Varying the interplay of calix[5] arenes through chloromethane inclusion

Clark TE; Makha M; Raston CL; Sobolev AN

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Varying the interplay of calix[5] arenes through chloromethane inclusion

机译：通过加入氯甲烷改变杯[5]芳烃的相互作用

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摘要

Three inclusion complexes of calix[5] arenes as dichloromethane (DCM) or chloroform solvates have been structurally authenticated, namely, the complexes of p-Bu-t-calix[5] arene, 1, or p-H-calix[5] arene, with DCM, 2, and a new polymorph of the complex of p-phenyl-calix[5] arene with chloroform, 3. Complex 1 has two adjacent tbutyl groups of one calixarene embracing the analogous groups from another calixarene. Complex 2 has a slipped head-to-head arrangement of calixarenes with a DCM molecule in the cavity of each calixarene. In complex 3, the calixarenes form dimers through interdigitation, and these dimers are assembled with back-to-back arrangement of calixarenes from adjacent dimers. All solvate complexes were crystallized in the presence of p-carborane, which has complementarity of size of the cavity of the calixarenes yet is not incorporated in the structures.

机译：杯[5]芳烃的三种夹杂物，如二氯甲烷（DCM）或氯仿溶剂化物已得到结构鉴定，即p-Bu-t-calix [5]芳烃1或pH-calix [5]芳烃的络合物，与DCM 2和一个新的对苯基-杯杯[5]芳烃与氯仿配合物的多晶型物3。配合物1具有一个相邻杯的两个叔丁基，其中一个杯芳烃包含另一个杯芳烃的类似基团。络合物2具有杯芳烃的滑动的头对头排列，在每个杯芳烃的腔中具有DCM分子。在复合物3中，杯芳烃通过相互交叉形成二聚体，并且这些二聚体与相邻二聚体的杯芳烃的背对背排列组装在一起。所有的溶剂化物配合物在对-碳硼烷的存在下结晶，对-碳硼烷具有杯芳烃腔的大小的互补性，但是没有结合到结构中。

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《Crystal growth & design》 |2006年第12期|共5页
作者
Clark TE; Makha M; Raston CL; Sobolev AN;
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正文语种 eng
中图分类晶体学;
关键词
ONE-STEP SYNTHESIS; MOLECULAR-STRUCTURE; DEEP-CAVITY; FUNCTIONALIZED MACROCYCLES; CRYSTAL-STRUCTURE; SOLID-STATE; COMPLEX; CALIXARENES; C-60; ENCAPSULATION;

机译：一步合成;分子结构;深腔;功能性大环;晶体结构;固态;络合物;杯芳烃;C-60;封装;

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专利

1. Varying the interplay of calix[5] arenes through chloromethane inclusion [J] . Clark TE, Makha M, Raston CL, Crystal growth & design . 2006,第12期

机译：通过加入氯甲烷改变杯[5]芳烃的相互作用
2. Structural characterization of inclusion complexes of para-sulphonato-calix[8]arene with 1,2-bis(4-pyridyl)-ethane and 1,3-bis(4-pyridyl)-propane. New 'double cone' and 'up-flat-down' conformations of para-sulphonato-calix[8]arene [J] . Lesniewska B., Perret F., Suwinska K., CrystEngComm . 2014,第21期

机译：对磺酸盐杯[8]芳烃与1,2-双（4-吡啶基）-乙烷和1,3-双（4-吡啶基）-丙烷的包合物的结构表征。对中音杯[8]芳烃的新“双锥”和“上-下”构象
3. Inclusion of Cavitands and Calix arenes into a Metallobridged para-(1H-Imidazo[4,5-f][3,8]phenanthrolin-2-yl)-Expanded Calix[4]arene [J] . Enrique Botana, Eric Da Silva, Jordi Benet-Buchholz Angewandte Chemie . 2007,第26期

机译：将Cavitands和杯芳烃引入金属桥联的对-（1H-咪唑并[4,5-f] [3,8]菲咯啉-2-基）-扩展杯[4]芳烃
4. Self-Inclusion Phenomenon of Calix4arene Ruthenium and Rhodium Complexes [C] . Youichi Ishii, Shinji Onozaki, Kosuke Fujimoto Symposium on Organometallic Chemistry . 2006

机译：CALIX 4芳烃钌和铑配合物的自掺杂现象
5. Lower-rim chemistry of calix(5)arenes, isolation of calix(9--20)arenes, and investigations of the mechanisms of the base-induced and acid-catalyzed calixarene-forming reactions [D] . Stewart, Donald Ralph 1997

机译：杯芳烃（5）芳烃的下边缘化学，杯芳烃（9--20）芳烃的分离，以及碱诱导的和酸催化的杯芳烃形成反应机理的研究
6. Crystal structure of the inclusion complex 25-benzoylmethoxy-5111723-tetra-tert-butyl-262728-trihydroxy-281420-tetrathiacalix4arene–tetraethylammonium chloride (1/1) [O] . Mehmet Akkurt, Jerry P. Jasinski, Shaaban K. Mohamed, 2015

机译：包合物25-苯甲酰甲氧基-5111723-四叔丁基-262728-三羟基-281420-四硫杂杯4芳烃-四乙基氯化铵的晶体结构（1 / 1）
7. Self inclusion in a calix[5]arene structure; structure of the cone conformer of a pentahydroxy-p-tert-butylcalix[5]arene [O] . Gallagher, John F., Ferguson, George, Böhmer, Volker, 1994

机译：自包含在杯[5]芳烃结构中；五羟基对叔丁基杯[5]芳烃的锥形构象的结构

Varying the interplay of calix[5] arenes through chloromethane inclusion

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