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An (8,3)-a 3D coordination network and concomitant three-connected supramolecular isomers

机译:(8,3)-3D配位网络和伴随的三连接超分子异构体

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摘要

An unprecedented (8,3)-a 3D coordination network was synthesized using crystal engineering strategies as one of three concomitant supramolecular isomers of the general formula [Cu-2(tae)(bipy)(2)]center dot 2NO(3)(-)center dot xS (bipy) 4,4'-bipyridine; tae = dibasic tetraacetylethane; S = solvent: H2O/MeOH). The (8,3)-a network yields optically active single crystals with 58% solvent-accessible volume, despite 4-fold interpenetration.
机译:使用晶体工程策略合成了前所未有的(8,3)-3D配位网络,将其作为通式[Cu-2(tae)(bipy)(2)]中心点2NO(3)(的三种伴随超分子异构体之一)( -)中心点xS(bipy)4,4'-联吡啶; tae =二元四乙酰基乙烷; S =溶剂:H 2 O / MeOH)。尽管互穿四倍,但(8,3)-a网络可产生具有58%溶剂可及体积的旋光单晶。

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