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A new organically templated zinc phosphite synthesized in phosphorous acid flux and its hydrothermal analogue

机译:亚磷酸助熔剂合成的新型有机模板化亚磷酸锌及其水热类似物

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摘要

A new organically templated zinc phosphite, (H(2)bbp)(2)center dot Zn-6(HPO3)(8) (1) (bbp = 1,3-bis(4-pyridyl) propane), has been synthesized in a water-free flux of H3PO3. This compound possesses a new layered structure different from the analogue obtained in the corresponding hydrothermal synthesis, Zn(bbp)(0.5)(HPO3)center dot 0.5H(2)O (2). Crystal data: 1, monoclinic, P2(1)/c, a = 9.3364(5) angstrom, b = 14.8119(7) angstrom, c = 33.6668(8) angstrom, beta = 91.004(3)degrees, V = 4655.1(4) angstrom(3), Z = 4; 2, monoclinic, P2, a = 11.392(4) angstrom, b = 5.199(2) angstrom, c = 15.863(6) angstrom, beta = 106.329(5)degrees, V = 901.5(6) angstrom(3), Z = 4.
机译:合成了一种新的有机模板化亚磷酸锌((H(2)bbp)(2)中心点Zn-6(HPO3)(8)(1)(bbp = 1,3-双(4-吡啶基)丙烷)在无水的H3PO3中该化合物具有不同于相应水热合成中获得的类似物Zn(bbp)(0.5)(HPO3)中心点0.5H(2)O(2)的新层状结构。晶体数据:1,单斜晶,P2(1)/ c,a = 9.3364(5)埃,b = 14.8119(7)埃,c = 33.6668(8)埃,beta = 91.004(3)度,V = 4655.1( 4)埃(3),Z = 4; 2,单斜,P2 / n,a = 11.392(4)埃,b = 5.199(2)埃,c = 15.863(6)埃,beta = 106.329(5)度,V = 901.5(6)埃(3) ,Z = 4。

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