Rational Design of Lamellar π?π Stacked Organic Crystalline Materials with Short Interplanar Distance

Anjaneyulu Putta; Jeffery D. Mottishaw; Zhihua Wang; Haoran Sun

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Rational Design of Lamellar π?π Stacked Organic Crystalline Materials with Short Interplanar Distance

机译：晶面间距短的层状π？π堆积有机晶体材料的合理设计

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Organic crystalline materials having a lamellar π?π stacked structural motif with short interplanar distance are significant for many applications. By asymmetrically introducing perfluoroalkyl substituents onto and polarizable sulfur atoms into N-containing heteroaromatics, we successfully synthesized a novel type of aromatic material that preferentially forms lamellar π?π stacked crystalline materials with a interplanar π?π distance of 3.247 ?, more than 0.1 ? shorter than that of highly oriented pyrolytic graphite (HOPG) where interplanar distance ranges from 3.35 to 3.39 ?.

机译：具有短的晶面间距的层状πππ堆叠结构基序的有机晶体材料对于许多应用是重要的。通过将全氟烷基取代基不对称地引入含N的杂芳族化合物中以及将可极化的硫原子引入到含氮杂芳族化合物中，我们成功地合成了一种新型的芳香族材料，该材料优先形成层状πππ堆叠的晶体材料，其层间πππ间距为3.247π，大于0.1π。比高度取向的热解石墨（HOPG）短，其平面间距在3.35至3.39？之间。

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《Crystal growth & design》 |2014年第1期|共7页
作者
Anjaneyulu Putta; Jeffery D. Mottishaw; Zhihua Wang; Haoran Sun;
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正文语种 eng
中图分类晶体学;
关键词
crystalline; asymmetrically; interplanar;

机译：晶体;不对称;平面;

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1. Rational Design of Lamellar π?π Stacked Organic Crystalline Materials with Short Interplanar Distance [J] . Anjaneyulu Putta, Jeffery D. Mottishaw, Zhihua Wang, Crystal growth & design . 2014,第1期

机译：晶面间距短的层状π？π堆积有机晶体材料的合理设计
2. Monodisperse π–π Stacking Anthracene Dimer underrnPressure: Unique Fluorescence Behaviors and ExperimentalrnDetermination of Interplanar Distance at ExcimerrnEquilibrium Geometry [J] . Haichao Liu, Yuxiang Dai, Yu Gao, Advanced Optical Materials . 2018,第15期

机译：压力下单分散π–π堆叠蒽二聚体：独特的荧光行为和在准分子平衡几何条件下测定晶面间距离的实验
3. Monodisperse π–π Stacking Anthracene Dimer underPressure: Unique Fluorescence Behaviors and ExperimentalDetermination of Interplanar Distance at ExcimerEquilibrium Geometry [J] . Haichao Liu, Yuxiang Dai, Yu Gao, Advanced Optical Materials . 2018,第15期

机译：单分散π-π堆叠蒽二聚体压力：独特的荧光行为和实验在准分子的确定性测定跳闸距离均衡几何形状
4. Nano-Scale Lamellar Monoclinic Li2MnO3 Phase with Stacking Disorderingin Lithium-Rich and Oxygen-Deficient Li-Mn-O Cathode Materials [C] . Zhongling Xu, He Zheng, Jianbo Wang, Microscopy and microanalysis.;Microscopy and microanalysis. . -1

机译：纳米层状单斜Li2MnO3相，具有堆积无序富锂和缺氧的Li-Mn-O正极材料
5. Rational design, synthesis, and structure-property relationships of C3-symmetric chiral foldamers and surface-functionalized organic-inorganic hybrid materials. [D] . Opsitnick, Elizabeth A. 2011

机译：C3对称手性折叠剂和表面官能化的有机-无机杂化材料的合理设计，合成和结构-性质关系。
6. Disrupt and induce intermolecular interactions to rationally design organic semiconductor crystals: from herringbone to rubrene-like pitched π-stacking [O] . Chengyuan Wang, Daisuke Hashizume, Masahiro Nakano, 2020

机译：破坏并诱导分子间相互作用以合理设计有机半导体晶体：从人字形到杂液状倾斜π堆叠
7. “Disrupt and induce” intermolecular interactions to rationally design organic semiconductor crystals: from herringbone to rubrene-like pitched π-stacking [O] . Chengyuan Wang, Daisuke Hashizume, Masahiro Nakano, 2020

机译：“破坏并诱导”分子间相互作用，以合理设计有机半导体晶体：从人字形到杂液状倾斜π堆叠

Rational Design of Lamellar π?π Stacked Organic Crystalline Materials with Short Interplanar Distance

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