsorption [J] . Paramita Kar Ritesh Haldar Carlos J. Gómez-García and Ashutosh Ghosh Inorganic Chemistry . 2012,第7期

机译：含价价[MnII4MnIII2（μ4-O）2] 10+单元且具有邻苯二酚酶活性和选择性气体吸附作用的反铁磁多孔金属-有机骨架
4. A Mn(II) Metal-Organic Framework Constructed from a Tetrahedral Silicon-Cored Ligand [C] . Qing-Yu Ma, Rui-Fang Guan, Guo-Zhong Li, International Conference on Applied Mechanics and Materials . 2013

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5. Liquid-liquid Interface Synthesis Method of Unprecedented Metal-organic Frameworks: Fundamental Theory, New Materials and Applications [D] . ?Fonseca, Javier Fonseca 2020

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机译：基于六核钴硫基簇的两个金属有机骨架或来自三角形MII3（3OH）（M = CO和Mn）单位的锰羟基链：具有软磁性行为的反铁磁性和旋涂反铁磁性排序

Azido-directed formation of an unprecedented Mn(II)-organic framework with nanoscale cubic cage units

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