Preparation and Guest Release Properties of Supramolecular 3?Chlorobenzo[b]thiophene Heterocyclic Host Complex

Takashi Wakabayashi; Tomoyuki Amako; Hideyuki Tabata; Reiko Kuroda; Yoshitane Imai

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Preparation and Guest Release Properties of Supramolecular 3?Chlorobenzo[b]thiophene Heterocyclic Host Complex

机译：超分子3？氯苯并[b]噻吩杂环主体配合物的制备及释放特性

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Supramolecular 3-chlorobenzo[b]thiophene heterocyclic host complex composed of chiral (1R,2S)-2- amino-1,2-diphenylethanol was successfully prepared using 3- chlorobenzo[b]thiophene-2-carboxylic acid. Four types of guest n-alkyl alcohols could be stored in one-dimensional channel-like cavities composed of chiral 2_1-helical columnar network structures. The release properties of the guest alcohol changed depending on the length of the alkyl chain in the alcohol.

机译：使用3-氯苯并[b]噻吩-2-羧酸成功地制备了由手性（1R，2S）-2-氨基-1,2-二苯乙醇组成的超分子3-氯苯并[b]噻吩杂环主体配合物。四种客体正烷基醇可以存储在由手性2_1-螺旋柱状网络结构组成的一维通道状腔中。客体醇的释放特性根据醇中烷基链的长度而变化。

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来源
《Crystal growth & design》 |2014年第1期|共6页
作者
Takashi Wakabayashi; Tomoyuki Amako; Hideyuki Tabata; Reiko Kuroda; Yoshitane Imai;
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正文语种 eng
中图分类晶体学;
关键词
heterocyclic; structures; depending;

机译：杂环;结构;依赖;

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1. Preparation and Guest Release Properties of Supramolecular 3?Chlorobenzo[b]thiophene Heterocyclic Host Complex [J] . Takashi Wakabayashi, Tomoyuki Amako, Hideyuki Tabata, Crystal growth & design . 2014,第1期

机译：超分子3？氯苯并[b]噻吩杂环主体配合物的制备及释放特性
2. Control of release properties of guest molecules by the type of benzoheterocyclic ring in supramolecular host complexes [J] . Hige S., Shiota N., Kobayashi Y., Tetrahedron . 2012,第48期

机译：通过超分子宿主复合物中苯并杂环的类型控制客体分子的释放特性
3. Control of release properties of guest molecules by the type of benzoheterocyclic ring in supramolecular host complexes [J] . Hige S., Shiota N., Kobayashi Y., Tetrahedron . 2012,第48期

机译：通过超分子宿主复合物中苯并杂环的类型控制客体分子的释放特性
4. PREPARATION AND RELEASE PROPERTIES OF A pH-TUNABLE CARBOXYMETHYL CELLULOSE HYDROGEL/METHYLENE BLUE HOST/GUEST MODEL [C] . Yang Shaoping, Fu Shiyu, Zhou Yiming, International symposium on emerging technologies of pulping and papermaking;ISETPP . 2010

机译：可调节pH的羧甲基纤维素水/亚甲基蓝宿主/客体模型的制备和释放性能
5. Cucurbit[n]uril host -guest complexes: The effects of inclusion on the chemical reactivity and spectroscopic properties of aromatic guest molecules [D] . Wang, Ruibing 2007

机译：葫芦[n] uril主体-客体复合物：夹杂物对芳族客体分子化学反应性和光谱性质的影响
6. Supramolecular Chemistry And Self-assembly Special Feature: Supramolecular recognition: On the kinetic lability ofthermodynamically stable host–guest association complexes [O] . Andrew J. Goshe, Ian M. Steele, Christopher Ceccarelli, 2002

机译：超分子化学与自组装特殊功能：超分子识别：关于分子的动力学不稳定性热力学稳定的主客联合体
7. Supramolecular polymer hydrogels induced by host–guest interactions with di-[cyclobis(paraquat-p-phenylene)] cross-linkers: from molecular complexation to viscoelastic properties [O] . Fumagalli, Matthieu, Belal, Khaled, Guo, Hui, 2017

机译：主客体与双[[环双（百草枯-对苯撑）]交联剂的客体相互作用诱导的超分子聚合物水凝胶：从分子络合到粘弹性

Preparation and Guest Release Properties of Supramolecular 3?Chlorobenzo[b]thiophene Heterocyclic Host Complex

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