Molecular networks created by charge-assisted hydrogen bonding in carboxylate salts of a bis(amidine)

Lie S.; Maris T.; Malveau C.; Beaudoin D.; Helzy F.; Wuest J.D.

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Molecular networks created by charge-assisted hydrogen bonding in carboxylate salts of a bis(amidine)

机译：在双（（）的羧酸盐中通过电荷辅助氢键形成的分子网络

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Amidines can be protonated by carboxylic acids to give amidinium carboxylates, and the ions can associate by forming multiple charge-assisted hydrogen bonds according to reliable motifs. Extended hydrogen-bonded networks can be constructed by treating suitable bis(amidines) with acids containing multiple carboxyl groups. To further explore the potential of this strategy, we have determined the structures of salts produced by treating 2,2′-bi-2-imidazoline, a cyclic bis(amidine), with oxalic, fumaric, terephthalic, and trimesic acids. The structures of the salts proved to incorporate features resulting predictably from the geometry of the ions and their ability to engage in charge-assisted hydrogen bonds.

机译：idine可以被羧酸质子化以生成am基羧酸盐，并且离子可以根据可靠的图案通过形成多个电荷辅助的氢键来缔合。扩展的氢键网络可以通过用含有多个羧基的酸处理合适的双（am）来构建。为了进一步探索该策略的潜力，我们确定了用草酸，富马酸，对苯二甲酸和均苯三酸处理2,2'-bi-2-咪唑啉（一种环状双（idine））所产生的盐的结构。盐的结构被证明具有可预测的特征，这些特征是由离子的几何形状以及它们参与电荷辅助氢键的能力所预测的。

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《Crystal growth & design》 |2013年第5期|共6页
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Lie S.; Maris T.; Malveau C.; Beaudoin D.; Helzy F.; Wuest J.D.;
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1. Molecular networks created by charge-assisted hydrogen bonding in carboxylate salts of a bis(amidine) [J] . Lie S., Maris T., Malveau C., Crystal growth & design . 2013,第5期

机译：在双（（）的羧酸盐中通过电荷辅助氢键形成的分子网络
2. Charge-assisted N-H(+)center dot center dot center dot O(-) and O-H center dot center dot center dot O(-) hydrogen bonds control the supramolecular aggregation of ferrocenedicarboxylic acid and bis-amidines [J] . Braga D., Grepioni F., De Cian A., New Journal of Chemistry . 2000,第7期

机译：电荷辅助的N-H（+）中心点中心点中心点O（-）和O-H中心点中心点中心点O（-）氢键控制二茂铁羧酸和双-的超分子聚集
3. Charge-assisted N-H~(+)…O~(-) and O-H…O~(-) hydrogen bonds control the supramolecular aggregation of ferrocenedicarboxylic acid and bis-amidines [J] . Dario Braga, Lucia Maini, Fabrizia Grepioni New Journal of Chemistry . 2000,第7期

机译：电荷辅助的N-H〜（+）…O〜（-）和O-H…O〜（-）氢键控制二茂铁羧酸和双-的超分子聚集
4. Intramolecular Hydrogen Bonding of Oxidation Intermediates of Bisphenol Derivatives in Relation to Photothermographic Activity in Silver Salt Photothermographic Systems [C] . Hiromi Akahori, Kiyokazu Morita, Ayumu Nishijima, International Symposium on Silver Halide Technology . 2004

机译：双酚衍生物氧化中间体关于银盐光热敏体系中的光热摄取活性的氧化中间体的分子内氢键
5. Molecular orbital, generalized valence bond, and complete active space calculations on transition metal compounds with agostic hydrogen and bridging carbonyls: New basis sets, geometry of trichloromethyltitanium, and bonding of bis(cyclopentadienyldicarbonylchromium). [D] . Williamson, Rodney Lowell. 1989

机译：含氢和桥联羰基的过渡金属化合物的分子轨道，广义价键和完整的活性空间计算：新的基集，三氯甲基钛的几何形状和双（环戊二烯基二羰基铬）的键合。
6. Bis(benzyltrimethylammonium) bis(4SR12SR18RS26RS)-41826-trihydroxy-12-oxido-1317-dioxaheptacyclo14.10.0.0314.0412.0611.01826.01924hexacosa-13(14)681015192123-nonaene-525-dione sesquihydrate: dimeric structure formation via O—H—O−negative charge-assisted hydrogen bonds (–CAHB) with benzyltrimethylammonium counter-ions [O] . Ravell Bengiat, Maayan Gil, Asne Klein, 2016

机译：双（苄基三甲基铵）双（4SR12SR18RS26RS）-41826-三羟基-12-氧化物-1317-二氧杂庚环14.10.0.0314.0412.0611.01826.01924 hexacosa- 13（14）681015192123-壬二烯-525-二酮倍半水合物：通过OH-O-形成二聚体结构负电荷辅助氢键（–CAHB）与苄基三甲基铵抗衡离子
7. Molecular Networks Created by Charge-Assisted Hydrogen Bonds Between Bis(aminidinium) Cations and Carboxylates, Sulfonates, Phosphonates and Phosphates [O] . Lie Chin Cheong Sharon 2013

机译：双（a）阳离子与羧酸盐，磺酸盐，膦酸盐和磷酸盐之间的电荷辅助氢键形成的分子网络

Molecular networks created by charge-assisted hydrogen bonding in carboxylate salts of a bis(amidine)

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