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首页> 外文期刊>Advanced Powder Technology: The internation Journal of the Society of Powder Technology, Japan >High shear-granulated hierarchically porous spheres nanostructure-designed for high-performance supercapacitors
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High shear-granulated hierarchically porous spheres nanostructure-designed for high-performance supercapacitors

机译:高剪切颗粒状的分层多孔球体纳米结构设计用于高性能超级电容器

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摘要

In this work, the nanosheets-composed porous spheres with a narrow pore size distribution are designed as a rational microstructure configuration of electrode materials for Faraday supercapacitors (FSs). The design of this structure is based on the electrochemical mechanism of FSs, which is beneficial to the redox reactions of electrode materials and the transfer of electrolyte ions to the greatest extent. This structure is built by the interlocking of nanosheets under the high shear mixer-exerted shear force using Zn2+ doped Ni(OH)(2) nanosheets as building blocks. It is found that the strong shear force is the driving force for the interlocking of nanosheets. The layer-by-layer growth through the nanosheets interlocking results in the formation of nanostructured spheres designed by us. Due to the appropriate pore structure and the two-dimensional morphology of building blocks, the porous spheres of Zn2+ doped Ni(OH)(2) present high electrochemical performance. (C) 2019 The Society of Powder Technology Japan. Published by Elsevier B.V. and The Society of Powder Technology Japan. All rights reserved.
机译:在这项工作中,纳米胸部和孔尺寸分布的多孔球形被设计为法拉第超级电容器(FSS)的电极材料的合理微观结构配置。该结构的设计基于FSS的电化学机理,这对电极材料的氧化还原反应和电解质离子的转移至最大程度的转移是有益的。这种结构是通过使用Zn2 +掺杂Ni(OH)(2)纳米晶片作为构建块的高剪切混合器施加的剪切力下的纳米片互锁。发现强剪切力是纳米片互锁的驱动力。逐层通过纳米蛋白酶的增长互锁导致由我们设计的纳米结构球形成。由于适当的孔结构和构建块的二维形态,Zn2 +掺杂Ni(OH)(2)的多孔球体具有高电化学性能。 (c)2019年日本粉末技术学会。由elsevier b.v发表。和日本粉末科技会。版权所有。

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