Hydrogen-bonded 3-D network structures of lanthanide aquo ions and 4,4 '-bipyridine with carbaborane anions

Cunha-Silva L; Westcott A; Whitford N; Hardie MJ

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Hydrogen-bonded 3-D network structures of lanthanide aquo ions and 4,4 '-bipyridine with carbaborane anions

机译：镧系元素水族离子和4,4'-联吡啶与碳硼烷阴离子的氢键3-D网络结构

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A series of three-dimensional (3-D) hydrogen-bonded structures of lanthanide aquo ions and 4,4'-bipyridine (bpy) or protonated bpyH(+) as ligands and hydrogen-bonding tectons have been characterized by single-crystal X-ray crystallography, with both Cl- and [Co(C2B9H11)(2)](-) counteranions. All show related structures with unidirectional rectangular channels filled by additional bpy molecules for the complexes [Yb(H2O)(8)](bpy)(2.5)Cl-3-6.5(H2O) and [Yb(H2O)(8)](4)(bpy)(9.5)Cl-12-24.5(H2O) or by [Co(C2B9H11)(2)](-) anions for the complexes [Ln(bpy)(H2O)(8)](2)(bpy)(10)[Co(C2B9H11)(2)](6)-1.5(EtOH)-15(H2O) where Ln = La, Ce, [Sm(H2O)(5)(bpy)(2)(EtOH)]-[Sm(H2O)(6)(bpyH)(EtOH)](bpyH)(bpy)(10)[Co(C2B9H)(2)](8)-EtOH-9(H2O), and [Ln(H2O)(6)(bpy)(bpyH(0.5))](2)[Ln(H2O)(7)(bpy)](bpyH)(2)-(bpy)(14)[Co(C2B9H11)(2)](12)-n(EtOH)-5(H2O) where Ln = Gd, Tb, and Ho. The smaller (CB11H12)(-) anion does not template a similar structure; instead the complex [(bpyH)(3)(bpy)(CB11H12)(3)] is isolated with a one-dimensional (1-D) hydrogen-bonded ladder structure.

机译：镧系元素水离子和4,4'-联吡啶（bpy）或质子化的bpyH（+）作为配体和氢键构造的一系列三维（3-D）氢键结构已通过单晶X表征射线晶体学，同时带有Cl-和[Co（C2B9H11）（2）]（-）抗衡阴离子。所有都显示了具有单向矩形通道的相关结构，该矩形通道由用于复合物[Yb（H2O）（8）]（bpy）（2.5）Cl-3-6.5（H2O）和[Yb（H2O）（8）]（ 4）（bpy）（9.5）Cl-12-24.5（H2O）或配合物[Ln（bpy）（H2O）（8）]（2）（）的[Co（C2B9H11）（2）]（-）阴离子bpy）（10）[Co（C2B9H11）（2）]（6）-1.5（EtOH）-15（H2O）其中Ln = La，Ce，[Sm（H2O）（5）（bpy）（2）（EtOH ）]-[Sm（H2O）（6）（bpyH）（EtOH）]（bpyH）（bpy）（10）[Co（C2B9H）（2）]（8）-EtOH-9（H2O）和[Ln （H2O）（6）（bpy）（bpyH（0.5））]（2）[Ln（H2O）（7）（bpy）]（bpyH）（2）-（bpy）（14）[Co（C2B9H11）（ 2）]（12）-n（EtOH）-5（H2O），其中Ln = Gd，Tb和Ho。较小的（CB11H12）（-）阴离子没有模板化相似的结构;取而代之的是，复合物[（bpyH）（3）（bpy）（CB11H12）（3）]是通过一维（1-D）氢键梯形结构分离的。

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《Crystal growth & design》 |2006年第3期|共10页
作者
Cunha-Silva L; Westcott A; Whitford N; Hardie MJ;
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正文语种 eng
中图分类晶体学;
关键词
WEAKLY COORDINATING ANIONS; CRYSTAL-STRUCTURES; COBALT(III) BIS(DICARBOLLIDE); SOLID-STATE; SUPRAMOLECULAR CHEMISTRY; CARBORANE ANIONS; COMPLEXES; CYCLOTRIVERATRYLENE; FRAMEWORKS; ASSEMBLIES;

机译：弱配位阴离子;晶体结构;双（钴）双（钴）钴;固态;超分子化学;碳硼烷阴离子;络合物;环戊三烯;骨架;组合物;

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专利

1. Hydrogen-bonded 3-D network structures of lanthanide aquo ions and 4,4 '-bipyridine with carbaborane anions [J] . Cunha-Silva L, Westcott A, Whitford N, Crystal growth & design . 2006,第3期

机译：镧系元素水族离子和4,4'-联吡啶与碳硼烷阴离子的氢键3-D网络结构
2. One-dimensional coordination polymers with phenyl-carbaborane anions: Ag(I)/4,4 '-bipyridine and 2,3-bis-(2-pyridyl)pyrazine complexes [J] . Cunha-Silva L, Ahmad R, Carr MJ, Crystal growth & design . 2007,第4期

机译：与苯基-碳硼烷阴离子的一维配位聚合物：Ag（I）/ 4,4'-联吡啶和2,3-双-（2-吡啶基）吡嗪配合物
3. Novel hydrogen-bonded three-dimensional networks encapsulating one-dimensional covalent chains: [M(4,4 '-bipy)(H2O)4](4-abs)2 center dot nH(2)O (4,4 '-bipy=4,4 '-Bipyridine; 4-abs=4-aminobenzenesulfonate) (M=Co, n=1; M=Mn, n=2) [J] . Wang YH., Feng LY., Li YG., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2002,第24期

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4. Synthesis, Structures and Properties of Two New Three-dimensional Ce(lll) Coordination Polymers with 2,2'-bipyridine-4,4'-dicarboxylic Acid [C] . Ruiping Zheng, Huiyuan Chen, Junjie He International Conference on Advanced Engineering Materials and Technology . 2013

机译：两种新三维Ce（LLL）配位聚合物的合成，结构和性质用2,2'-硼烷-4,4'-二羧酸
5. Host -guest interactions and photophysical properties within 4,4'-bipyridine-derived templated and non-templated metal-organic framework materials of the lanthanide elements and calcium [D] . de Lill, Daniel Thomas 2008

机译：镧系元素和钙的4,4'-联吡啶衍生的模板化和非模板化金属有机骨架材料中的主体与客体的相互作用和光物理性质
6. Crystal structure of a host–guest complex of the tris-urea receptor 3-(4-nitrophenyl)-11-bis{2-3-(4-nitrophenyl)ureidoethyl}urea that encapsulates hydrogen-bonded chains of dihydrogen phosphate anions with separate tetra-n-butylammonium counter-ions [O] . Ruyu Wang, Xi Shu, Yu Fan, 2019

机译：三尿素受体3-（4-硝基苯基）-11-双{2- 3- 3-（4-硝基苯基）脲基乙基}脲的主体-客体复合物的晶体结构该结构封装了氢键磷酸二氢根阴离子与单独的四正丁基铵抗衡离子的链
7. The role of acid in the formation of hydrogen-bonded networks featuring 4,4'-dicarboxy-2,2'-bipyridine (H2dcbp): Synthesis, structural and magnetic characterisation of {[Cu(H2dcbp)Cl2].H2O}2 and [Cu(H2dcbp)(NO3)2(H2O)] [O] . Tynan, Eithne, Jensen, Paul, Lees, Anthea C., 2005

机译：酸在形成以4,4'-二羧基-2,2'-联吡啶（H2dcbp）为特征的氢键网络中的作用：{[Cu（H2dcbp）Cl2] .H2O} 2的合成，结构和磁性表征[铜（H2dcbp）（NO3）2（H2O）]

Hydrogen-bonded 3-D network structures of lanthanide aquo ions and 4,4 '-bipyridine with carbaborane anions

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