Organo-inorganic tetrameric zinc cluster with phosphate bridges. [Zn-4(HPO4)(4)(phen)(4)](H3PO4)(2)(H2O)(4)

Venegas-Yazigi D; Cubillos M; Le Fur E; Pivan JY; Garland MT; Baggio R; Spodine E

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Organo-inorganic tetrameric zinc cluster with phosphate bridges. [Zn-4(HPO4)(4)(phen)(4)](H3PO4)(2)(H2O)(4)

机译：具有磷酸桥的有机-无机四聚体锌簇。 [Zn-4（HPO4）（4）（phen）（4）]（H3PO4）（2）（H2O）（4）

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A novel molecular tetrameric zinc cluster with phosphate bridges has been synthesized by a hydrothermal method and characterized by X-ray diffraction. The structure is stabilized by neutral H3PO4 and water molecules. Both phosphorus and water oxygen atoms play a central role as connecting agents in this planar, weblike array. Protruding phenanthroline ligands bonded to the zinc atoms are present both above and below the plane, constituting the main interaction between neighboring planes, through pi-pi stacking. The distance between ring centroids varies between 3.489 and 4.109 angstrom.

机译：通过水热法合成了具有磷酸酯桥的新型分子四聚体锌簇，并通过X射线衍射对其进行了表征。该结构由中性的H3PO4和水分子稳定。磷和水氧原子在这种平面的网状阵列中均起着连接剂的核心作用。通过pi-pi堆积，在平面的上方和下方均存在与锌原子键合的突出的菲咯啉配体，构成相邻平面之间的主要相互作用。环形心之间的距离在3.489和4.109埃之间变化。

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来源
《Crystal growth & design》 |2005年第5期|共3页
作者
Venegas-Yazigi D; Cubillos M; Le Fur E; Pivan JY; Garland MT; Baggio R; Spodine E;
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正文语种 eng
中图分类晶体学;
关键词
FRAMEWORK; CHANNELS; DESIGN;

机译：框架;渠道;设计;

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1. Organo-inorganic tetrameric zinc cluster with phosphate bridges. [Zn-4(HPO4)(4)(phen)(4)](H3PO4)(2)(H2O)(4) [J] . Venegas-Yazigi D, Cubillos M, Le Fur E, Crystal growth & design . 2005,第5期

机译：具有磷酸桥的有机-无机四聚体锌簇。 [Zn-4（HPO4）（4）（phen）（4）]（H3PO4）（2）（H2O）（4）
2. Syntheses, crystal structures and magnetic properties of two new bimetallic phosphates M(phen)(H2O)(VO)(H2O)(HPO4)(2) (M = Ni, Co; phen=1,10-phenanthroline) [J] . Cui YJ, Xing Y, Li GH, International Journal of Quantum Chemistry . 2004,第9期

机译：两种新型双金属磷酸盐M（phen）（H2O）（VO）（H2O）（HPO4）（2）的合成，晶体结构和磁性能（M = Ni，Co; phen = 1,10-phenothroline）
3. Isolation of a zinc phosphate primary building unit, [C6N2H18](2+)[Zn(HPO4)(H2PO4)(2)](2-), and its transformation to an open-framework phosphate, [C6N2H18](2+)[Zn-3(H2O)(4)(HPO4)(4)](2-) [J] . Neeraj S., Rao CNR., Natarajan S. International Journal of Quantum Chemistry . 2000,第2期

机译：分离磷酸锌主要建筑单元[C6N2H18]（2 +）[Zn（HPO4）（H2PO4）（2）]（2-），并将其转变为开放骨架的磷酸盐[C6N2H18]（2+） [Zn-3（H2O）（4）（HPO4）（4）]（2-）
4. A Novel Chain-like Organic-Inorganic Hybrid Material: Hydrothermal Synthesis and Structureof H3N(CH2)4NH3 { Mn(phen)2(H2O)2Mn(phen)22MnMo12O24(HPO4)6(PO4)2(OH)6 }·4H2O [C] . International symposium on solid state chemistry in China amp; 8th Chinese national conference on solid state chemistry and inorganic synthesis : Book of abstracts . 2002

机译：一种新型的链状有机-无机杂化材料：H3N（CH2）4NH3 {Mn（phen）2（H2O） 2 Mn（phen）2 2 MnMo12O24（HPO4）6（PO4）的水热合成和结构）2（OH）6}·4H2O
5. Stabilization of tetrameric metavanadate ion by tris(110-phenanthroline)cobalt(III): Synthesis spectroscopic and X-ray structural study of Co(phen)33(V4O12)2Cl·27H2O [O] . RAJ PAL SHARMA, AJNESH SINGH, PALOTH VENUGOPALAN, -1

机译：TRIS（110-菲咯啉）钴（III）的四聚体甲烷酸盐离子的稳定化：CO（phen）3 3（V4O12）2CL·27H2O的合成光谱和X射线结构研究
6. Organo-Inorganic Tetrameric Zinc Cluster with Phosphate Bridges. Zn4(HPO4)4(phen)4(H3PO4)2(H2O)4 [O] . -1

机译：具有磷酸盐桥的有机无机四聚锌簇。 Zn4（HPO 4）4（PhO）4（H3PO4）2（H2O）4

Organo-inorganic tetrameric zinc cluster with phosphate bridges. [Zn-4(HPO4)(4)(phen)(4)](H3PO4)(2)(H2O)(4)

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