Synthesis, characterization, and thermal study of a T4(2)6(2) water tape in a proton-transfer salt host

Li M; Chen SP; Xiang JF; He HJ; Yuan LJ; Sun JT

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Synthesis, characterization, and thermal study of a T4(2)6(2) water tape in a proton-transfer salt host

机译：质子转移盐宿主中T4（2）6（2）水带的合成，表征和热研究

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An ice-like T4(2) 6(2) water tape was self-assembled in a novel proton-transfer salt, (enH(2))(3)[Zn(AEDP)(2)]center dot 6H(2)O(1), which bonds to the salt host via hydrogen bonds. Thermogravimetry analysis shows that the water tape can change to tetramer water clusters by heating at 100 degrees C, which are completely removed at 200 degrees C. Interestingly, the dehydrated complex can be regenerated in water vapor.

机译：一条冰状的T4（2）6（2）水带在新型质子转移盐中自组装，（enH（2））（3）[Zn（AEDP）（2）]中心点6H（2） O（1），它通过氢键与盐主体结合。热重分析表明，通过在100摄氏度下加热，水带可以变成四聚体水簇，在200摄氏度下可以完全除去。有趣的是，脱水的络合物可以在水蒸气中再生。

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来源
《Crystal growth & design》 |2006年第6期|共3页
作者
Li M; Chen SP; Xiang JF; He HJ; Yuan LJ; Sun JT;
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正文语种 eng
中图分类晶体学;
关键词
ORGANIC SUPRAMOLECULAR COMPLEX; SELF-ASSEMBLED CHAIN; GAS-SOLID REACTION; FRAMEWORK STRUCTURE; (H2O)(10) CLUSTER; CRYSTAL HOST; CYCLIC HEXAMERS; ACID; MOLECULES; STATE;

机译：有机超分子复合物;自组装链;气固反应;骨架结构;（H2O）（10）团簇;晶体主体;循环六方体;酸;分子;状态;

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1. Synthesis, characterization, and thermal study of a T4(2)6(2) water tape in a proton-transfer salt host [J] . Li M, Chen SP, Xiang JF, Crystal growth & design . 2006,第6期

机译：质子转移盐宿主中T4（2）6（2）水带的合成，表征和热研究
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Synthesis, characterization, and thermal study of a T4(2)6(2) water tape in a proton-transfer salt host

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