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首页> 外文期刊>Crystal growth & design >Pillared Two-Dimensional Metal?Organic Frameworks Based on a Lower-Rim Acid Appended Calix[4]arene
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Pillared Two-Dimensional Metal?Organic Frameworks Based on a Lower-Rim Acid Appended Calix[4]arene

机译:基于低R酸的杯状二维金属有机骨架[J]芳烃

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摘要

Solvothermal reactions of the lower-rim functionalized diacid calix[4]arene 25,27-bis(methoxycarboxylic, acid)-26,28-dihydroxy-4-tert-butylcalix- [4]arene, (LH_2) with Zn(NO_3)_2·6H_2O and the dipyridyl ligands 4,4′-bipyridyl (4,4′- bipy), 12-di(4-pyridyl)ethylene (DPE), or 4,4′-azopyridyl (4,4′-azopy) afforded a series of two-dimensional structures of the formulas {[Zn(4,4′-bipy)(L)]·21/4DEF}_n, (1), {[Zn_2(L)(DPE)]·DEF}_n (2), and {[Zn(OH_2)_2(L)(4,4′-azopy)]·DEF}_n, (3) (DEF = diethylformamide).
机译:下边缘官能化的二酸杯[4]芳烃25,27-双(甲氧基羧酸,酸)-26,28-二羟基-4-叔丁基杯-[4]芳烃(LH_2)与Zn(NO_3)的溶剂热反应_2·6H_2O和二吡啶基配体4,4'-联吡啶基(4,4'-联吡啶),12-二(4-吡啶基)乙烯(DPE)或4,4'-偶氮吡啶基(4,4'-偶氮基)给出了一系列{{Zn(4,4'-bipy)(L)]·21 / 4DEF} _n,(1),{[Zn_2(L)(DPE)]·DEF}的二维结构_n(2)和{[Zn(OH_2)_2(L)(4,4'-azopy)]·DEF} _n,(3)(DEF =二乙基甲酰胺)。

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