An aqua-soluble copper(II)-sodium two-dimensional coordination polymer with intercalated infinite chains of decameric water clusters

Karabach YY; Kirillov AM; da Silva MFCG; Kopylovich MN; Pombeiro AJL

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An aqua-soluble copper(II)-sodium two-dimensional coordination polymer with intercalated infinite chains of decameric water clusters

机译：具有十聚体水簇的无穷链插值的水溶铜（II）-钠二维配位聚合物

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Self-assembly synthesis in water, at room temperature, with dinuclear copper triethanolaminate and aqua-sodium building blocks as well as benzene-1,2,4,5-tetracarboxylate linkers leads to the formation of an heteronuclear Cu-Na assembly with a two-dimensional metal-organic framework, providing the first example of an aqua-soluble copper-containing coordination polymer that hosts infinite chains of decameric water clusters (H2O)(10) formed by quasiplanar cyclic water octamers with two pendent water molecules.

机译：在室温下，使用双核三乙醇胺铜和水钠结构单元以及苯1,2,4,5-四羧酸酯连接基在水中自组装合成导致形成具有两个杂原子的铜-钠组装体维有机金属框架，提供了包含水溶性铜的配位聚合物的第一个示例，该聚合物具有由具有两个侧垂水分子的准平面环状水八聚体形成的十聚体水簇（H2O）（10）的无限链。

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来源
《Crystal growth & design》 |2006年第10期|共4页
作者
Karabach YY; Kirillov AM; da Silva MFCG; Kopylovich MN; Pombeiro AJL;
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正文语种 eng
中图分类晶体学;
关键词
COPPER TRIETHANOLAMINE COMPLEXES; ORGANIC SUPRAMOLECULAR COMPLEX; SECONDARY BUILDING UNITS; (H2O)(10) CLUSTER; SOLID-STATE; 1; 2; 4; 5-BENZENETETRACARBOXYLIC ACID; PEROXIDATIVE OXIDATION; FRAMEWORK STRUCTURE; CRYSTAL-STRUCTURE; METAL-COMPLEXES;

机译：铜三乙醇胺络合物;有机超分子络合物;二级建筑单元;（H2O）（10）团簇;固态;1;2;4;5-苯甲醛四羧酸;过氧化氧化;骨架结构;晶体结构;

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1. An aqua-soluble copper(II)-sodium two-dimensional coordination polymer with intercalated infinite chains of decameric water clusters [J] . Karabach YY, Kirillov AM, da Silva MFCG, Crystal growth & design . 2006,第10期

机译：具有十聚体水簇的无穷链插值的水溶铜（II）-钠二维配位聚合物
2. An Infinite Sandwich-type Copper (i) Coordination Polymer Containing 2-d Double Chains Layers Structure Intercalated With The Terephthalic Acid Layers [J] . M. J. Ren, J. Zhang, P. Zhao, Journal of inorganic and organometallic polymers and materials . 2008,第2期

机译：无限夹心型铜（i）配位聚合物，其中包含插有对苯二甲酸层的二维双链层结构
3. A layered zinc(II) coordination polymer containing infinite Zn-S-Zn chains and its cluster-like derivative [J] . Luo D., Chen Z., Wu L., Zeitschrift fur Anorganische und Allgemeine Chemie . 2013,第14期

机译：含无限个Zn-S-Zn链的层状锌（II）配位聚合物及其簇状衍生物
4. Synthesis and Crystal Structure of a New Copper(II) Coordination Polymer Cu(II)C_(16) H_(18) N_4O_4S_n [C] . LI Jia-gui, ZHU Wan-ren, DING Shu-hong, International Conference on Chemical Engineering and Advanced Materials . 2012

机译：新型铜（II）配位聚合物的合成和晶体结构Cu（II）C_（16）H_（18）N_4O_4S _N
5. Chemistry of copper peptide complexes: Alkoxide coordination in copper(II) and copper(III) peptide complexes, and base decomposition of copper(III) peptide complexes [D] . Wang, Lihua. 1991

机译：铜肽络合物的化学：铜（II）和铜（III）肽络合物中的醇配位，以及铜（III）肽络合物的碱分解
6. Polydi-μ-glycinato-copper(II): a two-dimensional coordination polymer [O] . Fabienne Gschwind, Martin Jansen 2011

机译：聚di-μ-氨基乙酸铜（II）：一种二维配位聚合物
7. Synthesis and characterisation of new copper(II) coordination polymers constructed from pyrazine–tetrazole ligands with the formation of a water cluster [O] . Ursula Sheridan, John F. Gallagher, Elisa Fadda, 2016

机译：用吡嗪 - 四唑配体与水簇形成的新铜（II）配位聚合物的合成与表征
8. Studies in the Field of Coordination Chain Polymers Vii. Coordination Polymers Based on Quinizarin and 4, 4 '-Bis-(Acetoacetyl)-Diphenyl Ether [R] . Korshak, V. V., Vinogradova, S. V., Morozova, D. T. 1964

机译：配位链聚合物领域的研究Vii。基于喹吖啶和4,4'-双（乙酰乙酰基） - 二苯醚的配位聚合物

An aqua-soluble copper(II)-sodium two-dimensional coordination polymer with intercalated infinite chains of decameric water clusters

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