Supramolecular Interactions between Finite Tapes of Water Molecules and Hydrated Metal Ions To Produce Infinite Two- Dimensional Cationic Layers of Water Molecules

Geeta Hundal; Maninder Singh Hundal; Young Kyu Hwang; Jong San Chang

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Supramolecular Interactions between Finite Tapes of Water Molecules and Hydrated Metal Ions To Produce Infinite Two- Dimensional Cationic Layers of Water Molecules

机译：水分子有限带与水合金属离子之间的超分子相互作用产生无限大的二维水分子阳离子层

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摘要

A supramolecular self-assembly of finite tapes of lattice water molecules with the coordinated water molecules of hydrated metal ions forms 2D cationic layers of water molecules in the coordination complex [Ni(H_2O)_6][Ni(Pydi)_2(H_2O)_2]·4H_2O (Pydi = 2,5-pyridinedicarboxylate). It reveals yet another unique mode of the cooperative association of water molecules. The anionic layers have a well-known 2D, nonporous metal? organic framework formed by the assistance from H-bonding of coordinating water molecules.

机译：晶格水分子有限带与水合金属离子的配位水分子的超分子自组装形成配位络合物[Ni（H_2O）_6] [Ni（Pydi）_2（H_2O）_2]中水分子的二维阳离子层。 ·4H_2O（Pydi = 2,5-吡啶二羧酸酯）。它揭示了水分子协同缔合的另一种独特模式。阴离子层具有众所周知的二维无孔金属？通过配位水分子的氢键形成的有机骨架。

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《Crystal growth & design》 |2014年第1期|共5页
作者
Geeta Hundal; Maninder Singh Hundal; Young Kyu Hwang; Jong San Chang;
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原文格式 PDF
正文语种 eng
中图分类晶体学;
关键词
Supramolecular; hydrated; framework;

机译：超分子;水合;骨架;

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1. Supramolecular Interactions between Finite Tapes of Water Molecules and Hydrated Metal Ions To Produce Infinite Two- Dimensional Cationic Layers of Water Molecules [J] . Geeta Hundal, Maninder Singh Hundal, Young Kyu Hwang, Crystal growth & design . 2014,第1期

机译：水分子有限带与水合金属离子之间的超分子相互作用产生无限大的二维水分子阳离子层
2. Construction of diverse supramolecular assemblies of dimetal subunits differing in coordinated water molecules via strong hydrogen bonding interactions: Synthesis, crystal structures and spectroscopic properties [J] . Sadhika Khullar1, Sanjay K Mandal1 Journal of Chemical Sciences . 2014,第5期

机译：通过强大的氢键相互作用构建双金属亚基的不同超分子组装体，它们的配位水分子不同：合成，晶体结构和光谱性质
3. Structural investigation of metal-organic cu(ii) coordination frameworks constructed from n-donor and α, ω-dicarboxylate ligands by one pot synthesis: Zigzag strands, layered networks and its interaction with lattice water molecules [J] . Kathalikkattil A.C., Subramanian P.S., Eringathodi S. Journal of chemical crystallography . 2010,第12期

机译：通过一锅法合成由n-给体和α，ω-二羧酸酯配体构建的金属-有机cu（ii）配位框架的结构研究：之字形链，分层网络及其与晶格水分子的相互作用
4. Two dimensional thin film surface layer structure of the promising new photo-catalyst InVO_4 for water molecule decomposition with water molecules adsorbed on the surface [C] . M. Oshikiri, M. Boero, J. Ye, Ninth Annual International Conference on Composites Engineering ICCE/9 . 2002

机译：有前景的新型光催化剂InVO_4的二维薄膜表面层结构，用于水分子分解并吸附在表面上
5. Supramolecular Assembly Containing α-Helical Peptide Molecules in Lipid Bilayer Membrane and at the Air/Water Interface [D] . Fujita, Katsuhiko 1995

机译：脂质双层膜中和在空气/水界面处包含α-螺旋肽分子的超分子组装。
6. NMR observation of individual molecules of hydration water bound to DNA duplexes: direct evidence for a spine of hydration water present in aqueous solution. [O] . E Liepinsh, G Otting, K Wüthrich 1992

机译：NMR观察结合到DNA双链体的水合水分子的分子：水溶液中存在水合水脊柱的直接证据。
7. 3P-105 Analysis of cooperative modes of water and understandings of dynamical interaction between water and solute molecules through it(Water, Hydration Electrolyte,The 47th Annual Meeting of the Biophysical Society of Japan) [O] . Hiroshi Teramoto, Tamiki Komatsuzaki 2009

机译：3P-105通过IT（水，水合和电解质，日本生物物理学会47年度会议的水和溶质分子动态相互作用的合作方式分析
8. From Molecules to Devices: Supramolecular Interactions in Materials for Advanced Applications [R] . Painelli, A. , Terenziani, F. 2004

机译：从分子到器件：用于高级应用的材料中的超分子相互作用

Supramolecular Interactions between Finite Tapes of Water Molecules and Hydrated Metal Ions To Produce Infinite Two- Dimensional Cationic Layers of Water Molecules

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