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首页> 外文期刊>Advanced materials interfaces >Ti‐Substituted Keggin‐Type Polyoxotungstate as Proton and Electron Reservoir Encaged into Metal–Organic Framework for Carbon Dioxide Photoreduction
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Ti‐Substituted Keggin‐Type Polyoxotungstate as Proton and Electron Reservoir Encaged into Metal–Organic Framework for Carbon Dioxide Photoreduction

机译：Ti取代的Keggin型多氧化钨酸盐作为质子和电子储存器中的金属有机框架，用于二氧化碳光敏

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Abstract > A key challenge for photocatalystic CO <sub>2</sub> reduction is the design and synthesis of photocatalyst with remarkable performance in visible‐light absorption, CO <sub>2</sub> adsorption, and electron‐coupled proton transfer. Here a visible light–driven hybrid photocatalyst Au@NENU‐10, consisting of Au nanoparticles (NPs), Ti‐substituted keggin‐type polyoxometalate [PTi <sub>2</sub> W <sub>10</sub> O <sub>40</sub> ] 7? (PTiW), and HKUST‐1, is synthesized by the one‐pot method at atmosphere condition where PTiW acts as both electrons' and protons' reservoir, and a reactive active center is encaged into HKUST‐1 to boost CO <sub>2</sub> reduction, HKUST‐1 as a microreactor to concentrate CO <sub>2</sub> molecules, and Au NPs harvesting visible light. Notably, compared to [PW <sub>12</sub> O <sub>40</sub> ] 3? ‐encaged HKUST‐1 (NENU‐3) with an octahedron shape, the Ti‐substituted counterpart of NENU‐10 shows a cube shape with a little corner cut, which is ascribed to the higher net charge on terminal oxygen atoms of PTiW, slowing down the crystal growth along the 〈100〉 direction. Moreover, PTiW always exposes on {100} plane of HKUST‐1 in the synthesis process, stabilizing Au NPs and thus being dispersed evenly in NENU‐10. Owing to the stronger protonation of Ti?O and Ti?O?W, Au@NENU‐10 shows higher CO <sub>2</sub> reduction activity and selectivity under visible‐light irradiation (λ 420 nm), about 85.3‐fold and 5.2‐fold enhancement, respectively, corresponding to the CO <sub>2</sub> ‐to‐CO and CO <sub>2</sub> ‐to‐H <sub>2</sub> conversion in contrast to Au@NENU‐3. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 光催化作用的关键挑战 <sub> 2 </ sub> 减少是光催化剂的设计和合成，具有显着性能的可见光吸收，CO <sub> 2 </ sub> 吸附和电子耦合质子转移。这里是一个可见光驱动的杂交光催化剂Au @ nenu-10，由Au纳米颗粒（NPS）组成，Ti取代的Keggin型聚氧酸盐[PTI <sub> 2 </ sub> W. <sub> 10 </ sub> O. <sub> 40 </ sub> ] 7？</ sup> （PTIW）和HKUST-1由一个罐方法在大气条件下合成，其中PTIW作为电子'和质子的储存器，并将反应活性中心摄藏在HKust-1中以加强CO <sub> 2 </ sub> 减少，HKUST-1作为微光反应器浓缩CO <sub> 2 </ sub> 分子，以及收获可见光的Au nps。值得注意的是，与[PW相比 <sub> 12 </ sub> O. <sub> 40 </ sub> ] 3？</ sup> 具有八面体形状的HKUST-1（Nenu-3），Nenu-10的Ti取代对应物显示了具有小角落切割的立方体形状，其归因于PTIW的末端氧原子上的净电荷较高，沿<100>方向下晶体生长。此外，PTIW总是在合成过程中曝光HKUST-1的{100}平面，稳定Au nps并因此在Nenu-10中均匀分散。由于TI和TI的质量较强，o？W，AU @ Nenu-10显示了更高的CO <sub> 2 </ sub> 可见光照射（λ＆ 420nm）下的减少活性和选择性，分别为约85.3倍和5.2倍的增强，对应于CO <sub> 2 </ sub> -to-co和co <sub> 2 </ sub> -TO-H. <sub> 2 </ sub> 与au @ nenu-3相比，转换。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-18063/'>《Advanced materials interfaces》</a> <b style="margin: 0 2px;">|</b><span>2018年第21期</span><b style="margin: 0 2px;">|</b><span>共7页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liu Shu‐Mei&option=202" target="_blank" rel="nofollow">Liu Shu‐Mei;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhang Zhong&option=202" target="_blank" rel="nofollow">Zhang Zhong;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Li Xiaohui&option=202" target="_blank" rel="nofollow">Li Xiaohui;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jia Hongjie&option=202" target="_blank" rel="nofollow">Jia Hongjie;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ren Mingwen&option=202" target="_blank" rel="nofollow">Ren Mingwen;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liu Shuxia&option=202" target="_blank" rel="nofollow">Liu Shuxia;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>College of Materials Science and EngineeringJilin UniversityChangchun Jilin 130022 China;</p> <p>Key Laboratory of Polyoxometalate Science of the Ministry of EducationNortheast Normal UniversityChangchun Jilin 130024 China;</p> <p>Key Laboratory of Polyoxometalate Science of the Ministry of EducationNortheast Normal UniversityChangchun Jilin 130024 China;</p> <p>College of Materials Science and EngineeringJilin UniversityChangchun Jilin 130022 China;</p> <p>College of Materials Science and EngineeringJilin UniversityChangchun Jilin 130022 China;</p> <p>Key Laboratory of Polyoxometalate Science of the Ministry of EducationNortheast Normal UniversityChangchun Jilin 130024 China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/6960.html" title="特种结构材料">特种结构材料;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=carbon dioxide reduction&option=203" rel="nofollow">carbon dioxide reduction;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=metal–organic frameworks&option=203" rel="nofollow">metal–organic frameworks;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=polyoxometalates&option=203" rel="nofollow">polyoxometalates;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=titanium substitution&option=203" rel="nofollow">titanium substitution;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=visible‐light driven catalysis&option=203" rel="nofollow">visible‐light driven catalysis;</a> </p> <div class="translation"> 机译：二氧化碳减少;金属 - 有机框架;多氧化硅酸盐;钛替代;可见光驱动的催化; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704022434759.html">Ti‐Substituted Keggin‐Type Polyoxotungstate as Proton and Electron Reservoir Encaged into Metal–Organic Framework for Carbon Dioxide Photoreduction</a> <b>[J]</b> . <span> <a 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href="/academic-journal-cn_china-science-technology-information_thesis/0201264808148.html">二聚体结构的Keggin型磷钨酸盐在环己醇氧化中的催化作用</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=薛莹雪&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 薛莹雪</a> <span> <a href="/journal-cn-38487/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 中国科技信息 </a> </span> <span> . 2014</span><span>,第021期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-nanjing-normal-university-natural-science-edition_thesis/0201250288566.html">TiⅣ取代的Keggin型多金属氧酸盐的合成及其在水溶液中的行为</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘红霞&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 刘红霞</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=杨春&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,杨春</a> <span> <a href="/journal-cn-4678/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 南京师大学报（自然科学版） </a> </span> <span> . 2007</span><span>,第002期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-14758_thesis/020221231821.html">超临界二氧化碳改性全氟磺酸质子交换膜应用于直接甲醇燃料电池</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=苏力军&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 苏力军</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=裴素鹏&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,裴素鹏</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李磊&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,李磊</a> <span> <a href="/conference-cn-14758/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 第三届膜分离技术在冶金工业中应用研讨会 </a> <span> <span> . 2009</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020312761933.html">V、Mn取代的Keggin型锗钨酸盐的合成及催化氧化性质的研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李冬柳&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 李冬柳</a> <span> . 2009</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/061204359803.html">基于Zn取代Keggin型杂多钨酸盐的有机-无机复合物、合成方法及应用</a> <b>[P]</b> . <span> 中国专利： CN110252404B </span> <span> . 2021.04.23</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120101057406.html">基于Zn取代Keggin型杂多钨酸盐的有机-无机复合物、合成方法及应用</a> <b>[P]</b> . <span> 中国专利： CN110252404A </span> <span> . 2019-09-20</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130412621576.html">Method for adsorbing carbon dioxide onto porous metal-organic framework materials, method for cooling porous metal-organic framework materials, method for obtaining aldehyde using porous metal-organic framework materials, and method for warming porous metal-organic framework materials</a> <b>[P]</b> . <span> 外国专利： <!-- 美国专利： --> US9309264B2 </span> <span> . 2016-04-12</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：将二氧化碳吸附到多孔金属有机骨架材料上的方法，冷却多孔金属有机骨架材料的方法，使用多孔金属有机骨架材料获得醛的方法以及加热多孔金属有机骨架材料的方法 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130415801438.html">METHOD FOR ADSORBING CARBON DIOXIDE ONTO POROUS METAL-ORGANIC FRAMEWORK MATERIALS, METHOD FOR COOLING POROUS METAL-ORGANIC FRAMEWORK MATERIALS, METHOD FOR OBTAINING ALDEHYDE USING POROUS METAL-ORGANIC FRAMEWORK MATERIALS, AND METHOD FOR WARMING POROUS METAL-ORGANIC FRAMEWORK MATERIALS</a> <b>[P]</b> . <span> 外国专利： <!-- 美国专利： --> US2015073164A1 </span> <span> . 2015-03-12</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：将二氧化碳吸附在多孔金属有机框架材料上的方法，冷却多孔金属有机框架材料的方法，使用多孔金属有机框架材料获取醛的方法以及对多孔金属材料进行保温的方法 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130435827218.html">The compound photocatalysts for carbon dioxide reduction and carbon dioxide photoreduction mannered null precious metal</a> <b>[P]</b> . <span> 外国专利： <!-- 日本专利： --> JP3876305B2 </span> <span> . 2007-01-31</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：用于二氧化碳还原和二氧化碳光还原的复合光催化剂 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" 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