Staging Bonding between Group 12 Metal Ions and Neutral Selenium Donors: Intermolecular Interactions of Mixed N,Se Donor Ligands and Anions

Hain Malia S.; Fukuda Yoko; Ramirez Carolina Rojas; Winer Benjamin Y.; Winslow Stephanie E.; Pike Robert D.; Bebout Deborah C.

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Staging Bonding between Group 12 Metal Ions and Neutral Selenium Donors: Intermolecular Interactions of Mixed N,Se Donor Ligands and Anions

机译：第12组金属离子与中性硒供体之间的分阶段键合：混合的N，Se供体配体和阴离子的分子间相互作用

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The versatile pyridyl synthons of mixed N,Se donor ligands bis(pyridin-2-ylmethyl)selane (L) and 1,2-bis(pyridin-2-ylmethyl)diselane (L*) served the dual roles of metal chelating anchors and mediators of supramolecular associations in a crystallographic approach to documenting uncommon bonding between divalent Group 12 metal ions and neutral selenium functionalities. Five new molecular species with diverse ligand configurations and conformations were structurally characterized. Two macrocyclic polymorphs of [ZnLCl2] have intermolecular Se-Cl interactions rather than the desired intramolecular Zn-Se binding. Rare examples of Cd(II)-selenoether bonding are provided by tricoordinate L in dinuclear [CdLCl(mu-Cl)](2) and mononuclear [CdL(mu-NO3)(2)]. Unique intramolecular Zn-selenoether and Cd-diselenide bonds are reported for [ZnL(mu-NO3)(2)] and [CdL*(mu-NO3)(2)], respectively. In addition, a cocrystal of [CdL(mu-NO3)(2)] and [CdL*(mu-NO3)(2)] is structurally characterized. The intermolecular pyridyl pi-interactions observed in these diverse structures are highlighted.

机译：混合的N，Se供体配体双（吡啶-2-基甲基）硒烷（L）和1,2-双（吡啶-2-基甲基）二硒烷（L *）的多用途吡啶基合成子起着金属螯合锚和晶体学方法中超分子缔合体的介体，用于记录二价12族金属离子与中性硒官能团之间的罕见键合。在结构上表征了五个具有不同配体构型和构象的新分子物种。 [ZnLCl2]的两个大环多晶型物具有分子间Se-Cl相互作用，而不是所需的分子内Zn-Se结合。三配位L在双核[CdLCl（mu-Cl）]（2）和单核[CdL（mu-NO3）（2）]中提供了Cd（II）-硒醚键的稀有例子。分别报告了[ZnL（mu-NO3）（2）]和[CdL *（mu-NO3）（2）]的独特的分子内Zn-硒醚键和Cd-二硒键。另外，[CdL（mu-NO3）（2）]和[CdL *（mu-NO3）（2）]的共晶体在结构上被表征。这些不同的结构中观察到的分子间吡啶基pi相互作用突出显示。

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《Crystal growth & design》 |2014年第12期|共11页
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Hain Malia S.; Fukuda Yoko; Ramirez Carolina Rojas; Winer Benjamin Y.; Winslow Stephanie E.; Pike Robert D.; Bebout Deborah C.;
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1. Staging Bonding between Group 12 Metal Ions and Neutral Selenium Donors: Intermolecular Interactions of Mixed N,Se Donor Ligands and Anions [J] . Hain Malia S., Fukuda Yoko, Ramirez Carolina Rojas, Crystal growth & design . 2014,第12期

机译：第12组金属离子与中性硒供体之间的分阶段键合：混合的N，Se供体配体和阴离子的分子间相互作用
2. Coordination chemistry of iron triad metals with organic N-donor ligands and boron cluster anions [B10H10](2-), [B12H12](2-), and [B10Cl10](2-): Complexation and accompanying processes [J] . Avdeeva V. V., Malinina E. A., Kuznetsov N. T. Russian Journal of Inorganic Chemistry . 2017,第13期

机译：铁三合会金属的配位化学与有机N-供体配体和硼簇阴离子[B10H10]（2-），[B12H12]（2-）和[B10Cl10]（2-）：络合和随附的过程
3. Coordination chemistry of iron triad metals with organic N-donor ligands and boron cluster anions [B10H10](2-), [B12H12](2-), and [B10Cl10](2-): Complexation and accompanying processes [J] . Avdeeva V. V., Malinina E. A., Kuznetsov N. T. Russian Journal of Inorganic Chemistry . 2017,第13期

机译：铁三合会金属的配位化学与有机N-供体配体和硼簇阴离子[B10H10]（2-），[B12H12]（2-）和[B10Cl10]（2-）：络合和随附的过程
4. Third-order NLO properties of metal complexes containing delocalized oxygen or sulphur donor ligands and mixed oxygen and sulphur donor ligands [C] . Ajaib S. Dhindsa, Univ. of Wales, Bangor, Optical Materials Technology for Energy Efficiency and Solar Energy Conversion XIV . 1995

机译：包含离域氧或硫供体配体以及氧和硫供体配体混合的金属配合物的三阶NLO性质
5. Experimental and theoretical studies of binding interactions in divalent transition metal cation-N-donor ligand complexes: Structures, sequential bond dissociation energies, mechanisms and energetics of collision-induced dissociation. [D] . Nose, Holliness. 2014

机译：二价过渡金属阳离子-N-供体配体配合物中结合相互作用的实验和理论研究：结构，顺序键解离能，碰撞诱导解离的机理和能量。
6. Can Serendipity Still Hold Any Surprises in the Coordination Chemistry of Mixed-Donor Macrocyclic ligands? The Case Study of Pyridine-Containing 12-Membered Macrocycles and Platinum Group Metal ions Pd [O] . Alessandra Garau, Giacomo Picci, Massimiliano Arca, 2021

机译：Serendipity仍然在混合供体宏环配体的协调化学中持有任何惊喜吗？含吡啶的12-元宏型克和铂族金属离子PD的案例研究
7. Two different hydrogen bond donor ligands together: A selectivity improvement in organometallic {Re(CO) 3} anion hosts [O] . Pérez, Julio, Riera, Lucía 2013

机译：两种不同的氢键供体配体在一起：有机金属{Re（CO）3}阴离子主体中的选择性提高
8. Importance of weak hydrogen bonding C-H--donor and C-H--anion interactions in governing the structural properties of organic donors BEDT-TTF and BEDO-TTF and their charge-transfer salts. [R] . Whangbo, M. H., Jung, D., Ren, J., 1989

机译：弱氢键C-H - 供体和C-H - 阴离子相互作用在控制有机供体BEDT-TTF和BEDO-TTF及其电荷转移盐的结构性质中的重要性。

Staging Bonding between Group 12 Metal Ions and Neutral Selenium Donors: Intermolecular Interactions of Mixed N,Se Donor Ligands and Anions

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