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首页> 外文期刊>Advanced materials interfaces >Templated Synthesis of Nickel?Iron Layered Double Hydroxide for Enhanced Electrocatalytic Water Oxidation: Towards the Development of Non‐Precious‐Metal Catalysts
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Templated Synthesis of Nickel?Iron Layered Double Hydroxide for Enhanced Electrocatalytic Water Oxidation: Towards the Development of Non‐Precious‐Metal Catalysts

机译：镍的模特合成铁层的双氢氧化物，用于增强电催化水氧化：朝向非珍贵金属催化剂的发育

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Abstract >Layered double hydroxides (LDHs) have recently attracted intense research attention because of their applications in the development of highly active and cost‐effective electrocatalysts for the oxygen evolution reaction and in the fields of drug delivery, energy storage, for example. In this work, we report a cheap and simple route for the synthesis of nickel–iron LDH (Ni?Fe LDH) using an iron‐based metal?organic framework, Fe‐MIL‐88 as a template. The prepared Ni?Fe LDH is characterized by scanning electron microscopy, transmission electron microscopy, X‐ray photoelectron spectroscopy, Fourier‐transform infrared spectroscopy and X‐ray diffraction techniques. Ni?Fe LDH is found to be highly active and stable for water oxidation in alkaline solution as compared to commercial Pt/C. The concept of using a metal?organic framework as a structure‐directing agent to synthesize Ni?Fe LDH and the use of the material for the oxygen evolution reaction is explored for the first time. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract XMLNS =“http://www.wiley.com/namespaces/wiley”type =“main”xml：lang =“en”> <标题类型=“main”>抽象</ title> >分层双氢氧化物（LDHS）最近吸引了激烈的研究，因为它们在氧气进化反应和药物递送领域的高活性和成本效率的电催化剂的发展中的应用，例如，储能。在这项工作中，我们使用铁基金属α有机框架，Fe-MIL-88作为模板来报告一种廉价而简单的途径。制备的NiαFeLDH的特征在于扫描电子显微镜，透射电子显微镜，X射线光电子能谱，傅里叶变换红外光谱和X射线衍射技术。与商业Pt / c相比，发现NiαFeLDH对于碱性溶液中的水氧化非常活跃和稳定。使用金属的概念？有机框架作为合成Ni的结构引导剂和用于合成氧气进化反应的材料的使用。</ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-18063/'>《Advanced materials interfaces》</a> <b style="margin: 0 2px;">|</b><span>2017年第12期</span><b style="margin: 0 2px;">|</b><span>共6页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yadav Dharmendra Kumar&option=202" target="_blank" rel="nofollow">Yadav Dharmendra Kumar;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ganesan Vellaichamy&option=202" target="_blank" rel="nofollow">Ganesan Vellaichamy;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Sonkar Piyush Kumar&option=202" target="_blank" rel="nofollow">Sonkar Piyush Kumar;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Gupta Rupali&option=202" target="_blank" rel="nofollow">Gupta Rupali;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of Chemistry Institute of ScienceBanaras Hindu UniversityVaranasi- 221005 India;</p> <p>Department of Chemistry Institute of ScienceBanaras Hindu UniversityVaranasi- 221005 India;</p> <p>Department of Chemistry Institute of ScienceBanaras Hindu UniversityVaranasi- 221005 India;</p> <p>Department of Chemistry Institute of ScienceBanaras Hindu UniversityVaranasi- 221005 India;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/6960.html" title="特种结构材料">特种结构材料;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=electrocatalysis&option=203" rel="nofollow">electrocatalysis;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=electrochemical impedence spectroscopy&option=203" rel="nofollow">electrochemical impedence spectroscopy;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=layered double hydroxides&option=203" rel="nofollow">layered double hydroxides;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=metal?organic frameworks&option=203" rel="nofollow">metal?organic frameworks;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=oxygen evolution reaction&option=203" rel="nofollow">oxygen evolution reaction;</a> </p> <div class="translation"> 机译：电寄生分析;电化学阻抗光谱;层叠双氢氧化物;金属？有机框架;氧气进化反应; 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