Temperature-Related Synthesis of Two Anionic Metal-Organic Frameworks with Distinct Performance in Organic Dye Adsorption

Jia Yan-Yuan; Ren Guo-Jian; Li Ai-Lin; Zhang Li-Zhu; Feng Rui; Zhang Ying-Hui; Bu Xian-He

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Temperature-Related Synthesis of Two Anionic Metal-Organic Frameworks with Distinct Performance in Organic Dye Adsorption

机译：与温度相关的两种在有机染料吸附中具有不同性能的阴离子金属有机骨架的合成

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In this paper, two 3D anionic metal-organic frameworks, [(CH3CH2)(2)NH2]center dot[Zn(BTC)(1/3)(PyC)]center dot 1/2CH(3)CN center dot 2H(2)O (NKU-102) and [(CH3CH2)(2)NH2]center dot[Zn-2(BTC) (PyC)]center dot 1.5H(2)O center dot DEF (NKU-103), were constructed from the same reaction system at different temperature. Though both are of anionic framework, NKU-102 possesses a sealed 3D framework based on octahedral cage and shows negligible adsorption capacity of organic dyes, whereas NKU-103 features an open triangular microchannel surrounded by two types of helical chains, and thus exhibits outstanding size-selective adsorption toward small cationic organic dyes.

机译：在本文中，两个3D阴离子金属有机骨架，[（CH3CH2）（2）NH2]中心点[Zn（BTC）（1/3）（PyC）]中心点1 / 2CH（3）CN中心点2H（构造了2）O（NKU-102）和[（CH3CH2）（2）NH2]中心点[Zn-2（BTC）（PyC）]中心点1.5H（2）O中心点DEF（NKU-103）来自同一反应体系的温度不同。尽管两者均为阴离子骨架，但NKU-102拥有基于八面体笼的密封3D骨架，并显示出对有机染料的吸附能力可忽略不计，而NKU-103具有一个开放的三角形微通道，被两种类型的螺旋链包围，因此具有出色的尺寸对小型阳离子有机染料的选择性吸附。

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《Crystal growth & design》 |2016年第10期|共5页
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Jia Yan-Yuan; Ren Guo-Jian; Li Ai-Lin; Zhang Li-Zhu; Feng Rui; Zhang Ying-Hui; Bu Xian-He;
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中图分类晶体学;
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1. Temperature-Related Synthesis of Two Anionic Metal-Organic Frameworks with Distinct Performance in Organic Dye Adsorption [J] . Jia Yan-Yuan, Ren Guo-Jian, Li Ai-Lin, Crystal growth & design . 2016,第10期

机译：与温度相关的两种在有机染料吸附中具有不同性能的阴离子金属有机骨架的合成
2. High-performance adsorption and separation of anionic dyes in water using a chemically stable graphene-like metal-organic framework [J] . Li Jun-Jiao, Wang Chong-Chen, Fu Hui-fen, Dalton transactions: An international journal of inorganic chemistry . 2017,第31期

机译：使用化学稳定的石墨烯 - 样金属 - 有机框架在水中高性能吸附和分离阴离子染料
3. An Anionic Nanotubular Metal-Organic Framework for High-Capacity Dye Adsorption and Dye Degradation in Darkness [J] . Deng Shu-Qi, Miao Yi-Ling, Tan Yu-Ling, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2019,第20期

机译：用于高容量染料吸附和染料在黑暗中降解的阴离子纳米管金属 - 有机框架
4. Dyes Adsorption on Cu_3(BTC)_2 Metal-Organic Framework [C] . S. Loera-Serna, J. Garcia-Ortiz, E. Ortiz National SBIR/STTR conference;Annual nanotech conference and expo;Annual TechConnect world innovation conference expo . 2016

机译：染料在Cu_3（BTC）_2金属有机骨架上的吸附
5. Synthesis and Adsorption Experiments with Metal-Organic Frameworks for High School and Undergraduate Laboratory Settings [D] . Holley, Kate. 2019

机译：高中和本科实验室环境金属有机框架的合成与吸附试验
6. Confinement of pyridinium hemicyanine dye within an anionic metal-organic framework for two-photon-pumped lasing [O] . Jiancan Yu, Yuanjing Cui, Hui Xu, -1

机译：吡啶金属半菁染料在阴离子金属-有机骨架内的限制用于双光子泵浦激光
7. Temperature-Related Synthesis of Two Anionic MetalOrganic Frameworks with Distinct Performance in Organic Dye Adsorption [O] . -1

机译：与有机染料吸附不同性能的两个阴离子金属有机框架的温度相关合成

Temperature-Related Synthesis of Two Anionic Metal-Organic Frameworks with Distinct Performance in Organic Dye Adsorption

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