On‐Site Surface Coordination Complexation via Mechanochemistry for Versatile Metal–Phenolic Networks Films

Kang Junjie; Bai Guoqiang; Ma Shuanhong; Liu Xinghuan; Ma Zhiyuan; Guo Xuhong; Wang Xiaolong; Dai Bin; Zhou Feng; Jia Xin

摘要

Abstract >The development of functional metal–phenolic networks (MPNs) films by a simple and green strategy on metallic plane substrates for surface modification is a big challenge. Herein, tribochemistry, as an effective and robust method to prepare MPNs films with versatile applications and controllable thickness (≈1.5 nm to 2.2 μm) by surface coordination complexation derived from tannic acid (TA) and metal oxides or ions (M) on plane substrates, is reported. The mechanism of the formation of TA‐M films is investigated in detail, showing that films are constructed by two‐layer structures. At the bottom of films, the chelation of TA active moieties and M is triggered by friction, facilitating the coating growth and reducing the friction coefficient. There is a downward trend in the concentration of M with the thickness of films increasing, which is attributed to the diffusion of metal ions. As a result, the dominant structure of films changes into the hydrogen bonding or π–π stacking interaction among oligomers derived from coupling of the TA active moieties. Such facile surface modification strategy can broaden in situ mechanochemical synthesis of functional layers and open a promising route for the design of patterning, antifouling, and controlled release coatings. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> >通过在金属平面底板上通过用于表面改性的金属平面基板的简单和绿色策略的开发是一个很大的挑战。在本文中，作为一种有效且稳健的方法，以通过衍生自鞣酸（TA）和金属氧化物或离子基板上的金属氧化物或离子（M）的表面配位络合来制备具有通用应用和可控厚度（≈1.5nm至2.2μm）的MPNS膜据报道。详细研究了Ta-M膜的形成机制，表明薄膜由双层结构构成。在薄膜的底部，通过摩擦触发TA活性部分和M的螯合，促进涂层生长并降低摩擦系数。薄膜厚度增加的M浓度下降趋势，其归因于金属离子的扩散。结果，薄膜的主导结构变为衍生自TA活性部分偶联的低聚物之间的氢键或π-π堆叠相互作用。这种容易表面改性策略可以拓宽功能层的原位机械化学合成，并打开有希望的途径，用于设计图案化，防污和控制释放涂层。</ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-18063/'>《Advanced materials interfaces》</a> <b style="margin: 0 2px;">|</b><span>2019年第5期</span><b style="margin: 0 2px;">|</b><span>共11页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kang Junjie&option=202" target="_blank" rel="nofollow">Kang Junjie;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Bai Guoqiang&option=202" target="_blank" rel="nofollow">Bai Guoqiang;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ma Shuanhong&option=202" target="_blank" rel="nofollow">Ma Shuanhong;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liu Xinghuan&option=202" target="_blank" rel="nofollow">Liu Xinghuan;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ma Zhiyuan&option=202" target="_blank" rel="nofollow">Ma Zhiyuan;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Guo Xuhong&option=202" target="_blank" rel="nofollow">Guo Xuhong;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wang Xiaolong&option=202" target="_blank" rel="nofollow">Wang Xiaolong;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Dai Bin&option=202" target="_blank" rel="nofollow">Dai Bin;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhou Feng&option=202" target="_blank" rel="nofollow">Zhou Feng;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jia Xin&option=202" target="_blank" rel="nofollow">Jia Xin;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>School of Chemistry and Chemical Engineering/Key Laboratory for Green Processing of Chemical Engineering of Xinjiang BingtuanShihezi UniversityShihezi 832003 P. R. China;</p> <p>School of Chemistry and Chemical Engineering/Key Laboratory for Green Processing of Chemical Engineering of Xinjiang BingtuanShihezi UniversityShihezi 832003 P. R. China;</p> <p>State Key Laboratory of Solid LubricationChinese Academy of SciencesLanzhou 730000 P. R. China;</p> <p>School of Chemistry and Chemical Engineering/Key Laboratory for Green Processing of Chemical Engineering of Xinjiang BingtuanShihezi UniversityShihezi 832003 P. R. China;</p> <p>Department of ChemistryUniversité de MontréalC. P. 6128 Succursale Centre‐ville Montreal QC H3C 3J7 Canada;</p> <p>State Key Laboratory of Chemical EngineeringEast China University of Science and TechnologyShanghai 200237 P. R. China;</p> <p>State Key Laboratory of Solid LubricationChinese Academy of SciencesLanzhou 730000 P. R. China;</p> <p>School of Chemistry and Chemical Engineering/Key Laboratory for Green Processing of Chemical Engineering of Xinjiang BingtuanShihezi UniversityShihezi 832003 P. R. China;</p> <p>State Key Laboratory of Solid LubricationChinese Academy of SciencesLanzhou 730000 P. R. China;</p> <p>School of Chemistry and Chemical Engineering/Key Laboratory for Green Processing of Chemical Engineering of Xinjiang BingtuanShihezi UniversityShihezi 832003 P. R. China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/6960.html" title="特种结构材料">特种结构材料;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=active moieties&option=203" rel="nofollow">active moieties;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=coordination complexation&option=203" rel="nofollow">coordination complexation;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=mechanochemistry&option=203" rel="nofollow">mechanochemistry;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=metal–phenolic networks&option=203" rel="nofollow">metal–phenolic networks;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=multifunctional coatings&option=203" rel="nofollow">multifunctional coatings;</a> </p> <div class="translation"> 机译：积极的部分;协调络合;机械化学;金属 - 酚醛网络;多功能涂料; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704022435381.html">Metal‐Phenolic Networks Films: On‐Site Surface Coordination Complexation via Mechanochemistry for Versatile Metal–Phenolic Networks Films (Adv. 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initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：通过机械化学（研磨或研磨），其制备方法，其外膜/遮瑕/紫外线吸收剂，其自组装涂料，其外膜材料或其表面，其染发剂及其表面，其染发剂及其表面其它用途 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130461148589.html">Ligand stabilized +1 metal beta-diketonate coordination complexes and their use in chemical vapor deposition of metal thin films</a> <b>[P]</b> . <span> 外国专利：  US5220044A </span> <span> . 1993-06-15</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：配体稳定的+1金属β-二酮酸酯配合物及其在金属薄膜化学气相沉积中的用途 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130462684428.html">Ligand stabilized +1 metal beta-diketonate coordination complexes and their use in chemical vapor deposition of metal thin films</a> <b>[P]</b> . <span> 外国专利：  US5096737A 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