Combining cyanometalates and coordination clusters: An alternative synthetic route toward original molecular materials

Mondal A.; Dassié P.-I.; Chamoreau L.-M.; Journaux Y.; Julve M.; Lisnard L.; Lescou?zec R.

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Combining cyanometalates and coordination clusters: An alternative synthetic route toward original molecular materials

机译：氰基金属酸盐和配位簇的组合：替代原始分子材料的合成途径

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As an original synthetic route to molecular magnetic materials, we have reacted partially-blocked cyanometalates with preformed coordination cluster. The association of the fac-[Fe(Tp)(CN)_3]~- assembling metalloligand with the [Cu_3(OH)(pz)_3]~(2+) trigonal cluster has afforded a novel coordination network where the trimetallic copper(II) nodes are linked by the iron(III) complexes into chains and by coordinating acetate into a two-dimensional framework.

机译：作为分子磁性材料的原始合成途径，我们使部分封闭的氰基金属酸盐与预先形成的配位簇反应。 fac- [Fe（Tp）（CN）_3]〜-组装金属配体与[Cu_3（OH）（pz）_3]〜（2+）三角簇的缔合提供了一个新颖的配位网络，其中三金属铜（ II）节点通过铁（III）配合物链接成链，并通过将乙酸盐配位成二维框架。

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《Crystal growth & design》 |2013年第10期|共5页
作者
Mondal A.; Dassié P.-I.; Chamoreau L.-M.; Journaux Y.; Julve M.; Lisnard L.; Lescou?zec R.;
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正文语种 eng
中图分类 54.9;
关键词
Coordination clusters; Coordination networks; Cyanometalates;

机译：配位簇;配位网络;氰基金属酸盐;

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1. Combining cyanometalates and coordination clusters: An alternative synthetic route toward original molecular materials [J] . Mondal A., Dassié P.-I., Chamoreau L.-M., Crystal growth & design . 2013,第10期

机译：氰基金属酸盐和配位簇的组合：替代原始分子材料的合成途径
2. Molecular-Based Magnetism in High-Spin Molecular Clusters and Three-Dimensional Networks Based on Cyanometalate Building Blocks [J] . Melanie Pilkington, Silvio Decurtins Chimia . 2000,第10期

机译：高旋转分子簇和基于氰基金属酸盐构建基的三维网络中基于分子的磁性。
3. Coordination Clusters of 3d-Metals That Behave as Single-Molecule Magnets (SMMs): Synthetic Routes and Strategies [J] . Maniaki Diamantoula, Pilichos Evangelos, Perlepes Spyros P. Frontiers in Chemistry . 2018,第2008期

机译：作为单分子磁体（SMM）的3d金属的协调簇：合成途径和策略
4. Clusters assembled materials: a new class of nanostructured materials with original structures and properties [C] . A. Perez, P. Melinon, V. Dupuis, Third international conference on intelligent materials and Third European conference on smart structures and materials . 1996

机译：聚集组装的材料：具有原始结构和性能的新型纳米结构材料
5. The coordination chemistry of a chelating tricyclic bisamidine and a new synthetic route to a C(2)-symmetric tricyclic bisamidine [D] . Li, Jingwei 2007

机译：螯合三环双am的配位化学和一个新的合成路线到C（2）对称三环双am
6. Coordination Clusters of 3d-Metals That Behave as Single-Molecule Magnets (SMMs): Synthetic Routes and Strategies [O] . Diamantoula Maniaki, Evangelos Pilichos, Spyros P. Perlepes 2018

机译：作为单分子磁体（SMM）的3d金属的协调簇：合成途径和策略
7. Combining oxime-based [Mn6] clusters with cyanometalates: 1D chains of [Mn6] SMMs from [M(CN)2]- (M = Au, Ag) [O] . Sanz, Sergio, Lorusso, Giulia, Evangelisti, Marco, 2015

机译：结合基于肟的[Mn6]簇和氰基金属酸盐：[M（CN）2]-（M = Au，Ag）的[Mn6] SMM的一维链
8. Standard Reference Materials: Comparison of Original and Supplemental SRM 705, Narrow Molecular Weight Distribution Polystyrene. [R] . Wagner, H. L. 1972

机译：标准参考材料：原始和补充sRm 705，窄分子量分布聚苯乙烯的比较。

Combining cyanometalates and coordination clusters: An alternative synthetic route toward original molecular materials

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