>A new bisolvent approach is introduced to overcome the limitation of wet chemical routes of a semiconducting'/> Role of Water in the Dynamic Crystallization of CuTCNQ for Enhanced Redox Catalysis (TCNQ = Tetracyanoquinodimethane)
  • 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>Advanced materials interfaces >Role of Water in the Dynamic Crystallization of CuTCNQ for Enhanced Redox Catalysis (TCNQ = Tetracyanoquinodimethane)
【24h】

Role of Water in the Dynamic Crystallization of CuTCNQ for Enhanced Redox Catalysis (TCNQ = Tetracyanoquinodimethane)

机译：水在CutCNQ动态结晶中的作用，增强氧化还原催化（TCNQ =四环喹啉二甲烷）

获取原文
获取原文并翻译 | 示例
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

>A new bisolvent approach is introduced to overcome the limitation of wet chemical routes of a semiconducting phase I CuTCNQ (7,7,8,8‐tetracyanoquinodimethane) synthesis, which currently does not allow these materials to be grown beyond certain dimensions (10–15 μm). The use of water as a cosolvent during acetonitrile‐mediated conventional synthesis of CuTCNQ allows a dynamic control over its crystallization and dissolution process through favorably shifting the reaction equilibrium. This enables CuTCNQ structures of unique morphologies with secondary growth, alongside dimensions exceeding 100 μm to be produced. These new morphologies of phase I CuTCNQ show remarkable promise in redox catalysis over their conventional counterparts by facilitating efficient charge transfer at the catalyst–reactant interface. As catalytic, sensing, and electronic performance of materials strongly depend upon their morphological characteristics, the concepts introduced here have potential applicability for controllable fabrication of a range of metal‐organic charge transfer complexes of technological importance.
机译： 引入了一种新的双溶解方法来克服半导体I型Cuccnq（7,7,8,8-四环二甲喹甲烷）合成的湿化学途径的限制，这目前不允许这些材料长出某些尺寸（ 10-15μm）。在乙腈介导的CutCNQ期间使用水作为阳离子的CutcNQ允许通过有利地移位反应平衡，动态控制通过结晶和溶解过程。这使得具有次级生长的独特形态的CutCNQ结构，宽度超过100μm的尺寸。通过促进催化剂反应物界面的有效电荷转移，这些新的阶段I CutCNQ表现出氧化还原催化剂的卓越许可。作为催化，感测和材料的电子性能强烈取决于它们的形态特征，这里介绍的概念具有可控制的制造一系列金属 - 有机电荷转移复合物的技术重要性。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号