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Insights into multi-objective design of metal-organic frameworks

机译:对金属有机框架的多目标设计的见解

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摘要

Metal-organic frameworks (MOFs) are a highly versatile class of crystalline porous materials. In recent years, many diverse MOF materials have been experimentally realized, exhibiting a wide range of underlying topologies. In this work, we guide material design efforts by identifying the most promising MOF topologies for achieving high surface area frameworks. High surface area is one of the most targeted properties of MOF materials for adsorption applications, and we focus on evaluating the achievable surface area (gravimetric, volumetric, and a composite function) within each topological class by means of multiobjective optimization, illustrating that researchers can focus on a few select topologies to achieve a particular balance between gravimetric and volumetric surface area.
机译:金属有机骨架(MOF)是一类用途广泛的结晶多孔材料。近年来,已经通过实验实现了许多不同的MOF材料,这些材料展现了各种基础拓扑。在这项工作中,我们通过确定实现高表面积框架的最有希望的MOF拓扑结构来指导材料设计工作。高表面积是MOF材料在吸附应用中最具针对性的特性之一,我们专注于通过多目标优化来评估每个拓扑类别中可达到的表面积(重力,体积和复合函数),这表明研究人员可以重点介绍几种选择的拓扑,以实现重量和体积表面积之间的特定平衡。

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